Ruthenium (Ru)‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analys...Ruthenium (Ru)‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analysis of their basic properties and oxidation behavior. There is particular emphasis on Ru‐catalyzed gas‐solid catalytic reactions, including the catalytic oxidation of VOCs, preferential oxidation of CO, synthesis of ammonia, oxidation of HCl and partial oxidation of CH4. Recent litera‐ture on catalysis is summarized and compared. Finally, we describe current challenges in the field and propose approaches for future development of Ru‐based catalysts.展开更多
A stochastic local limited one-dimensional rice-pile model is numerically investigated. The distributions for avalanche sizes have a clear power-law behavior and it displays a simple finite size scaling. We obtain the...A stochastic local limited one-dimensional rice-pile model is numerically investigated. The distributions for avalanche sizes have a clear power-law behavior and it displays a simple finite size scaling. We obtain the avalanche exponents Ts= 1.54±0.10,βs = 2.17±0.10 and TT = 1.80±0.10, βT =1.46 ± 0.10. This self-organized critical model belongs to the same universality class with the Oslo rice-pile model studied by K. Christensen et al. [Phys. Rev. Lett. 77 (1996) 107], a rice-pile model studied by L.A.N. Amaral et al. [Phys. Rev. E 54 (1996) 4512], and a simple deterministic self-organized critical model studied by M.S. Vieira [Phys. Rev. E 61 (2000) 6056].展开更多
It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically.Thro...It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically.Through the study on typical organic reactions happened in ILs,such as Diels-Alder,esterification and Friedel-Crafts reaction,the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.展开更多
We investigate the evolution of cooperation with evolutionary public goods games based on finite populations, where four pure strategies: cooperators, defectors, punishers and loners who are unwilling to participate ...We investigate the evolution of cooperation with evolutionary public goods games based on finite populations, where four pure strategies: cooperators, defectors, punishers and loners who are unwilling to participate are considered. By adopting approximate best response dynamics, we show that the magnitude of rationality not only quantitatively explains the experiment results in [Nature (London) 425 (2003) 390], but also it will heavily influence the evolution of cooperation. Compared with previous results of infinite populations, which result in two equilibriums, we show that there merely exists a special equilibrium cooperation. In addition, we characterize that loner's and the relevant high value of bounded rationality will sustain payoff plays an active role in the maintenance of cooperation, which will only be warranted for the low and moderate values of loner's payoff. It thus indicates the effects of rationality and loner's payoff will influence the cooperation. Finally, we highlight the important result that the introduction of voluntary participation and punishment will facilitate cooperation greatly.展开更多
Purpose: The purpose of this study was to investigate the impact of acute exercise on reaction time and response preparation during a Go/No Go Task in children with attention deficit hyperactivity disorder (ADHD). ...Purpose: The purpose of this study was to investigate the impact of acute exercise on reaction time and response preparation during a Go/No Go Task in children with attention deficit hyperactivity disorder (ADHD). Methods: Nineteen children with ADHD (aged between 8 and 12 years old) undertook a 30-min intervention that consisted of treadmill running or video-watching presented in a counterbalanced order on different days. A Go/No Go Task was administrated after exercise or video-watching. Results: The results indicated a shorter reaction time and smaller contingent negative variation (CNV) 2 amplitude following exercise relative to the video-watching. For event related potential (ERP) analyses, greater CNV l and CNV 2 amplitudes in response to No Go stimuli in com- parison to Go stimuli was observed in the video-watching session only. Conclusion: These findings suggest that acute exercise may benefit children with ADHD by developing appropriate response preparation, particularly in maintaining a stable motor preparatory set prior to performing the given task.展开更多
Three phosphate extraction methods were used to investigate the dissolution, availability and transformation of Kunyang phosphate rock (KPR) in two surface acid soils. Dissolution was determined by measuring the incre...Three phosphate extraction methods were used to investigate the dissolution, availability and transformation of Kunyang phosphate rock (KPR) in two surface acid soils. Dissolution was determined by measuring the increase in the amounts of soluble and adsorbed inorganic phosphate fractions, and did not differ significantly among the three methods. Significant correlations were obtained among P fractions got by the three extraction methods. Dissolution continued until the end of the 90 day incubation period. At the end of the period, much of the applied phosphate recovered in both soils were in the Al and Fe P or in the hydroxide and bicarbonate extractable inorganic P fractions. The dissolution of KPR in the two soils was also similar: increased addition of phosphate rock resulted in decreased dissolution. The similarity in the order and extent of dissolution in the two soils was probably due to the similarity in each soil of several factors that are known to influence phosphate rock dissolution, namely low CEC, pH, P level, and base status; and high clay and free iron and aluminum oxide contents. The results suggested that KPR could be an alternative P source in the long, if not the short, term in the soils, provided that those factors influencing P availability in the soils are not limiting.展开更多
In the article, the fully discrete finite difference scheme for a type of nonlinear reaction-diffusion equation is established. Then the new function space is introduced and the stability problem for the finite differ...In the article, the fully discrete finite difference scheme for a type of nonlinear reaction-diffusion equation is established. Then the new function space is introduced and the stability problem for the finite difference scheme is discussed by means of variational approximation method in this function space. The approach used is of a simple characteristic in gaining the stability condition of the scheme.展开更多
Purpose: The purpose of this study was to determine the effects of acute exercise on motor response inhibition using both behavioral and electrophysiological approaches. Methods: The P3 and N1 event-related potenti...Purpose: The purpose of this study was to determine the effects of acute exercise on motor response inhibition using both behavioral and electrophysiological approaches. Methods: The P3 and N1 event-related potential (ERP) components were recorded while performing a stop-signal task in 21 college students following a moderately intense acute exercise bout for 30 min and a sedentary control session that involved reading. Results: Acute exercise induced a shorter stop signal response time (SSRT) as compared to control; however, the go response time (Go RT) remained unchanged. In examining the ERP data, acute exercise increased both P3 amplitude and latency but did not affect the N1 component. Conclusion: Acute exercise has a selective and beneficial effect on cognitive function, specifically affecting the motor response inhibition aspect of executive function. Furthermore, acute exercise predominately impacts later stages of information processing during motor response inhibition, which may lead to an increase in attentional resource allocation and confer the ability to successfully withhold a response to achieve motor response inhibition.展开更多
Laboratory experiments were conducted to investigate the transformation and performance of a granular sequence batch reactor(SBR) under the conventional organic loading rate(OLR) condition.Aerobic granules were succes...Laboratory experiments were conducted to investigate the transformation and performance of a granular sequence batch reactor(SBR) under the conventional organic loading rate(OLR) condition.Aerobic granules were successfully cultivated in a SBR by means of alternative feeding load combined with reducing settling time after 60 d operational period.Subsequently,the black fungal granules were presented in reactor because of the filamentous overgrowth on the surface of aerobic granules.A small amount of fungal granules had no effect on the performance of granular SBR.Aerobic granules completely vanished and fungal granules eventually became the dominant species in subsequent 90 d operation after granulation.The three-dimensional excitation emission matrix(EEM) spectra result shows that the extracellular polymeric substances(EPS) component in both granules has no much difference,whereas the content of EPS in fungal granules is higher than that in bacterial granules.Due to their low bioactivity,the chemical oxidation demand(COD) and NH4-N removal efficiencies gradually decrease from 90.4%–96.5% and 99.5% to 71.8% and 32.9% respectively while the fungal granules become dominant in the SBR.展开更多
The catalytic hydrogenation of halonitroarenes to haloanilines is a green and sustainable process for the production of key nitrogen-containing intermediates in fine chemical industry.Chemoselective hydrogenation pose...The catalytic hydrogenation of halonitroarenes to haloanilines is a green and sustainable process for the production of key nitrogen-containing intermediates in fine chemical industry.Chemoselective hydrogenation poses a significant challenge,which requires the rational design of the catalysts with proper hydrogenation ability for nitro group and simultaneously preventing dehalogenation of halogen group.Herein,a highly effective Rh@Al_(2)O_(3)@C single-atom catalyst(SAC)was developed for the hydrogenation of m-chloronitrobenzene(m-CNB)to m-chloroaniline(m-CAN),through an in-situ grafting of metal during the assembly of MIL-53(Al),followed by confined pyrolysis.Extensive characterizations reveal an exquisite structure of the Rh@Al_(2)O_(3)@C,containing atomically dispersed Rh sites onto Al_(2)O_(3) confined by the amorphous carbon.The five-coordinated aluminum(Al^(Ⅴ))species are essential for achieving the atomic dispersion of Rh atoms,providing the unsaturated coordinative sites for metal.Compared to the benchmark Rh/γ-Al_(2)O_(3) and Rh/C nanocatalysts,the Rh@Al_(2)O_(3)@C SAC affords an excellent turnover frequency of 2317 molm-CNB·molRh^(–1)·h^(–1),the highest value to date in heterogeneous catalyst systems for the hydrogenation of m-CNB at 313 K and 20 bar H2,together with a sustained selectivity to m-CAN(~98%)during five consecutive runs.The superior catalytic performance of the Rh@Al_(2)O_(3)@C is attributed to a proper modulation of electronic structure of hydrogenation metal by forming SAC,together with an enhanced accessibility of acid function sites.展开更多
We designed and synthesized ligand L1 with C3 synametry in the paper, through self-assembly with silver nitrate obtained complexes 1 of silver double helix with three nuclear, that were used to characterize its struct...We designed and synthesized ligand L1 with C3 synametry in the paper, through self-assembly with silver nitrate obtained complexes 1 of silver double helix with three nuclear, that were used to characterize its structure by NMR and mass spectrometry, the complex silver as the catalytic sites, and the ligand L of hydrogen on the nitrogen fell microphone has certain basic, that can be used as an auxiliary Methylene dehydrogenation of Isopropyl methyl cyanoacetate, thereby accelerating the reaction. Further, the introduction of a chiral ligand to give complexes 2, to achieve an asymmetric aldol reaction of methyl isocyanoacetate.展开更多
It is generally agreed that focus-on-form has been one of the prevalent teaching methods in the area of second language acquisition and correspondingly received considerable attention. This paper focuses on reactive f...It is generally agreed that focus-on-form has been one of the prevalent teaching methods in the area of second language acquisition and correspondingly received considerable attention. This paper focuses on reactive focus-on-form, introduces its corrective feedback strategies, discusses their contributions and the learner uptake in L2 classroom and addresses their implications for further research in this light in the Chinese context.展开更多
基金supported by Beijing Natural Science Foundation (8164063)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB05050100)~~
文摘Ruthenium (Ru)‐based catalysts are widely employed in several types of gas‐solid reactions because of their high catalytic activities. This review provides theoretical research on Ru‐based catalysts and an analysis of their basic properties and oxidation behavior. There is particular emphasis on Ru‐catalyzed gas‐solid catalytic reactions, including the catalytic oxidation of VOCs, preferential oxidation of CO, synthesis of ammonia, oxidation of HCl and partial oxidation of CH4. Recent litera‐ture on catalysis is summarized and compared. Finally, we describe current challenges in the field and propose approaches for future development of Ru‐based catalysts.
基金supported by the Science Foundation of Henan University of Science and Technology under Grant Nos.05-032 and 2006QN033
文摘A stochastic local limited one-dimensional rice-pile model is numerically investigated. The distributions for avalanche sizes have a clear power-law behavior and it displays a simple finite size scaling. We obtain the avalanche exponents Ts= 1.54±0.10,βs = 2.17±0.10 and TT = 1.80±0.10, βT =1.46 ± 0.10. This self-organized critical model belongs to the same universality class with the Oslo rice-pile model studied by K. Christensen et al. [Phys. Rev. Lett. 77 (1996) 107], a rice-pile model studied by L.A.N. Amaral et al. [Phys. Rev. E 54 (1996) 4512], and a simple deterministic self-organized critical model studied by M.S. Vieira [Phys. Rev. E 61 (2000) 6056].
基金Supported by the National Natural Science Foundation of China(21176248)
文摘It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically.Through the study on typical organic reactions happened in ILs,such as Diels-Alder,esterification and Friedel-Crafts reaction,the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
基金Supported by National Nature Science Foundation under Grant No.60904063the Tianjin municipal Natural Science Foundation under Grant Nos.11JCYBJC06600,11ZCKF6X00900,11ZCKFGX00900
文摘We investigate the evolution of cooperation with evolutionary public goods games based on finite populations, where four pure strategies: cooperators, defectors, punishers and loners who are unwilling to participate are considered. By adopting approximate best response dynamics, we show that the magnitude of rationality not only quantitatively explains the experiment results in [Nature (London) 425 (2003) 390], but also it will heavily influence the evolution of cooperation. Compared with previous results of infinite populations, which result in two equilibriums, we show that there merely exists a special equilibrium cooperation. In addition, we characterize that loner's and the relevant high value of bounded rationality will sustain payoff plays an active role in the maintenance of cooperation, which will only be warranted for the low and moderate values of loner's payoff. It thus indicates the effects of rationality and loner's payoff will influence the cooperation. Finally, we highlight the important result that the introduction of voluntary participation and punishment will facilitate cooperation greatly.
基金particularly supported by the "Aim for the Top University Plan" of the National Taiwan Normal University and Ministry of Education,Taiwan,Chinaby the Ministry of Science and Technology (Taiwan,China) under grant NSC102-2410-H-003-128
文摘Purpose: The purpose of this study was to investigate the impact of acute exercise on reaction time and response preparation during a Go/No Go Task in children with attention deficit hyperactivity disorder (ADHD). Methods: Nineteen children with ADHD (aged between 8 and 12 years old) undertook a 30-min intervention that consisted of treadmill running or video-watching presented in a counterbalanced order on different days. A Go/No Go Task was administrated after exercise or video-watching. Results: The results indicated a shorter reaction time and smaller contingent negative variation (CNV) 2 amplitude following exercise relative to the video-watching. For event related potential (ERP) analyses, greater CNV l and CNV 2 amplitudes in response to No Go stimuli in com- parison to Go stimuli was observed in the video-watching session only. Conclusion: These findings suggest that acute exercise may benefit children with ADHD by developing appropriate response preparation, particularly in maintaining a stable motor preparatory set prior to performing the given task.
文摘Three phosphate extraction methods were used to investigate the dissolution, availability and transformation of Kunyang phosphate rock (KPR) in two surface acid soils. Dissolution was determined by measuring the increase in the amounts of soluble and adsorbed inorganic phosphate fractions, and did not differ significantly among the three methods. Significant correlations were obtained among P fractions got by the three extraction methods. Dissolution continued until the end of the 90 day incubation period. At the end of the period, much of the applied phosphate recovered in both soils were in the Al and Fe P or in the hydroxide and bicarbonate extractable inorganic P fractions. The dissolution of KPR in the two soils was also similar: increased addition of phosphate rock resulted in decreased dissolution. The similarity in the order and extent of dissolution in the two soils was probably due to the similarity in each soil of several factors that are known to influence phosphate rock dissolution, namely low CEC, pH, P level, and base status; and high clay and free iron and aluminum oxide contents. The results suggested that KPR could be an alternative P source in the long, if not the short, term in the soils, provided that those factors influencing P availability in the soils are not limiting.
文摘In the article, the fully discrete finite difference scheme for a type of nonlinear reaction-diffusion equation is established. Then the new function space is introduced and the stability problem for the finite difference scheme is discussed by means of variational approximation method in this function space. The approach used is of a simple characteristic in gaining the stability condition of the scheme.
基金supported in part by grants from the Ministry of Science and Technology to Yu-Kai Chang (NSC 102-2410-H-179-014-MY3)
文摘Purpose: The purpose of this study was to determine the effects of acute exercise on motor response inhibition using both behavioral and electrophysiological approaches. Methods: The P3 and N1 event-related potential (ERP) components were recorded while performing a stop-signal task in 21 college students following a moderately intense acute exercise bout for 30 min and a sedentary control session that involved reading. Results: Acute exercise induced a shorter stop signal response time (SSRT) as compared to control; however, the go response time (Go RT) remained unchanged. In examining the ERP data, acute exercise increased both P3 amplitude and latency but did not affect the N1 component. Conclusion: Acute exercise has a selective and beneficial effect on cognitive function, specifically affecting the motor response inhibition aspect of executive function. Furthermore, acute exercise predominately impacts later stages of information processing during motor response inhibition, which may lead to an increase in attentional resource allocation and confer the ability to successfully withhold a response to achieve motor response inhibition.
基金Project(51078036) supported by the National Natural Science Foundation of China
文摘Laboratory experiments were conducted to investigate the transformation and performance of a granular sequence batch reactor(SBR) under the conventional organic loading rate(OLR) condition.Aerobic granules were successfully cultivated in a SBR by means of alternative feeding load combined with reducing settling time after 60 d operational period.Subsequently,the black fungal granules were presented in reactor because of the filamentous overgrowth on the surface of aerobic granules.A small amount of fungal granules had no effect on the performance of granular SBR.Aerobic granules completely vanished and fungal granules eventually became the dominant species in subsequent 90 d operation after granulation.The three-dimensional excitation emission matrix(EEM) spectra result shows that the extracellular polymeric substances(EPS) component in both granules has no much difference,whereas the content of EPS in fungal granules is higher than that in bacterial granules.Due to their low bioactivity,the chemical oxidation demand(COD) and NH4-N removal efficiencies gradually decrease from 90.4%–96.5% and 99.5% to 71.8% and 32.9% respectively while the fungal granules become dominant in the SBR.
文摘The catalytic hydrogenation of halonitroarenes to haloanilines is a green and sustainable process for the production of key nitrogen-containing intermediates in fine chemical industry.Chemoselective hydrogenation poses a significant challenge,which requires the rational design of the catalysts with proper hydrogenation ability for nitro group and simultaneously preventing dehalogenation of halogen group.Herein,a highly effective Rh@Al_(2)O_(3)@C single-atom catalyst(SAC)was developed for the hydrogenation of m-chloronitrobenzene(m-CNB)to m-chloroaniline(m-CAN),through an in-situ grafting of metal during the assembly of MIL-53(Al),followed by confined pyrolysis.Extensive characterizations reveal an exquisite structure of the Rh@Al_(2)O_(3)@C,containing atomically dispersed Rh sites onto Al_(2)O_(3) confined by the amorphous carbon.The five-coordinated aluminum(Al^(Ⅴ))species are essential for achieving the atomic dispersion of Rh atoms,providing the unsaturated coordinative sites for metal.Compared to the benchmark Rh/γ-Al_(2)O_(3) and Rh/C nanocatalysts,the Rh@Al_(2)O_(3)@C SAC affords an excellent turnover frequency of 2317 molm-CNB·molRh^(–1)·h^(–1),the highest value to date in heterogeneous catalyst systems for the hydrogenation of m-CNB at 313 K and 20 bar H2,together with a sustained selectivity to m-CAN(~98%)during five consecutive runs.The superior catalytic performance of the Rh@Al_(2)O_(3)@C is attributed to a proper modulation of electronic structure of hydrogenation metal by forming SAC,together with an enhanced accessibility of acid function sites.
文摘We designed and synthesized ligand L1 with C3 synametry in the paper, through self-assembly with silver nitrate obtained complexes 1 of silver double helix with three nuclear, that were used to characterize its structure by NMR and mass spectrometry, the complex silver as the catalytic sites, and the ligand L of hydrogen on the nitrogen fell microphone has certain basic, that can be used as an auxiliary Methylene dehydrogenation of Isopropyl methyl cyanoacetate, thereby accelerating the reaction. Further, the introduction of a chiral ligand to give complexes 2, to achieve an asymmetric aldol reaction of methyl isocyanoacetate.
文摘It is generally agreed that focus-on-form has been one of the prevalent teaching methods in the area of second language acquisition and correspondingly received considerable attention. This paper focuses on reactive focus-on-form, introduces its corrective feedback strategies, discusses their contributions and the learner uptake in L2 classroom and addresses their implications for further research in this light in the Chinese context.