“物必有合”:董仲舒政治哲学再探讨

董仲舒"王道之三纲"并非"君为臣纲,父为子纲,夫为妻纲"意义上的绝对服从。董仲舒强调《春秋》大义,也非主张绝对服从。后人对董仲舒"王道之三纲"与"《春秋》之法"的曲解,是建立在对其政治哲学深层意涵的误解之上的。董仲舒政治哲学的深层根基是"物必有合"的思想及其与此相关的"三才之道"。

分中有合——武汉地铁线网服务中心方案设计

本文介绍了地铁线网服务中心这一特殊功能的建筑，着重分析了武汉地铁线网服务中心方案（中标）设计中的一些新思路和突破点。

“不作好恶”与阳明心学有无相合特质

王阳明心学体现为有无相合的性质,包括以有合无、无中生有两方面。"不作好恶"是理解王阳明有无相合心学特质的重要观念。"不作好恶"有三层意涵,这三层意涵无不关联并指向着王阳明有无相合的哲学理想:心之本体无有作好作恶指示出"无中生有"的学问;不作好恶的工夫指示出"以有合无"的思想;情顺万物的境界也就是即有即无的圆融境界。

“合中有分 分中有合”的器乐教学模式研究

当今,传统的高师音乐教学已不能适应现代音乐教育的要求与发展,教学改革势在必行。本文结合器乐教学改革实践,分析了高师音乐教学模式改革的原因,提出了"合中有分,分中有合"的高师音乐教学模式。

Mesoporous Carbon Nanofibers Loaded with Ordered PtFe Alloy Nanoparticles for Electrocatalytic Nitrate Reduction to Ammonia

Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we prepared mesoporous carbon nanofibers(mCNFs)functionalized with ordered PtFe alloys(O-PtFe-mCNFs)by a composite micelle interface-induced co-assembly method using poly(ethylene oxide)-block-polystyrene(PEO-b-PS)as a template.When employed as electrocatalysts,O-PtFe-mCNFs exhibited superior electrocatalytic performance for the NO_(3RR)compared to the mCNFs functionalized with disordered PtFe alloys(D-PtFe-mCNFs).Notably,the NH_(3)production performance was particularly outstanding,with a maximum NH_(3)yield of up to 959.6μmol/(h·cm~2).Furthermore,the Faraday efficiency(FE)was even 88.0%at-0.4 V vs.reversible hydrogen electrode(RHE).This finding provides compelling evidence of the potential of ordered PtFe alloy catalysts for the electrocatalytic NO_(3)RR.

A review of anode materials for sodium ion batteries

Lithium-ion batteries(LIBs)are used in electric vehicles and portable smart devices,but lithium resources are dwindling and there is an increasing demand which has to be catered for.Sodium ion batteries(SIBs),which are less costly,are a promising replacement for LIBs because of the abundant natural reserves of sodium.The anode of a SIB is a necessary component of the battery but is less understood than the cathode.This review outlines the development of various types of anodes,including carbonbased,metallic and organic,which operate using different reaction mechanisms such as intercalation,alloying and conversion,and considers their challenges and prospects.Strategies for modifying their structures by doping and coating,and also modifying the solid electrolyte interface are discussed.In addition,this review also discusses the challenges encountered by the anode of SIBs and the solutions.

Modeling and characterization on electroplastic effect during dynamic deformation of 5182-O aluminum alloy

The coupling effects of electrical pulse,temperature,strain rate,and strain on the flow behavior and plasticity of 5182-O aluminum alloy were investigated and characterized.The isothermal tensile test and electrically-assisted isothermal tensile test were performed at the same temperature,and three typical models were further embedded in ABAQUS/Explicit for numerical simulation to illustrate the electroplastic effect.The results show that electric pulse reduces the deformation resistance but enhances the elongation greatly.The calibration accuracy of the proposed modified Lim−Huh model for highly nonlinear and coupled dynamic hardening behavior is not much improved compared to the modified Kocks−Mecking model.Moreover,the artificial neural network model is very suitable to describe the macromechenical response of materials under the coupling effect of different variables.

Modeling of recrystallization behaviour of AA6xxx aluminum alloy during extrusion process

An innovative approach was introduced for the development of a AA6063 recrystallization model.This method incorporated a regression-based technique for the determination of material constants and introduced novel equations for assessing the grain size evolution.Calibration and validation of this methodology involved a combination of experimentally acquired microstructural data from the extrusion of three different AA6063 profiles and results from the simulation using the Qform Extrusion UK finite element code.The outcomes proved the agreement between experimental findings and numerical prediction of the microstructural evolution.The trend of the grain size variation based on different process parameters was accurately simulated,both after dynamic and static recrystallization,with an error of less than 25% in almost the whole sampling computations.

Synthesis and structures of cdq‑topological quaternary and(4,4,8)‑c topological quinary Zn‑MOFs with both oxalic acid and triazole ligands

Different solvothermal reactions of ZnC2O_(4)with oxalic acid(H_(2)ox)and 1,2,4-triazole(Htrz)successfully gave a new quaternary(NJTU-Bai83,NJTU-Bai=Nanjing Tech University Bai's group)and a new quinary(NJTU-Bai84)anionic metal-organic frameworks(MOFs),where NJTU-Bai83=(Me_(2)NH_(2))2[Zn_(3)(trz)_(2)(ox)_(3)]·2H_(2)O and NJTU-Bai84=(Me_(2)NH_(2))[Zn_(3)(trz)_(3)(ox)_(2)]·H_(2)O,respectively.With the[Zn_(2)(ox)4(trz)_(2)]secondary building unit(SBU)in NJTU-Bai83 replaced by the[Zn_(3)(ox)_(2)(trz)_(6)]and planar[Zn(ox)_(2)(trz)_(2)]ones in NJTU-Bai84,2D supramolecular building layers(SBLs)are changed from the A-layer and B-layer to another A-layer,while pillars are transformed from the tetrahedral[Zn(ox)_(2)(trz)_(2)]SBU to the irregular tetrahedral[Zn(ox)_(2)(trz)_(2)]and planar[Zn(ox)_(2)(trz)_(2)]SBUs.Thus,cdq-topological quaternary NJTU-Bai83 is tuned to(4,4,8)-c new topological quinary NJTU-Bai84.Two MOFs were well characterized by powder X-ray diffraction,thermogravimetric analysis,elemental analysis,etc.CCDC:2351819,NJTU-Bai83;2351820,NJTU-Bai84.

A Computational Framework for Parachute Inflation Based on Immersed Boundary/Finite Element Approach

A computational framework for parachute inflation is developed based on the immersed boundary/finite element approach within the open-source IBAMR library.The fluid motion is solved by Peskin's diffuse-interface immersed boundary(IB)method,which is attractive for simulating moving-boundary flows with large deformations.The adaptive mesh refinement technique is employed to reduce the computational cost while retain the desired resolution.The dynamic response of the parachute is solved with the finite element approach.The canopy and cables of the parachute system are modeled with the hyperelastic material.A tether force is introduced to impose rigidity constraints for the parachute system.The accuracy and reliability of the present framework is validated by simulating inflation of a constrained square plate.Application of the present framework on several canonical cases further demonstrates its versatility for simulation of parachute inflation.

Synthesis,crystal structure and photo-physical properties of tris(4-methyl-2,5-diphenylpyridine)iridium for OLED

Organic light-emitting diodes(OLEDs)have important applications in the field of next-generation displays and lighting,and phosphorescent iridium complexes are an important class of electroluminescent phosphorescent materials.In this paper,Ir(bmppy)_(3),tris(4-methyl-2,5-diphenylpyridine)iridium,was synthesized and elvaluted for photo-physical characteristics.Single crystals suitale for X-ray diffraction(XRD)were grown from a mixture solvent of dichloromethane and absolute ethanol.The composition and structur of Ir(bmppy)_(3)were determined by element analysis,NMR spectra and XRD.The complex crystallizes in the monoclinic symmetry with the space group P21/c with a slightly distorted octahedral configuration.As measured by UV-Visible and photoluminescence spectra,Ir(bmppy)_(3) displays a maximum emission at at 527 nm at ambient temperature,a typical green-emitting profile.The complex has potential for application in the OLED industry.

我国金融业混业经营的条件具备了吗?

混业经营代表了当今国际金融业经营模式的最新趋势。我国当前实行的是分业经营制度,这种制度在上世纪90年代治理我国通货膨胀和金融秩序混乱具有一定的积极作用,并且目前看来,其存在还具有一定的合理性。然而我国己加入WTO,这意味着我国经济将逐步地全面融入国际经济的大框架中,对国际金融业的混业经营趋势,我国的金融业经营制度将何去何从——这是一个需要做出抉择的问题。本文从我国的实情出发,提出我国金融业在改革的过渡期内,应采取分中有合的发展模式,逐步走向全面的混业经营。

Prediction of edge cracks and plastic-damage analysis of Mg alloy sheet in rolling

A thermal-mechanical-damage coupled finite elements model was established to investigate temperature changes, edge cracks and rolling force during roiling of magnesium alloy sheet. A cuneal sheet was also adopted to study the influence of reduction on temperature, damage and rolling force. The results show that with increasing the reduction, the rolling force increases, and the temperature of the Mg sheet decreases. Edge cracks occur when the reduction is above 51.6%, with the damage value of above 0.49. The plastic-damage in Mg sheet rolling is a result of hole development, shearing deformation and accumulative plastic strain.

Estimation of Net Primary Productivity of Terrestrial Vegetation in China by Remote Sensing

Among the many approaches for studying the net primary productivity (NPP), a new method by using remote sensing was introduced in this paper. With spectral information source (the visible band, near infrared band and thermal infrared band) of NOAA-AVHRR, we can get the relative index and parameters, which can be used for estimating NPP of terrestrial vegetation. By means of remote sensing, the estimation of biomass and NPP is mainly based on the models of light energy utilization. In other words, the biomass and NPP can be calculated from the relation among NPP, absorbed photosynthetical active radiation (APAR) and the rate (epsilon) of transformation of APAR to organic matter, thus: NPP = ( FPAR x PAR) x [epsilon * x sigma (T) x sigma (E) x sigma (S) x (1 - Y-m) x (1 - Y-g)]. Based upon remote sensing ( RS) and geographic information system (GIS), the NPP of terrestrial vegetation in China in every ten days was calculated, and the annual NPP was integrated. The result showed that the total NPP of terrestrial vegetation in China was 6.13 x 10(9) t C . a(-1) in 1990 and the maximum NPP was 1 812.9 g C/m(2). According to this result, the spatio-temporal distribution of NPP was analyzed. Comparing to the statistical models, the RS model, using area object other than point one, can better reflect the distribution of NPP, and match the geographic distribution of vegetation in China.

Measuring technical efficiency of Chinese nonferrous metals enterprises on a background of industry consolidation

Since 2009, Chinese nonferrous metals industry has been carried out industry consolidation with strong support by the central government. This work examined technical efficiency of Chinese nonferrous metals firms and its change during the period of 2007 and 2011. Based on financial data from nonferrous metals listed companies, technical efficiency of nonferrous metal minerals mining firms and nonferrous metal smelting, pressing and processing firms was estimated respectively using the data envelopment analysis （DEA） method. It was found that, in both sectors, number of pure technical and scale inefficient firms dominated over efficient ones. Overall, their technical and scale efficiency tended to be very low after 2009. In particular, efficiency scores of nonferrous metal smelting, pressing and processing firms fluctuated greatly during the research period. And a limited number of large leading firms were able to maintain 100% efficiency score in the industry, while efficiency of most of other leading firms has declined since 2009.

Fabrication and characterization of tungsten-containing mesoporous silica for heterogeneous oxidative desulfurization

A series of functional,tungsten-containing mesoporous silica materials（W-SiO2） have been fabricated directly from an ionic liquid that contained imidazole and polyoxometalate,which acted as mesoporous template and metal source respectively.These materials were then characterized through X-ray diffraction（XRD）,transmission electron microscopy（TEM）,Raman spectroscopy,Fourier transform infrared spectra（FTIR）,diffuse reflectance spectra（DRS）,and N2 adsorption-desorption,which were found to contain tungsten species that were effectively dispersed throughout the structure.The as-prepared materials W-SiO2 were also found to possess a mesoporous structure.The pore diameters of the respective sample W-SiO2-20 determined from the TEM images ranged from 2 to 4 nm,which was close to the average pore size determined from the nitrogen desorption isotherm（2.9 nm）.The materials were evaluated as catalysts for the heterogeneous oxidative desulfurization of dibenzothiophene（DBT）,which is able to achieve deep desulfurization within 40 min under the optimal conditions（Catalyst（W-SiO2-20）= 0.01 g,temperature = 60℃,oxidant（H2O2）= 20 μL）.For the removal of different organic sulfur compounds within oil,the ability of the catalyst（W-SiO2-20） under the same conditions to remove sulfur compounds decreased in the order：4,6-dimethyldibenzothiophene Dibenzothiophene Benzothiophene 1-dodecanethiol.Additionally,they did not require organic solvents as an extractant in the heterogeneous oxidative desulfurization process.After seven separate catalytic cycles,the desulfurization efficiency was still as high as 90.3%.From the gas chromatography-mass spectrometer analysis,DBT was entirely oxidized to its corresponding sulfone DBTO2 after reaction.A mechanism for the heterogeneous desulfurization reaction was proposed.

Finite element simulation of ball spinning of NiTi shape memory alloy tube based on variable temperature field

As a new attempt,ball spinning was used to manufacture the nickel-titanium shape memory alloy（NiTi SMA） tube at elevated temperature.The NiTi bar with a nominal composition of Ni50.9Ti49.1（mole fraction,%） was solution treated and was used as the original tube blank for ball spinning.Based on the variable temperature field and the constitutive equation,rigid-viscoplastic finite element method（FEM） was applied in order to simulate the ball spinning of NiTi SMA tube.The temperature field,the stress field,the strain field and the load prediction were obtained by means of FEM.FEM results reveal that there is a temperature increase of about 160 ℃ in the principal deformation zone of the spun part.It can be found from the stress fields and the strain fields that the outer wall of NiTi SMA tube is easier to meet the plastic yield criterion than the inner wall,and the plastic deformation zone is caused to be in a three-dimensional compressive stress state.The radial strain and the tangential strain are characterized by the compressive strain,while the axial strain belongs to the tensile strain.The variation of spinning loads with the progression of the ball is of great importance in predicting the stable flow of the spun part.

Analysis of deformation characteristic in multi-way loading forming process of aluminum alloy cross valve based on finite element model

The deformation characteristic in the forming process of aluminum alloy 7075 cross valve under multi-way loading was investigated by numerical simulation method. The results indicate that there exist 4 deformation patterns in the multi-way loading forming process of cross valve, such as forward extrusion, backward extrusion, forward-lateral extrusion and backward-lateral extrusion; one or several patterns occur at different forming stages depending on loading path. In general, the main deformation pattern is forward extrusion or backward extrusion at the initial stage; the main deformation pattern is backward extrusion at the intermediate stage, and the backward extrusion and forward-lateral extrusion occur at the final stage. In order to improve the cavity fill and reduce the forming defects, the lateral extrusion deformation should be increased at the initial and intermediate stages, and the forward extrusion deformation at the final forging stage should be reduced or avoided.

Multicomponent seismic forward modeling of gas hydrates beneath the seafloor

We investigated the effect of microscopic distribution modes of hydrates in porous sediments, and the saturation of hydrates and free gas on the elastic properties of saturated sediments. We simulated the propagation of seismic waves in gas hydrate-bearing sediments beneath the seafloor, and obtained the common receiver gathers of compressional waves（P-waves） and shear waves（S-waves）. The numerical results suggest that the interface between sediments containing gas hydrates and free gas produces a large-amplitude bottomsimulating reflector. The analysis of multicomponent common receiver data suggests that ocean-bottom seismometers receive the converted waves of upgoing P- and S-waves, which increases the complexity of the wavefield record.

Synthesis of nitrocarbazole compounds and their electrocatalytic oxidation of alcohol

Three compounds with nitrocarbazole frameworks were synthesized and their electrochemical reversibility as organic electrocatalysts was studied by cyclic voltammetry. The electrochemical reversibility and oxidation‐reduction potential of the compounds were greatly affected by their substituents. The oxidation‐reduction potential of the compound with an electron‐donating group was negative, while that of the compound with an electron‐withdrawing group on the carbazole framework was positive. The electrocatalytic oxidation activities of the nitrocarbazole compounds were investigated through cyclic voltammetry and controlled potential electrolysis at room tem‐perature. The electrocatalysts showed excellent selectivity for p‐methoxybenzyl alcohol, converting it to the corresponding aldehyde through electro‐oxidation with just 2.5 mol%of the electrocata‐lysts presented. The electrocatalysts maintained their excellent electroredox activity following re‐cycling.