The porous material HZSM-5 zeolite with micro-mesopore hierarchical porosity was prepared by post-treatment （combined alkali treatment and acid leaching） of parent zeolite and its catalytic performance for benzene a...The porous material HZSM-5 zeolite with micro-mesopore hierarchical porosity was prepared by post-treatment （combined alkali treatment and acid leaching） of parent zeolite and its catalytic performance for benzene alkylation with methanol was investigated. The effect of post-treatment on the textural properties was characterized by various techniques （including ICP-AES, XRD, nitrogen sorption isotherms, SEM, NH3-TPD, Py-IR and TG）. The results indicated that the post-treatment could modify the structural and acidic properties of HZSM-5 zeolite. In this procedure, not only additional mesopores were created by selective extraction of silicon but also the acidity was tuned. Consequently, the modified HZSM-5 zeolite showed larger external surface area with less acid sites as compared to the parent zeolite. It was found out that the modified zeolite exhibited a higher benzene conversion and xylene selectivity for alkylation of benzene with methanol as well as excellent life span of the catalyst than conventional ones. This can be explained by the facts that the presence of additional mesopores improved the diffusion property in the reactions. Furthermore, the modified zeolite showed an appropriate Bronsted acidity for effective suppression of the side reaction of methanol to olefins, thus reduced the accumulation of coke on the HZSM-5 zeolite, which was favorable for the catalyst stability. In comparison with the parent HZSM-5 zeolite, the modified zeolite by alkali treatment and acid leaching showed better performance for the benzene alkylation with methanol.展开更多
Integrable Rosochatius deformations of finite-dimensional integrable systems are generalized to the solitonhierarchy with self-consistent sources.The integrable Rosochatius deformations of the Kaup-Newell hierarchy wi...Integrable Rosochatius deformations of finite-dimensional integrable systems are generalized to the solitonhierarchy with self-consistent sources.The integrable Rosochatius deformations of the Kaup-Newell hierarchy withself-consistent sources,of the TD hierarchy with self-consistent sources,and of the Jaulent Miodek hierarchy with self-consistentsources,together with their Lax representations are presented.展开更多
The effect of multiple span suspension structure on the mechanical response of bridge deck pavement was studied, and finite element analysis (FEM) of stress and strain of pavement according to the bridge floor system ...The effect of multiple span suspension structure on the mechanical response of bridge deck pavement was studied, and finite element analysis (FEM) of stress and strain of pavement according to the bridge floor system features of super-long and high flexibility was made. Meanwhile, the FEM results were compared with those of the single span suspension structure. Three-stage analytic hierarchy process (AHP) is developed to analyze the mechanical response including whole bridge analysis, partial beams section analysis and orthotropic plate analysis. The most unfavorable load position was determined by the numerical solutions acquired from each stage to study the main mechanical index of multiple span suspension structure. The FEM results showed that the mechanical response numerical solutions by using the three-stage AHP are greater than those by simplified boundary condition, and the force condition of multiple span suspension structure is worse than that of the single span suspension structure.展开更多
基金Supported by the National Natural Science Foundation of China(NSFC-21476207 and NSFC-21506189)the National Basic Research Program of China(973 Program)(2011CB710800)
文摘The porous material HZSM-5 zeolite with micro-mesopore hierarchical porosity was prepared by post-treatment （combined alkali treatment and acid leaching） of parent zeolite and its catalytic performance for benzene alkylation with methanol was investigated. The effect of post-treatment on the textural properties was characterized by various techniques （including ICP-AES, XRD, nitrogen sorption isotherms, SEM, NH3-TPD, Py-IR and TG）. The results indicated that the post-treatment could modify the structural and acidic properties of HZSM-5 zeolite. In this procedure, not only additional mesopores were created by selective extraction of silicon but also the acidity was tuned. Consequently, the modified HZSM-5 zeolite showed larger external surface area with less acid sites as compared to the parent zeolite. It was found out that the modified zeolite exhibited a higher benzene conversion and xylene selectivity for alkylation of benzene with methanol as well as excellent life span of the catalyst than conventional ones. This can be explained by the facts that the presence of additional mesopores improved the diffusion property in the reactions. Furthermore, the modified zeolite showed an appropriate Bronsted acidity for effective suppression of the side reaction of methanol to olefins, thus reduced the accumulation of coke on the HZSM-5 zeolite, which was favorable for the catalyst stability. In comparison with the parent HZSM-5 zeolite, the modified zeolite by alkali treatment and acid leaching showed better performance for the benzene alkylation with methanol.
基金Supported by National Basic Research Program of China (973 Program) under Grant No.2007CB814800National Natural Science Foundation of China under Grant No.10801083
文摘Integrable Rosochatius deformations of finite-dimensional integrable systems are generalized to the solitonhierarchy with self-consistent sources.The integrable Rosochatius deformations of the Kaup-Newell hierarchy withself-consistent sources,of the TD hierarchy with self-consistent sources,and of the Jaulent Miodek hierarchy with self-consistentsources,together with their Lax representations are presented.
基金National Science and Technology Support Program of China ( No. 2009BAG15B03)
文摘The effect of multiple span suspension structure on the mechanical response of bridge deck pavement was studied, and finite element analysis (FEM) of stress and strain of pavement according to the bridge floor system features of super-long and high flexibility was made. Meanwhile, the FEM results were compared with those of the single span suspension structure. Three-stage analytic hierarchy process (AHP) is developed to analyze the mechanical response including whole bridge analysis, partial beams section analysis and orthotropic plate analysis. The most unfavorable load position was determined by the numerical solutions acquired from each stage to study the main mechanical index of multiple span suspension structure. The FEM results showed that the mechanical response numerical solutions by using the three-stage AHP are greater than those by simplified boundary condition, and the force condition of multiple span suspension structure is worse than that of the single span suspension structure.
