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核壳结构三维有序水凝胶的制备 被引量:1
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作者 牛忠伟 李丹 杨振忠 《高分子学报》 SCIE CAS CSCD 北大核心 2002年第6期850-853,共4页
Monodisperse core-shell (polystyrene/DAAM-EA-AM) emulsions were prepared by two-step seed polymerization,and crosslinked films were obtained by ambient drying the copolymerization emulsions accompanying a interfacial ... Monodisperse core-shell (polystyrene/DAAM-EA-AM) emulsions were prepared by two-step seed polymerization,and crosslinked films were obtained by ambient drying the copolymerization emulsions accompanying a interfacial crosslinking between DAAM/ADDH.The crosslinking degree increased with thermal treatment temperature and time.After alkaline hydrolysis of ester and amide groups resulting carboxylic groups,the films were transformed to be mesostructured hydrogels.The chemical composition and ordered morphologies were experimentally confirmed by FT-IR,SEM and POM.Water uptake of the hydrogels decreased with the thermal treatment time of the films,implying the crosslinking degree also increased. 展开更多
关键词 聚苯乙烯 核壳结构 三维有序水凝胶 制备
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磺化聚苯乙烯胶体晶的红外光谱分析 被引量:9
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作者 李丹 阎卫东 +1 位作者 杨振忠 张建明 《高分子学报》 SCIE CAS CSCD 北大核心 2001年第5期561-563,共3页
Monodispersed polystyrene latexes (100~500 nm) were prepared using seed emulsion polymerization.Hard and ordered polystyrene colloidal crystals were obtained by ambient drying the monodispersed polystyrene dispersion... Monodispersed polystyrene latexes (100~500 nm) were prepared using seed emulsion polymerization.Hard and ordered polystyrene colloidal crystals were obtained by ambient drying the monodispersed polystyrene dispersions.Polystyrene colloidal crystals were chemically modified by controlled sulfonation with sulfuric acid to derive a novel macro ordered hydrogels including ordered hydrogels and core/shell hydrogels,in which sulfuric acid and sulfone groups are responsible for the hydrophilic and crosslinking performances,respectively.The chemical structure and morphologies of the hydrogels were characterized by FT IR.It is shown that at a given concentration of sulfuric acid,the structural features of the samples are controlled by sulfonation time and temperature.The modification starts from the outer layer of polystyrene spheres of the colloidal crystals and increases both in reaction rate and sulfone group amount with temperature.A preliminary mechanism of the sulfonation process to prepare the ordered structures was proposed. 展开更多
关键词 磺化聚苯乙烯 体晶 有序水凝胶 红外光谱 磺化反应机理 浓硫酸 聚苯乙烯 改性
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