A one dimensional coordination polymer, [(C7H18N)(Ag2I3)]n((C7H18N)+=Methyltriethylammonium) has been successfully synthesized and characterized by X-ray single-crystal diffraction method. Structure analysis shows tha...A one dimensional coordination polymer, [(C7H18N)(Ag2I3)]n((C7H18N)+=Methyltriethylammonium) has been successfully synthesized and characterized by X-ray single-crystal diffraction method. Structure analysis shows that the compound consists of organic cations(Methyltriethylammonium) and inorganic anion chains (Ag2I3)n-. The inorganic moiety consists of AgI4 tetrahedron, which shares the same edges with adjacent AgI4 tetrahedrons to form one-dimensional infinite double chains along a-axis. There exists weak interaction among Ag…Ag atoms in the crystal. Anion chains are surrounded by Methyltriethylammonium cations. Anion chains and cations are in combination with each other by static attracting forces in the crystal to form so-called organic-inorganic hybrid structure. According to the crystal structure data, quantum chemistry calculation with DFT on B3LYP level was used to reveal the electronic structure of title compound. CCDC: 254288.展开更多
The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modifie...The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modified silicon gel as the substrate, a kind of novel inorganic-organic hybrid material with the polymer metal complex was synthesized. The result of ESR indicates that the inorganic/organic hybrid material with the polymer metal complex based on silicon gel possesses well paramagnetis.展开更多
文摘A one dimensional coordination polymer, [(C7H18N)(Ag2I3)]n((C7H18N)+=Methyltriethylammonium) has been successfully synthesized and characterized by X-ray single-crystal diffraction method. Structure analysis shows that the compound consists of organic cations(Methyltriethylammonium) and inorganic anion chains (Ag2I3)n-. The inorganic moiety consists of AgI4 tetrahedron, which shares the same edges with adjacent AgI4 tetrahedrons to form one-dimensional infinite double chains along a-axis. There exists weak interaction among Ag…Ag atoms in the crystal. Anion chains are surrounded by Methyltriethylammonium cations. Anion chains and cations are in combination with each other by static attracting forces in the crystal to form so-called organic-inorganic hybrid structure. According to the crystal structure data, quantum chemistry calculation with DFT on B3LYP level was used to reveal the electronic structure of title compound. CCDC: 254288.
文摘The homopolymer brushes of polyacrylamide(PAAM) on spherical silicon gel were synthesized by atom transfer radical polymerization(ATRP). The silicon gel initiator was prepared by self-assemble. Utilizing these modified silicon gel as the substrate, a kind of novel inorganic-organic hybrid material with the polymer metal complex was synthesized. The result of ESR indicates that the inorganic/organic hybrid material with the polymer metal complex based on silicon gel possesses well paramagnetis.
