The solid Supramolecular complexes of β-cyclodextrin （β-CD） with ethylenediamine 1, diethylenetriamine 2 and triethylamine 3 were obtained and characterized using elemental analysis, powder X-ray diffraction, infr...The solid Supramolecular complexes of β-cyclodextrin （β-CD） with ethylenediamine 1, diethylenetriamine 2 and triethylamine 3 were obtained and characterized using elemental analysis, powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and ^1H nuclear magnetic resonance spectroscopy. Based on the results of elemental analysis and ^1H NMR, the guest-host stoichiometries of the three solid complexes were determined to be 5：2 for 1-β-CD, hl for 2-β-CD, and 1：3 for 3-β-CD. The yields were relative to the molar volume ratio of guest to β-CD cavity, and increased in the order： 1-β-CD〈2-3-CD〈3-β-CD. X-ray diffraction patterns of the inclusion complexes gave very good exhibitions not only in location of diffraction peaks but also in shape and diffraction intensity of the peaks due to the intermolecular complexations between β-CD and the guests. The formation of host-guest inclusion complexes exhibited obviously enhanced phase change temperatures of the complexed guests such as 1 and 3. The H-5 protons located at the narrower rim inside the CD cavity experienced a higher shift upon inclusion while all other protons experienced lower shifts.展开更多
The crystal of the title compound with formula C36H44Cl2F3Mo2NO8S2 (Mr = 10002.62) crystallized in monoclinic, space group P21/n, with a = 9.6184(1), b = 22.3476(2), c = 20.7758(2) ?, ( = 90.172(1)(, V = 4465.70(7) ?3...The crystal of the title compound with formula C36H44Cl2F3Mo2NO8S2 (Mr = 10002.62) crystallized in monoclinic, space group P21/n, with a = 9.6184(1), b = 22.3476(2), c = 20.7758(2) ?, ( = 90.172(1)(, V = 4465.70(7) ?3, Z = 4, Dc = 1.491 g/cm3, F(000) = 2032, ( = 0.833 mm－1, Final R = 0.0665 and wR = 0.1650 for 5044 reflections with I >2.0( (I). The crystal structure revealed that the Mo2S2 core is planar, and the trifluoroacetic group acts as a bidentate bridging ligand and coordinates to two Mo atoms forming a five-membered ring plane, in which the Mo-Mo bond distance is 2.9222(9) ? and the O-C-O angle is 131.8(7)展开更多
To fully analyze emission characteristics of VOCs （Volatile Organic Compounds） from automobile coating industry in Chongqing city, related enterprises in the city were investigated in detail. The results show that t...To fully analyze emission characteristics of VOCs （Volatile Organic Compounds） from automobile coating industry in Chongqing city, related enterprises in the city were investigated in detail. The results show that the emission of VOCs from the automobile industry in Chongqing city was approximately 20,000 t in 2012, and the contribution rate of automobile coating was 83%. Most VOCs discharged from automobile coating industry were mainly from the use of coatings, diluents, curing agents and other materials containing VOCs. During the process of automobile coating, VOCs were mainly produced during the processes of spraying and drying. Besides, VOCs are partly produced during the processes of mixing paint, gluing, waxing and repairing. The major ingredients of VOCs discharged during the process of automobile coating were methylbenzene, dimethylbenzene, trimethylbenzene, cumene, ethyl acetate, butyl alcohol, n-butyl alcohol, isobutyl alcohol, formaldehyde, butanone, acetone, cyclohexanone and methyl ethyl ketone. Besides, the ingredients of naphtha and aromatic hydrocarbon in VOCs need to be determined. The maximum OFP （Ozone Formation Potential） of the above pollutants by the typical enterprises was 900-1,300 mg/m^3. The production of SOA （Secondary Organic Aerosol） was 3,636-11,073 t/a, which didn’t include the contribution of aldehydes, ketones, ethers and esters to SOA. This research could provide scientific reference for the establishment of emission standard, control technology and management methods of VOCs from automobile coating industry that accord with economic and social development in Chongqing city.展开更多
Fluorescent nanoparticles (NPs), including quantum dots (QDs), dye-doped NPs, and rare earth-based NPs, etc., have been a major focus of research and development during the past decade. The impetus behind such endeavo...Fluorescent nanoparticles (NPs), including quantum dots (QDs), dye-doped NPs, and rare earth-based NPs, etc., have been a major focus of research and development during the past decade. The impetus behind such endeavors can be attributed to their unique chemical and optical properties, such as bright fluorescence, high photostability, large Stocks shift and flexible processability. The introduction of fluorescent NPs into analytical chemistry has opened up new venues for fluorescent analysis. In this review, we focus on the developments and analytical applications of fluorescent NPs in the chemical and biological sensing of pH, ions, organic compounds, small biological molecules, nucleic acids, proteins, virus and bacteria. The review also points out the in vitro and in vivo imaging application of fluorescent NPs at the cell and body levels. Meanwhile, the ad- vantages of NPs brought field of sensing and signal transductions are also discussed.展开更多
文摘The solid Supramolecular complexes of β-cyclodextrin （β-CD） with ethylenediamine 1, diethylenetriamine 2 and triethylamine 3 were obtained and characterized using elemental analysis, powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis, and ^1H nuclear magnetic resonance spectroscopy. Based on the results of elemental analysis and ^1H NMR, the guest-host stoichiometries of the three solid complexes were determined to be 5：2 for 1-β-CD, hl for 2-β-CD, and 1：3 for 3-β-CD. The yields were relative to the molar volume ratio of guest to β-CD cavity, and increased in the order： 1-β-CD〈2-3-CD〈3-β-CD. X-ray diffraction patterns of the inclusion complexes gave very good exhibitions not only in location of diffraction peaks but also in shape and diffraction intensity of the peaks due to the intermolecular complexations between β-CD and the guests. The formation of host-guest inclusion complexes exhibited obviously enhanced phase change temperatures of the complexed guests such as 1 and 3. The H-5 protons located at the narrower rim inside the CD cavity experienced a higher shift upon inclusion while all other protons experienced lower shifts.
文摘The crystal of the title compound with formula C36H44Cl2F3Mo2NO8S2 (Mr = 10002.62) crystallized in monoclinic, space group P21/n, with a = 9.6184(1), b = 22.3476(2), c = 20.7758(2) ?, ( = 90.172(1)(, V = 4465.70(7) ?3, Z = 4, Dc = 1.491 g/cm3, F(000) = 2032, ( = 0.833 mm－1, Final R = 0.0665 and wR = 0.1650 for 5044 reflections with I >2.0( (I). The crystal structure revealed that the Mo2S2 core is planar, and the trifluoroacetic group acts as a bidentate bridging ligand and coordinates to two Mo atoms forming a five-membered ring plane, in which the Mo-Mo bond distance is 2.9222(9) ? and the O-C-O angle is 131.8(7)
文摘To fully analyze emission characteristics of VOCs （Volatile Organic Compounds） from automobile coating industry in Chongqing city, related enterprises in the city were investigated in detail. The results show that the emission of VOCs from the automobile industry in Chongqing city was approximately 20,000 t in 2012, and the contribution rate of automobile coating was 83%. Most VOCs discharged from automobile coating industry were mainly from the use of coatings, diluents, curing agents and other materials containing VOCs. During the process of automobile coating, VOCs were mainly produced during the processes of spraying and drying. Besides, VOCs are partly produced during the processes of mixing paint, gluing, waxing and repairing. The major ingredients of VOCs discharged during the process of automobile coating were methylbenzene, dimethylbenzene, trimethylbenzene, cumene, ethyl acetate, butyl alcohol, n-butyl alcohol, isobutyl alcohol, formaldehyde, butanone, acetone, cyclohexanone and methyl ethyl ketone. Besides, the ingredients of naphtha and aromatic hydrocarbon in VOCs need to be determined. The maximum OFP （Ozone Formation Potential） of the above pollutants by the typical enterprises was 900-1,300 mg/m^3. The production of SOA （Secondary Organic Aerosol） was 3,636-11,073 t/a, which didn’t include the contribution of aldehydes, ketones, ethers and esters to SOA. This research could provide scientific reference for the establishment of emission standard, control technology and management methods of VOCs from automobile coating industry that accord with economic and social development in Chongqing city.
基金supported by the National Natural Science Foundation of China (90606003 & 20775021)International Science & Technology Cooperation Program of China (2010DFB30300)+2 种基金Program for Changjiang Scholar and Innovative Research Team in UniversityProgram for New Century Excellent Talents in University (NCET-09-0338)Hunan Natural Science Foundation (10JJ7002 & 08JJ1002)
文摘Fluorescent nanoparticles (NPs), including quantum dots (QDs), dye-doped NPs, and rare earth-based NPs, etc., have been a major focus of research and development during the past decade. The impetus behind such endeavors can be attributed to their unique chemical and optical properties, such as bright fluorescence, high photostability, large Stocks shift and flexible processability. The introduction of fluorescent NPs into analytical chemistry has opened up new venues for fluorescent analysis. In this review, we focus on the developments and analytical applications of fluorescent NPs in the chemical and biological sensing of pH, ions, organic compounds, small biological molecules, nucleic acids, proteins, virus and bacteria. The review also points out the in vitro and in vivo imaging application of fluorescent NPs at the cell and body levels. Meanwhile, the ad- vantages of NPs brought field of sensing and signal transductions are also discussed.
