The main objectives were to (1) calculate the total volatile organic compounds (TVOCs) inhalation dose, (2) analyze the proportions of human’s inhaled contaminant dose from different sources, and (3) present a newly ...The main objectives were to (1) calculate the total volatile organic compounds (TVOCs) inhalation dose, (2) analyze the proportions of human’s inhaled contaminant dose from different sources, and (3) present a newly defined ratio of relative inhalation dose level (RIDL) to assess indoor air quality (IAQ). A user defined function based on CFD (computational fluid dynamics) was developed, which integrated human motion model with TVOCs emission model in a high sidewall air supply ventilation mode. Based on simulation results of 10 cases, it is shown that the spatial concentration distribution of TVOCs is affected by human motion. TVOCs diffusion characteristic of building material is the most effective way to impact the TVOCs inhalation dose. From the RIDL index, case A-2 has the most serious IAQ problem, while case D-1 is of the best IAQ.展开更多
The authors propose a new "three-layer" conceptual model for the air-sea exchange of organic gases, which includes a dynamic surface microlayer with photochemical and biological processes. A parameterization...The authors propose a new "three-layer" conceptual model for the air-sea exchange of organic gases, which includes a dynamic surface microlayer with photochemical and biological processes. A parameterization of this three-layer model is presented, which was used to calculate the air-sea fluxes of acetone over the Pacific Ocean. The air-sea fluxes of acetone calculated by the three-layer model are in the same direction but possess half the magnitude of the fluxes calculated by the traditional two-layer model in the absence of photochemical and biological processes. However, photochemical and biological processes impacting acetone in the microlayer can greatly vary the calculated fluxes in the three-layer model, even reversing their direction under favorable conditions. Our model may help explain the discrepancies between measured and calculated acetone fluxes in previous studies. More measurements are needed to validate our conceptual model and provide constraints on the model parameters.展开更多
Semi-empirical AM1 and ZINDO/S,as well as density function theory(DFT)method B3LYP/6-31G(d)quantum chemical calculations were carried out to study the electronic structures and optical properties of poly(p-phenylene v...Semi-empirical AM1 and ZINDO/S,as well as density function theory(DFT)method B3LYP/6-31G(d)quantum chemical calculations were carried out to study the electronic structures and optical properties of poly(p-phenylene vinylene)derivatives(PPVs)with 10 and 11 phenylene rings in the backbone.The calculations suggest that the assembly of alternate incorporation of CN and alkoxy substituted phenylene rings in the PPV backbone could be a good way to construct organic semiconductors with low HOMO/LUMO energy band-gaps.The effect of the end-group on the electronic structures and optical properties of the conjugated polymer was investigated by the calculated UV-Vis and UPS spectra.It was demonstrated that the aldehyde and phosphate end-groups have limited effects on the photophysical properties in the UV-Visible range.展开更多
The joint efficient ordering method is a fundamental method of ordering alternatives in group multi-objective programming problems. In this paper, the rational properties of the joint efficient mapping corresponding t...The joint efficient ordering method is a fundamental method of ordering alternatives in group multi-objective programming problems. In this paper, the rational properties of the joint efficient mapping corresponding to the joint efficient ordering method are studied, and some necessary conditions of this mapping are proven.展开更多
This paper investigates the equality-constrained minimization of polynomial functions. Let R be the field of real numbers, and R[x1,..., xn] the ring of polynomials over R in variables x1,..., xn. For an f ∈ R[x1,......This paper investigates the equality-constrained minimization of polynomial functions. Let R be the field of real numbers, and R[x1,..., xn] the ring of polynomials over R in variables x1,..., xn. For an f ∈ R[x1,..., xn] and a finite subset H of R[x1,..., xn], denote by V(f : H) the set {f( ˉα) | ˉα∈ Rn, and h( ˉα) =0, ? h ∈ H}. We provide an effective algorithm for computing a finite set U of non-zero univariate polynomials such that the infimum inf V(f : H) of V(f : H) is a root of some polynomial in U whenever inf V(f : H) = ±∞.The strategies of this paper are decomposing a finite set of polynomials into triangular chains of polynomials and computing the so-called revised resultants. With the aid of the computer algebraic system Maple, our algorithm has been made into a general program to treat the equality-constrained minimization of polynomials with rational coefficients.展开更多
基金Projects(2006BAJ02A08, 2006BAJ02A05) supported by the National Science and Technology Pillar Program Project during the 11th Five-Year Plan PeriodProject(2007-209) supported by the Excellent Youth Teacher of Ministry of Education of China
文摘The main objectives were to (1) calculate the total volatile organic compounds (TVOCs) inhalation dose, (2) analyze the proportions of human’s inhaled contaminant dose from different sources, and (3) present a newly defined ratio of relative inhalation dose level (RIDL) to assess indoor air quality (IAQ). A user defined function based on CFD (computational fluid dynamics) was developed, which integrated human motion model with TVOCs emission model in a high sidewall air supply ventilation mode. Based on simulation results of 10 cases, it is shown that the spatial concentration distribution of TVOCs is affected by human motion. TVOCs diffusion characteristic of building material is the most effective way to impact the TVOCs inhalation dose. From the RIDL index, case A-2 has the most serious IAQ problem, while case D-1 is of the best IAQ.
基金funded by the National Natural Science Foundation of China (Grant No. 41222035)
文摘The authors propose a new "three-layer" conceptual model for the air-sea exchange of organic gases, which includes a dynamic surface microlayer with photochemical and biological processes. A parameterization of this three-layer model is presented, which was used to calculate the air-sea fluxes of acetone over the Pacific Ocean. The air-sea fluxes of acetone calculated by the three-layer model are in the same direction but possess half the magnitude of the fluxes calculated by the traditional two-layer model in the absence of photochemical and biological processes. However, photochemical and biological processes impacting acetone in the microlayer can greatly vary the calculated fluxes in the three-layer model, even reversing their direction under favorable conditions. Our model may help explain the discrepancies between measured and calculated acetone fluxes in previous studies. More measurements are needed to validate our conceptual model and provide constraints on the model parameters.
基金supported by the National Natural Science Foundation of China(21274065,20804020,21001065)National Basic Research Program of China(2009CB930601)+1 种基金Natural Science Foundation of Jiangsu Province(BK2011751)A project funded by the priority academic program development of Jiangsu higher education institutions,and Scientific Re-search Foundation of Nanjing University of Posts and Telecommunications(NY210017,NY210046)
文摘Semi-empirical AM1 and ZINDO/S,as well as density function theory(DFT)method B3LYP/6-31G(d)quantum chemical calculations were carried out to study the electronic structures and optical properties of poly(p-phenylene vinylene)derivatives(PPVs)with 10 and 11 phenylene rings in the backbone.The calculations suggest that the assembly of alternate incorporation of CN and alkoxy substituted phenylene rings in the PPV backbone could be a good way to construct organic semiconductors with low HOMO/LUMO energy band-gaps.The effect of the end-group on the electronic structures and optical properties of the conjugated polymer was investigated by the calculated UV-Vis and UPS spectra.It was demonstrated that the aldehyde and phosphate end-groups have limited effects on the photophysical properties in the UV-Visible range.
基金The research is supported by National Natural Science Foundation of China under Grant No. 70071026 Science Foundation of Wenzhou University and Science Foundation of School of Mathematics and Information Science, Wenzhou University and Zhejiang Province Education Department Scientific Research Item.
文摘The joint efficient ordering method is a fundamental method of ordering alternatives in group multi-objective programming problems. In this paper, the rational properties of the joint efficient mapping corresponding to the joint efficient ordering method are studied, and some necessary conditions of this mapping are proven.
基金supported by National Natural Science Foundation of China(Grant No.11161034)
文摘This paper investigates the equality-constrained minimization of polynomial functions. Let R be the field of real numbers, and R[x1,..., xn] the ring of polynomials over R in variables x1,..., xn. For an f ∈ R[x1,..., xn] and a finite subset H of R[x1,..., xn], denote by V(f : H) the set {f( ˉα) | ˉα∈ Rn, and h( ˉα) =0, ? h ∈ H}. We provide an effective algorithm for computing a finite set U of non-zero univariate polynomials such that the infimum inf V(f : H) of V(f : H) is a root of some polynomial in U whenever inf V(f : H) = ±∞.The strategies of this paper are decomposing a finite set of polynomials into triangular chains of polynomials and computing the so-called revised resultants. With the aid of the computer algebraic system Maple, our algorithm has been made into a general program to treat the equality-constrained minimization of polynomials with rational coefficients.
