黔北凤冈地区页岩气吸附量影响因素分析

页岩气的吸附态是页岩气开采的主要来源之一,为了研究黔北凤冈地区影响页岩气吸附量的因素,选取凤冈1井(FC-1)等的页岩作为实验研究对象,分别进行了有机碳含量、矿物组分、孔隙结构和等温吸附曲线等分析。研究表明:凤参1井及相邻试验井页岩平均有机碳含量为4.97%,主要矿物质以石英、黏土矿物和钠长石为主,页岩孔隙的形状多为不规则的球形、椭球形、三角形;页岩对甲烷的吸附量与有机碳含量、黏土矿物质、有机质孔隙和压力呈正相关,与温度、石英矿物质、水含量呈负相关。适当进行储层改造,改善控制开采过程中页岩气解吸的影响因素,对提高页岩气开采效率、延长开采时间具有重要意义。

Relationships among Glomalin Related Soil Protein,Soc and Soil Texture under Different Land Use Types

[Objective] The aim was to reveal the effects of different land use types on soil composition. [Method] GPRS,soil organic carbon content and soil texture in 3 depths (0-10,10-20,20-50 cm) of 5 main kind of selected land use type were examined in Hainan. [Result] The results showed that GRSP and SOC content of four artificial land use types decreased compared with the natural secondary forest land,the GRSP content of all samples ranged from 0.53-4.80 mg/g,accounting for 7.9%-23.4% of the SOC,which means that GRSP was one important component of SOC pool in soil. The ratio of GRSP to SOC was significantly different among land use types but the depths. GRSP and SOC exhibited obvious vertical distribution pattern. GRSP was significantly positively related to SOC and sand content but negatively related to silt and clay content. [Conclusion] The sand content determined the GRSP content significantly and loam was better matrix for GRSP accumulation than clay.

Application of a wide-field electromagnetic method to shale gas exploration in South China

In an effort to reduce the shale gas exploration risks and costs, we applied the wide-field electromagnetic method （WFEM）, because of its strong anti-interference capability, high resolution, ability to conduct exploration at large depths, and high efficiency, to the Bayan Syncline in the South Huayuan block, Hunan Province. We collected rock samples and analyzed their resistivity and induced polarization （IP） and built A series of two-dimensional models for geological conditions to investigate the applicability of WFEM to different geological structures. We also analyzed the correlation between TOC of shale and the resistivity and IP ratio to determine the threshold for identifying target formations. We used WFEM to identify the underground structures and determine the distribution, depth, and thickness of the target strata. Resistivity, IP, and total organic carbon were used to evaluate the shale gas prospects and select favorable areas （sweet spots） for exploration and development. Subsequently, drilling in these areas proved the applicability of WFEM in shale gas exploration.

Labile Organic Matter Content and Distribution as Affected by Six-year Soil Amendments to Eroded Chinese Mollisols

Labile organic carbon （LOC） is a fraction of soil organic carbon （SOC） with rapid turnover time and is affected by soil fertilization. This investigation characterized the SOC content, LOC content and LOC distribution in the treatment plots of surface soil erosion at five levels （0-, 5-, 10-, 20- and 30-cm erosion）. The soil had received contrasting fertilizer treatments （i.e., chemical fertilizer or chemical fertilizer ＋ manure） for 6 years. This study demonstrated that both SOC and various LOC fractions contents were higher in the plots with fertilizer ＋ manure than in those with fertilizer alone under the same erosion conditions. The SOC and LOC contents de- creased as the erosion depth increased. Light fraction organic carbon, particulate organic carbon, easily oxidizable organic carbon （KMnO4-oxydizable organic carbon）, and microbial biomass carbon were 27% 57%, 37%-7%, 20%-25%, and 29%-33% higher respectively in the fertilizer ＋ manure plots, than in the fertilizer alone plots. Positive correlations （p 〈 0.05） between SOC content and different fractions contents were observed in all plots except the correlation between total SOC content and water-soluble organic carbon content in the different fertilization treatments. Obviously, fertilizer ＋ manure treatments would be conducive to the accumulation of LOC and SOC in the Black soil of Northeast China.

Effects of Thinning and Litter Fall Removal on Fine Root Production and Soil Organic Carbon Content in Masson Pine Plantations

Soils play a critical role in the global carbon cycle, and can be major source or sink of CO2 depending upon land use, vegetation type and soil management practices. Fine roots are important component of a forest ecosystem in terms of water and nutrient uptake. In this study the effects of thinning and litter fall removal on fine root production and soil organic carbon content were examined in 20-year-old Masson pine （Pinus resinosa） plantations in Huitong, Hunan Province of China in the growing seasons of 2004 and 2005. The results showed that fine root production was significantly lower in the thinning plots than in the control plots, with a decrease of 58% and 14% in 2004 and 2005 growing seasons, respectively. Litter fall removal significantly increased fine root production by 14% in 2004. Soil temperature （Tsoil） and soil moisture （Msoil） were higher in the thinning plots than those in the controls. Litter fall removal had significant effects on Tsoil and Msoil. Soil organic carbon content was higher in the thinning plots but was lower in the plots with litter fall removal compared with that in the controls. Our results also indicated that annual production of fine roots resulted in small carbon accumulation in the upper layers of the soil, and removal of tree by thinning resulted in a significant increase of carbon storage in Masson pine plantations.

Temporal and Spatial Variability of Dissolved Organic Carbon Concentration in the Xijiang River, South China

A whole year analysis of riverine dissolved organic carbon (DOC) concentrations in the Xijiang River (XJR), South China, showed that the mean riverine DOC concentration (1.24 mg L-1) in the XJR was notably lower than the averaged value (5.75 mg L-1) of the global riverine DOC concentration in several major rivers. There is an inconspicuous monthly fluctuation of the DOC signal in the XJR, but on a semi-yearly time scale, however, the riverine DOC concentration had significant difference between hydrological seasons. The DOC level during the flood season (1.18 mg L-1) was less than that during the non-flood season (1.40 mg L-1). Owing to the concomitance of the flushing and dilution effects of the runoff during the high-water period, the variation of riverine DOC concentration with discharge in the XJR differed from that reported in many other major rivers. The DOC export flux above the city of Wuzhou was about 0.62× 106 g C km-2 yr-1. The DOC transported during the "056" Massive Flood period comprised 30.35% of the annual total, while the discharge accounted for 36.32% of the total annual flow. The characteristics in riverine DOC concentration in the XJR were attributed to the combined effect of the geomorphologic, monsoon climatic and hydrological processes as well as land-use within the drainage basin.

Characteristics of heavy metals in soils under different land use in a typical karst area, Southwest China

This study investigated the distribution of six pollutant elements(Cr, Cu, Pb, Zn, Cd, and As), and their relationship to soil organic carbon(SOC) in five soil profiles in the Puding area. Results show SOC content decreased exponentially to the depth of soil profiles; the vertical distribution patterns of SOC in soil profiles were partially controlled by land use. The concentrations of these pollutant elements in most soils were lower than background values, indicating that the local soil was less likely to be contaminated by foreign inputs. Geo-accumulation index values of these elements in most soil samples were less than 1, suggesting that the soil of this area may not be polluted. The concentrations of Cr, Cu, As, and Zn in soils from all land use types were significantly negatively correlated with SOC contents. Geochemical approaches confirmed that the soil of this area was less influenced by pollutant elements.

Difference in Organic Carbon Contents and Distributions in Particle-size Fractions between Soil and Sediment on the Southern Loess Plateau, China

The purpose of this study was to assess the effect of long-term cultivation and water erosion on the soil organic carbon （OC） in particle-size fractions. The study site is located at Nihegou Watershed in the Southern Loess Plateau, China. The soil at this site is loess with loose and silty structure, and contains macropores. The results showed that the OC concentrations in sediments and in the particle-size fractions of sediments were higher than those in soils and in the particle-size fractions of soils. The OC concentration was highest in the clay particles and was lowest in the sand particles. Clay particles possessed higher OC enrichment ability than silt and sand particles. The proportions of OC in the silt fractions of soil and sediment were the highest （mean value of 53.87% and 58.48%, respectively）, and the total proportion of OC in the clay and silt fractions accounted for 96% and 98% of the total OC in the soil and sediment, respectively. The loss of OC was highest in silt particles, with an average value of 0.16 Mg ha^-1 y^-1, and was lowest in the sand （0.003 Mg ha^-1 y^-l）. This result suggests that the fine particle-size fraction in the removed sediment may be an important indicator to assess soil OC losses.

Effects of Land Cover on Soil Organic Carbon Stock in a Karst Landscape with Discontinuous Soil Distribution

Land cover type is critical for soil organic carbon （SOC） stocks in territorial ecosystems. However, impacts of land cover on SOC stocks in a karst landscape are not fully understood due to discontinuous soil distribution. In this study, considering soil distribution, SOC content and density were investigated along positive successional stages （cropland, plantation, grassland, scrubland, secondary forest, and primary forest） to determine the effects of land cover type on SOC stocks in a subtropical karst area. The proportion of continuous soil on the ground surface under different land cover types ranged between 0.0% and 79.8%. As land cover types changed across the positive successional stages, SOC content in both the 0-20 cm and 20-50 cm soil layers increased significantly. SOC density （SOCD） within O-lOO cm soil depth ranged from 1.45 to 8.72 kg m^-2, and increased from secondary forest to primary forest, plantation, grassland, scrubland, and cropland, due to discontinuous soil distribution. Discontinuous soil distribution had a negative effect on 8OC stocks, highlighting the necessity for accurate determination of soil distribution in karst areas. Generally, ecological restoration had positive impacts on SOC accumulation in karst areas, but this is a slow process. In the short term, the conversion of croplandto grassland was found to be the most efficient way for SOC sequestration.

Pedogenic Carbonate and Soil Dehydrogenase Activity in Response to Soil Organic Matter in Artemisia ordosica Community

Little attention has been paid to the role of soil organic matter （OM） in the formation of pedogenic carbonate in desert soils. The relationships among soil OM, soil dehydrogenase activity （DHA）, and soil CaCO3 in a plant community dominated by Artemisia ordosica, located on the eastern boundary of Tcngger Desert in the Alxa League, Inner Mongolia, China, were studied to understand whether OM was directly involved in the formation of pedogenic carbonate. The results showed that DHA and CuCO3 positively correlated with OM content, and DHA, OM, and CaCO3 were correlated with each other in their spatial distribution, indicating that abundant OM content contributed to the formation of CaCO3. Therefore, the formation of pedogenic CaCO3 was a biotic process in the plant community dominated by A. ordosica.

Key Variables Explaining Soil Organic Carbon Content Variations in Croplands and Non-Croplands in Chinese Provinces

Soil organic carbon (SOC) plays an important role in global carbon cycles.Large spatial variations in SOC contents result in uncertain estimates of the SOC pool and its changes.In the present study,the key variables explaining the SOC contents of croplands (CPs) and non-croplands (NCPs) in Chinese provinces were investigated.Data on SOC and other soil properties (obtained from the Second National Soil Survey conducted in the late 1970s to the early 1990s),climate parameters,as well as the proportion of the CP to the total land area (Pcp) were used.SOC content variations within a province were larger than those among provinces.Soil clay and total phosphorus content,ratio of annual precipitation to mean temperature,as well as Pcp were able to explain 75% of the SOC content variations in whole soil samples.Soil pH,mean temperature during the growing season from May to October,and mean annual wind velocity were able to explain 63% of the SOC content variations in NCP soils.Compared with NCP soils,CP soils had lower SOC contents,with smaller variations within and among provinces and lower C/N ratios.Stepwise regression showed that the soil clay content was a unique factor significantly correlated with the SOC content of CP soils.However,this factor only explained 24% of the variations.This result suggested that variables related to human activities had greater effects on SOC content variations in CP soils than soil properties and climate parameters.Based on SOC contents directly averaged from soil samples and estimated by regression equations,the total SOC pool in the topsoil (0-20 cm) of China was estimated at 60.02 Pg and 57.6 Pg.Thousands of years of intensive cultivation in China resulted in CP topsoil SOC loss of 4.34-4.98 Pg.

Effects of slope position and land use on the stability of aggregateassociated organic carbon in calcareous soils

Topography and land use affect soil organic carbon(SOC) storage, stabilization, and turnover, through several biogeochemical processes. This study investigated the aggregate composition and SOC content of bulk soils and aggregates at different slope positions under different land uses in a typical karst catchment of southwestern China. Our results show that the proportion of macro-aggregates and the SOC content of bulk soils and aggregates at different slope positions decreased from the upper to the lower slope. The SOC content generally increased with an increase in the mean weight diameter and proportion of macro-aggregates under different land uses. Our results indicate that macro-aggregates in forest and grassland soils make a greater contribution to both aggregate composition and SOC content than that in arable land soils. Therefore,converting farmland to forest or grassland can facilitate the accumulation of macro-aggregates as well as the storage of SOC.

Holocene Climate Cycles in Northwest Margin of Asian Monsoon

In the mid-latitude regions of the Asian continent, Zhuye Lake is located in the northwest margin of the Asian monsoon, where the modem climate is affected by the Asian monsoon and Westerlies. In this study, we investi- gated the absolutely dated Holocene records in Zhuye Lake for detecting the Holocene climate cycles. Totally, 14 14C dates and 6 optically simulated luminescence （OSL） dates are obtained from the QTH01 and QTH02 sections. The proxies of grain-size, total organic carbon content （TOC）, C/N and 813C are used for wavelet analysis, and the results show obvious -256, -512 and -1024-year climate cycles, which are consistent with the Holocene millennial and cen- tennial scale climate cycles in the typical Asian summer monsoon domain. In different parts of the Zhuye Lake, the Holocene sediments show variable climate cycles that are affected by the lake basin topography. In the Zhuye Lake, the Holocene climate cycles are mainly correlated with the solar-related Asian summer monsoon variability and the North Atlantic ice-rafting events.

Factors Acquisition and Content Estimation of Farmland Soil Organic Carbon Based upon Internet of Things

Aiming at the shortage of sufficient continuous parameters for using models to estimate farmland soil organic carbon(SOC) content, an acquisition method of factors influencing farmland SOC and an estimation method of farmland SOC content with Internet of Things(IOT) are proposed in this paper. The IOT sensing device and transmission network were established in a wheat demonstration base in Yanzhou Distict of Jining City, Shandong Province, China to acquire data in real time. Using real-time data and statistics data, the dynamic changes of SOC content between October 2012 and June 2015 was simulated in the experimental area with SOC dynamic simulation model. In order to verify the estimation results, potassium dichromate external heating method was applied for measuring the SOC content. The results show that: 1) The estimated value matches the measured value in the lab very well. So the method is feasible in this paper. 2) There is a clear dynamic variation in the SOC content at 0.2 m soil depth in different growing periods of wheat. The content reached the highest level during the sowing period, and is lowest in the flowering period. 3) The SOC content at 0.2 m soil depth varies in accordance with the amount of returned straw. The larger the amount of returned straw is, the higher the SOC content.

Effects of Introduction of Two Kinds of Legume Species on Soil Quality in Semiarid Loess Plateau

[Objective] The study aimed to find an efficient and sustainable way to improve the degraded soil quality in the semiarid Loess Plateau. [Method] This study was done with three treatments： （1） the perennial legume species alfalfa （Medicago sativa L.） （AF） planted at a density of 22.5 kg/hm 2 ; （2） the biennial legume species sweetclover （Melilotus officinalis L.） （SF） planted at a density of 11.3 kg/hm 2 ; and （3） natural regeneration （NR）. [Result] It is found that NR helped improve deep soil water but with the lowest aboveground biomass. In contrast, AF has the lowest soil water content but with the highest aboveground biomass. Furthermore, in contrast to SF, NR and AF have a higher soil organic carbon and total nitrogen. However, there were no significant differences on soil total and available phosphorus, and soil microbial biomass among all the treatments. As the experiment lasts, AP decreased significantly in all treatments in comparison with their initial values at the beginning of the experiment in 2003. [Conclusion] NR was the best way to restore the deep soil water among all the treatments, and phosphorus fertilizer was necessary for the sustainable development of agricultural production. This research provides a valuable example of soil quality restoration in semiarid regions.

Soil Organic Carbon and Nutrients along an Alpine Grassland Transect across Northern Tibet

Soil carbon and nutrient contents and their importance in advancing our understanding of biogeochemical cycling in terrestrial ecosystem, has motivated ecologists to find their spatial patterns in various geographical area. Few studies have focused on changes in the physical and chemical properties of soils at high altitudes. Our aim was to identify the spatial distribution of soil physical and chemical properties in cold and arid climatic region. We also tried to explore relationship between soil organic carbon （SOC） and total nitrogen （TN）, total phosphorus （TP）, available nitrogen （AN）, available phosphorus （AP）, soil particle size distribution （PSD）. Samples were collected at 44 sites along a 300 km transect across the alpine grassland of northern Tibet. The study results showed that grassland type was the main factor influencing SOC, TN and TP distribution along the Gangdise Mountain-Shenzha-Shuanghu Transect. SOC, TN and TP contents were significantly higher in alpine meadow than alpine steppe ecosystems. SOC, TN, TP and AN contents in two soil layers （0-15 cm and 15-3o cm） showed no significant differences, while AP content in top soft （0-15 cm） was significantly higher than that in sub-top soil （15-30cm）. SOC content was correlated positively with TN and TP content （r = 0.901and 0.510, respectively）. No correlations were detected for clay content and fractal dimension of particle size distribution （D）. Our study results indicated the effects of vegetation on soil C, N and P seem to be more important than that of rocks itself along latitude gradient on the northern Tibetan Plateau. However, we did not found similar impacts of vegetation on soil properties in depth. Inaddition, this study also provided an interesting contribution to the global data pool on soil carbon stocks.

Preliminary Evaluation of Soils from Kwalkwalawa （Sokoto） and Bakolori （Talata Mafara） Regions Used for Rice and Fishing Activities

Kwalkwalawa is an area noted for extensive rice production and fishing activities, while Talata Mafara is a site used mainly for rice production. Soils of the two areas were taken and evaluated for potentialities of rice-cum-fish culture. Three replicate soil samples were collected in October 2004 and 2005 from three sampling sites within the study area at 0-15 cm and 15-30 cm depth. Analysis of the samples indicated that at Kwalkwalawa the soil pH was 7.35 and 7.28 for 0-15 cm and 15-30 cm depth, respectively, and 6.75 and 6.67 for Talata Mafara, respectively, during 2004. During 2005, the pH at Kwalkwalawa was 6.75 and 7.18, while at Talata Mafara ranged between 5.63 and 5.14. Organic carbon content at Kwalkwalawa estimated during 2004 was 1.12 g/kg and 0.81 g/kg for 0-15 cm and 15-30 cm, whereas at Talata Mafara amounted 0.93 g/kg and 0.11 g/kg. During 2005, noted values of organic carbon at Kwalkwalawa lowered to 0.45-0.28 g/kg and at Talata Mafara lowered to 0.38-0.06 g/kg. Total nitrogen （N） at Kwalkwalawa during 2004 was 0.04 g/kg and 0.03 g/kg for 0-15 cm and 15-30 cm, at Talata Mafara it was both 0.04 g/kg for both depths. During 2005, at Kwalkwalawa, total N was 0.04 g/kg and 0.03 g/kg, and at Talata Mafara it was 0.05 g/kg for both depths. Available phosphorus （P） at Kwalkwalawa during 2004 was 1.93 mg/kg and 2.03 mg/kg for 0-15 cm and 15-30 cm, at Talata Mafara it was 1.59 mg/kg and 1.63 mg/kg. During 2005, available P was 5.82 mg/kg and 6.13 mg/kg for Kwalkwalawa and 1.67 mg/kg and 1.91 mg/kg for Talata Mafara, at 0-15 cm and 15-30 cm, respectively. Analysis of clay content indicated that at Kwalkwalawa the clay content was 11 g/kg for both depths during 2004 and 16.5 g/kg during 2005, and the soil texture was classified as sandy loam during both seasons. At Talata Mafara during 2004, the clay content was 73 g/kg and 93 g/kg for 0-15 cm and 15-30 cm. During 2005, it was 84 g/kg and 103 g/Kg. The soil was classified as loamy sand after fitting it into textural triangle. Results indicated the clay content at Kwalkwalawa over two seasons was stable, but at Talata Mafara it differed, even though the soil texture was the same for both seasons and sampling depths. The results showed that with some textural improvements, rice-cum-fish culture project can be undertaken in the study areas.

Characterization of Humic System in Fertilizer Raw Materials

The aim of the study was to characterize humus system of natural and artificial products. Humus systems from leonardite, lignite biotransformed with Trichoderma sp. （Plantagra）, plant materials after pyrolisis （charcoal） and composts are compared. Humus systems are characterized by Kononova-Belchikova＇s method, and heavy metals content was measured by atomic absorption spectroscopy （AAS）. Humic acids from the International Humic Substances Society （IHSS） collection are the standards for humus substances quality of compared products. Data obtained for leonardite indicate that the studied substances from factory, Izmir, Turkey contain humic acids over 94%. Compared to the standard, heavy metals content in these materials demonstrate high amounts. Organic carbon content in the composts is very low compared to the leonardite materials and IHSS collection, where the heavy metals content is lower. Biotransformed lignite is characterized with lower content of organic carbon, but humic acids are with high degree of humification. Results obtained show that the fourth studied humus systems may be used in agriculture on base of the high humic acids content. It is recommended to measure heavy metals content before applying the materials in agriculture.

Effects of Soil Management on Changes of Soil Carbon Content in Alluvial Paddy Soil

Effects of soil management on carbon content in alluvial paddy were investigated using past soil survey data of Niigata prefecture, Japan. The changes of soil management were as follows： （1） slight decrease in nitrogen and phosphate fertilizer application rates; （2） decrease to half in the application of soil amendments, like calcium silicate; （3） decrease in compost application and increase in rice straw application; （4） increase in pipe drainage. In spite of these changes, negligible change of carbon content in the plow-layer of alluvial paddy soils had been observed for past 25 years. However, without rice straw application and paddy-upland rotations, the soil carbon content had been decreased. Carbon content of alluvial paddy soils classified into Gley Lowland soil （Fluvisol or Gleysol） at the depth of 0-30 cm was calculated about 49-103 g-kg＂1 and gross carbon sequestration was calculated 7.68 Mt in the paddy field soils in Niigata prefecture.

Heavy Metal Pollution of Sediments from Coastal Areas： Assessment of the Environmental Impact of Polluted Surface Sediments from the Bay of Luanda, Angola

Luanda bay has been acting as a sink for the untreated municipal and industrial effluents from a part of the city. Sediment samples were analyzed for their total organic carbon contents and pseudo-total concentrations ofFe, Mn, Hg, Cd, Pb, Cu, Zn, Ni and Cr The highest concentrations of organic carbon and Hg, Cd, Pb, Cu and Zn were found near the sewerage discharge outlets, exceeding in these points the lowest Sediment Quality Guidelines for the occurrence of adverse biological effects. A further study, based on the latest version of the BCR sequential extraction procedure, was undertaken in order to assess the physical/chemical binding and bioavailability ofFe, Mn, Cd, Pb, Cu and Zn in these sediments. The toxic metals Cd, Zn, Pb and Cu pose a potential environmental risk, because they were extracted from the sediment labile fractions in concentrations that exceeded the corresponding ERL （Effects Range Low） values, entering the range within which adverse biological effects occur. The non-residual fractions of metals ranged from 91 to 100% for Cd, 89 to 94% for Zn, 67 to 100% for Pb, 71 to 82% for Cu, 30 to 77% for Mn and 39 to 48% for Fe. Measures to be taken for the disposal of the polluted dredged sediments are shown in this work.