Inorganic-organic hybrid materials are promising for application in the field of photocatalysis because of their excellent properties.Therefore,their syntheses,mechanisms,and applications are reviewed in this paper.Fi...Inorganic-organic hybrid materials are promising for application in the field of photocatalysis because of their excellent properties.Therefore,their syntheses,mechanisms,and applications are reviewed in this paper.First,we introduce the role of inorganic-organic photocatalysts,their advantages and disadvantages,and their design principles.Second,we present the top-down and bottom-up synthesis methods of the hybrid materials.The interaction between inorganic and organic components in hybrid materials is discussed,followed by how to improve inorganic-organic photocatalysts.Third,the applications of hybrid materials in the field of photocatalysis,such as realizing hydrogen evolution,organic pollutant degradation,heavy metals and CO_(2) reduction,sterilization,and nitrogen fixation,are examined.Finally,the application prospects and development directions of inorganic-organic hybrid materials are explored and the unsolved problems are described.展开更多
This paper is a result of a review through 25 papers on the synthesis of three-, four-, five-, six-, and seven-membered rings on solid support. Solid-phase organic synthesis methods that enable the rapid production of...This paper is a result of a review through 25 papers on the synthesis of three-, four-, five-, six-, and seven-membered rings on solid support. Solid-phase organic synthesis methods that enable the rapid production of arrays of heterocycles are of critical importance to the pharmaceutical industry. The generation of heterocyclic chemistry by solid-phase synthesis will definitely accelerate the development of pharmaceutical research.展开更多
文摘Inorganic-organic hybrid materials are promising for application in the field of photocatalysis because of their excellent properties.Therefore,their syntheses,mechanisms,and applications are reviewed in this paper.First,we introduce the role of inorganic-organic photocatalysts,their advantages and disadvantages,and their design principles.Second,we present the top-down and bottom-up synthesis methods of the hybrid materials.The interaction between inorganic and organic components in hybrid materials is discussed,followed by how to improve inorganic-organic photocatalysts.Third,the applications of hybrid materials in the field of photocatalysis,such as realizing hydrogen evolution,organic pollutant degradation,heavy metals and CO_(2) reduction,sterilization,and nitrogen fixation,are examined.Finally,the application prospects and development directions of inorganic-organic hybrid materials are explored and the unsolved problems are described.
文摘This paper is a result of a review through 25 papers on the synthesis of three-, four-, five-, six-, and seven-membered rings on solid support. Solid-phase organic synthesis methods that enable the rapid production of arrays of heterocycles are of critical importance to the pharmaceutical industry. The generation of heterocyclic chemistry by solid-phase synthesis will definitely accelerate the development of pharmaceutical research.
