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固相萃取-气相色谱法检测烟叶中18种有机氯类杀虫剂残留 被引量:1
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作者 方敦煌 宋春满 雷丽萍 《安徽农业科学》 CAS 2012年第32期15699-15700,共2页
[目的]建立固相萃取-气相色谱法检测烟草中18种有机氯类杀虫剂多残留检测分析方法。[方法]烟草样品经正己烷超声提取、Florisil固相萃取柱净化后,用气相色谱电子捕获检测器(ECD)进行有机氯类杀虫剂残留检测。[结果]在0.05~0.50μg/g浓... [目的]建立固相萃取-气相色谱法检测烟草中18种有机氯类杀虫剂多残留检测分析方法。[方法]烟草样品经正己烷超声提取、Florisil固相萃取柱净化后,用气相色谱电子捕获检测器(ECD)进行有机氯类杀虫剂残留检测。[结果]在0.05~0.50μg/g浓度范围内,18种有机氯类杀虫剂的线性关系良好,回收率在81.82%~101.50%,相对标准偏差为1.95%~4.56%(n=6),检测限均为0.01μg/g。[结论]该方法灵敏、快速、简便,适用于烟叶中有机氯类杀虫剂多残留分析。 展开更多
关键词 固相萃取 气相色谱法 有机氯类杀虫剂 烟叶
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常见杀虫剂的分类与科学选用 被引量:3
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作者 张默 《河北果树》 2001年第1期33-34,共2页
关键词 杀虫剂 选用 有机杀虫剂 有机氯类杀虫剂 氨基甲酸酯杀虫剂 沙蚕毒素杀虫剂 拟除虫菊酯杀虫剂 特异性昆虫生长调节剂 苯甲酰脲杀虫剂 生物源杀虫剂
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三七中农药残留联合健康风险评估 被引量:6
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作者 孙悦 王凯迪 +5 位作者 诸寅 苗水 保聪 蔡强 季申 赵远 《环境化学》 CAS CSCD 北大核心 2022年第7期2234-2244,共11页
研究三七中农药残留对人体的联合健康风险。针对出自文山平坝、云南曲靖等不同产地的51个三七样品进行农药残留检测,利用相对毒效因子法将各值与其相对应的残留限量值和安全指导值等结合进行联合健康风险评估,并将结果利用@risk 7.5软... 研究三七中农药残留对人体的联合健康风险。针对出自文山平坝、云南曲靖等不同产地的51个三七样品进行农药残留检测,利用相对毒效因子法将各值与其相对应的残留限量值和安全指导值等结合进行联合健康风险评估,并将结果利用@risk 7.5软件进行迭代。结果表明,检测的51个三七样本中,烯酰吗啉的检出率为100%,腐霉利、毒死蜱和吡唑醚菊酯的检出率均大于90%。针对联合毒性风险而言,三七中有机氯类杀虫剂和酰胺类杀菌剂农药残留对人体存在一定的健康风险,有机磷类、蜕皮激素类杀虫剂和噁唑类、有机氯类杀菌剂对人体存在潜在风险。有机氯类杀虫剂中,贡献水平最高的为狄氏剂,为18.66%,其次为七氯、环氧七氯和艾氏剂,分别占该类别累计暴露的15.99%、15.99%和13.33%,其余的均低于10%。酰胺类杀菌剂中,烯酰吗啉的贡献率最高,高达99.79%。居民长期服用三七存在一定的健康风险,需对烯酰吗啉的残留引起重视,且针对有机氯类杀虫剂建议加强农药污染土壤的修复。 展开更多
关键词 有机氯类杀虫剂 烯酰吗啉 相对毒效因子法 联合健康风险
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Concentrations and distribution of organochlorine pesticides in shellfish from Changjiang estuary 被引量:3
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作者 马继臻 沈新强 +1 位作者 袁骐 蒋玫 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2008年第4期388-393,共6页
To analyze and evaluate the status of organochlorine pollutants in the Changjiang (Yangtze River) estuary and adjacent waters, the concentrations of hexachlorocyclohexane (HCHs) and dichlorodiphenyltrichloroethane... To analyze and evaluate the status of organochlorine pollutants in the Changjiang (Yangtze River) estuary and adjacent waters, the concentrations of hexachlorocyclohexane (HCHs) and dichlorodiphenyltrichloroethane (DDTs) in shellfish collected in study area from 2006 to 2007 were determined with gas chromatography (GC). The concentration range of HCHs was (ND-12.13)×10^-3 mg/kg wet weight and averaged at 0.54×10^-3 mg/kg while the concentration of DDTs was in the range of (4.06-281.73) ×10^-3 mg/kg with a mean of 57.52×10^-3 mg/kg in the survey areas. The concentrations of DDTs in the shellfish were higher than HCHs', so that DDTs could be considered as typical organochlorine pollutants in the areas. The concentrations of DDTs in the shellfish were higher than HCHs', so that DDTs could be considered as typical organochlorines pollutants. The HCHs in all the shellfish conformed to the first level of criterion (0.02 mg/kg) of the Marion Biology Quality (GB 18421-2001), and that of DDTs in most samples were beyond the first level (0.01 mg/kg) but conformed to the second level (0.10 mg/kg). On average, α-HCH and δ-HCH occupied the most part of HCHs, while O,P'-DDT and P,P'-DDT occupied the most part of DDTs. The concentrations of organocholorine pesticides in shellfish samples varied in site and in species. The highest level occurred at the Shengsi (SS), followed by Yangkougang (YKG), Lvsi (LS), Dongyuan (DY) and Beibayao (BBY), low concentrations were observed at Changsha (CS), Beidaodi (BDD), and Gouqi (GQ). The concentration of HCHs and DDTs in most sites decreased clearly from 2006 to 2007 except for YKG, DY, BDD, LYS, and SS. All of above results suggested that the study area was slightly affected by organochlorine pesticide, special by DDTs. 展开更多
关键词 Changjiang (Yangtze River) estuary SHELLFISH organochlorine pesticides residual level
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