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基于离子液体电解液的有机电化学反应 被引量:3
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作者 褚道葆 周莹 +2 位作者 张雪娇 李艳 宋奇 《化学进展》 SCIE CAS CSCD 北大核心 2010年第12期2316-2327,共12页
室温离子液体(RTILs)作为一类在室温时呈液态且具有良好导电性的新型绿色溶剂,在有机电化学反应体系中的应用前景广阔。本文介绍了近年报道过的新型离子液体及离子液体电解液的特性,阐述了基于离子液体电解液的电化学实验方法,重点综述... 室温离子液体(RTILs)作为一类在室温时呈液态且具有良好导电性的新型绿色溶剂,在有机电化学反应体系中的应用前景广阔。本文介绍了近年报道过的新型离子液体及离子液体电解液的特性,阐述了基于离子液体电解液的电化学实验方法,重点综述了离子液体中的各种有机电化学反应,包括电化学还原反应、CO2在离子液体中的电化学固定、电化学氧化反应、烯烃的环氧化、选择性氟化反应、偶联反应、功能化有机硅氧烷的合成、电化学氟化脱硫反应、电化学聚合反应等,并展望了发展趋势。 展开更多
关键词 有机电化学反应 离子液体 电合成 化学方法
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Analysis and design of resistance-wire heater in MOCVD reactor 被引量:1
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作者 曲毓萱 王斌 +5 位作者 胡仕刚 吴笑峰 李志明 唐志军 李劲 胡莹璐 《Journal of Central South University》 SCIE EI CAS 2014年第9期3518-3524,共7页
Metal organic chemical vapor deposition(MOCVD) is a key equipment in the manufacturing of semiconductor optoelectronic devices and microwave devices in industry. Heating system is a vital part of MOCVD. Specific heati... Metal organic chemical vapor deposition(MOCVD) is a key equipment in the manufacturing of semiconductor optoelectronic devices and microwave devices in industry. Heating system is a vital part of MOCVD. Specific heating device and thermal control technology are needed for each new reactor design. By using resistance-wire heating MOCVD reaction chamber model, thermal analysis and structure optimization of the reactor were developed from the vertical position and the distance between coils of the resistance-wire heater. It is indicated that, within a certain range, the average temperature of the graphite susceptor varies linearly with the vertical distance of heater to susceptor, and with the changed distances between the coils; furthermore, single resistance-wire heater should be placed loosely in the internal and tightly in the external. The modulate accuracy of the temperature field approximately equals the change of the average temperature corresponding to the change of the coil position. 展开更多
关键词 metal organic chemical vapor deposition (MOCVD) reactor design thermal analysis filament heating
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