Hydrogen sulphide(H2 S)is a common air pollutant,which is produced in various industry processes.Therefore,it is of crucial importance to detect H2 S in real time.Many fluorescent sensors were reported aiming at detec...Hydrogen sulphide(H2 S)is a common air pollutant,which is produced in various industry processes.Therefore,it is of crucial importance to detect H2 S in real time.Many fluorescent sensors were reported aiming at detecting H2 S in solution;however,the fluorescence sensing of gaseous H2 S has not yet been reported.In this work,we utilized the post-functionalized fluorescent film,MIL-100(In)@Eu3+/Cu2+film,realizing fluorescence turn-on sensing of gaseous H2 S at room temperature for the first time with the limit of detection as low as 0.535 ppm,which is comparable to some reported fluorescent probes for S2-ions and semiconductor based gaseous H2 S sensors.The sensor was designed due to the strong affinity of H2 S with Cu2+.With the formation of CuS,the"antenna effect"between the ligand and Eu3+recovered,resulting in the fluorescence turn-on of Eu3+emission.Additionally,we proposed a new method to realize multi-colour anti-counterfeiting patterns with lanthanide ions ink,taking advantage of the extraordinary smooth surface and uncoordinated carboxylate groups within the MIL-100(In)film.展开更多
基金supported by the National Natural Science Foundation of China(U1609219,51632008,61721005,51432001and 51772268)Zhejiang Provincial Natural Science Foundation(LD18E020001)
文摘Hydrogen sulphide(H2 S)is a common air pollutant,which is produced in various industry processes.Therefore,it is of crucial importance to detect H2 S in real time.Many fluorescent sensors were reported aiming at detecting H2 S in solution;however,the fluorescence sensing of gaseous H2 S has not yet been reported.In this work,we utilized the post-functionalized fluorescent film,MIL-100(In)@Eu3+/Cu2+film,realizing fluorescence turn-on sensing of gaseous H2 S at room temperature for the first time with the limit of detection as low as 0.535 ppm,which is comparable to some reported fluorescent probes for S2-ions and semiconductor based gaseous H2 S sensors.The sensor was designed due to the strong affinity of H2 S with Cu2+.With the formation of CuS,the"antenna effect"between the ligand and Eu3+recovered,resulting in the fluorescence turn-on of Eu3+emission.Additionally,we proposed a new method to realize multi-colour anti-counterfeiting patterns with lanthanide ions ink,taking advantage of the extraordinary smooth surface and uncoordinated carboxylate groups within the MIL-100(In)film.
