The organic gel-thermal reduction process was used for the preparation of ferromagnetic metal Ni, Co and Fe fine fibers from the raw materials of citric acid, lactic acid and metal salts. The structure, thermal decomp...The organic gel-thermal reduction process was used for the preparation of ferromagnetic metal Ni, Co and Fe fine fibers from the raw materials of citric acid, lactic acid and metal salts. The structure, thermal decomposition process and morphologies of the gel precursors and fibers derived from thermal reduction of these gel precursors were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermo-gravimetric/differential scanning calorimetry and scanning electron microscopy. The results show that spinnability of gel largely depends on molecular structure of metal-carboxylate complex that is a linear-type structure formed in the gel. As a result, the gels exhibit a good spinnability. Metal Ni, Co and Fe fine fibers are featured with diameters of around 1 μm and a high aspect ratio up to 1×106.展开更多
Permanent magnets with high energy products are widely used in a variety of electromagnetic devices. Such devices can be found in marine, aerospace, and robotic applications which require the minimization of weight an...Permanent magnets with high energy products are widely used in a variety of electromagnetic devices. Such devices can be found in marine, aerospace, and robotic applications which require the minimization of weight and volume of the electromagnetic device. During the magnetizing process, the magnet may not be perfectly magnetized. Therefore, it needs to be demagnetized. Because of high coercivity of some permanent magnets, the demagnetization process requires the intense magnetic fields in close proximity with the magnetic material. The fields must be produced for a short period of time （millisecond range） and they also must be bidirectional in order to overcome the coercivity of magnetic material. Different parameters have been known to affect the demagnetizer operation such as the core shape, core material, turn number, cross section of air gap, magnet type and so on. The amplitude and waveform of the fixture current is obtained from PSPICE simulations and also from experimental measurement. A 2D finite element analysis is developed to simulate the magnetic fields and the mechanical forces. In this paper, the main parameters affecting the optimal design of the demagnetizer are discussed. Simulation results show that the core structure, air gap width, and turn numbers are the most important parameters when designing such a device.展开更多
Organic spintronics refers to control spin dependent transport through organic materials.In the last two decades,extraordinary development has been achieved for organic-spintronics.A series of theoretical and experime...Organic spintronics refers to control spin dependent transport through organic materials.In the last two decades,extraordinary development has been achieved for organic-spintronics.A series of theoretical and experimental studies have been done to reveal the mechanisms of spin dependent transport properties.The theoretical analysis is based on the non-equilibrium Green's function formalism provides a mathematical framework for solving the transmission coefficients in the Landauer formula from atomistic first principles without any phenomenological parameters.In this article,we provide a brief theoretical review on organic spintronics devices and device physics therein.展开更多
Advanced electromagnetic(EM)wave absorbing materials with strong absorption and broad bandwidth are important for military stealth and elimination of microwave pollution in consumers’electronics.Metal organic framewo...Advanced electromagnetic(EM)wave absorbing materials with strong absorption and broad bandwidth are important for military stealth and elimination of microwave pollution in consumers’electronics.Metal organic framework(MOF)-derived metal/carbon hybrids with ordered structure are significantly urgent in this field.In this contribution,we presented a design strategy of hollow cage-like or solid box-like magnetic/dielectric Fe/Co/C and dielectric Fe/Mn/C EM wave absorbing nanomaterials via pyrolyzing Prussian blue’s analogs with controllable topology and phase composition.The solid box-like Fe/Co/C and hollow cage-like Fe/Mn/C showed favorable absorption property with a broad effective absorption bandwidth(EAB)and a low reflection loss(RL).Especially,the EAB of 8.8 GHz at a thickness of 2.5 mm for solid box-like Fe/Co/C nanocomplex prepared at 900℃is a new record for this type of materials.The design and tuning strategy for EM wave absorbers derived from topology-controllable MOF is important for EM functional materials possessing great potential in military stealth and consumers’electronics.展开更多
In the past three decades, molecular magnetism has been a rapidly growing interdisciplinary field in chemistry, phys- ics and materials sciences. It covers diverse range of topics including inorganic/organic/hybrid ma...In the past three decades, molecular magnetism has been a rapidly growing interdisciplinary field in chemistry, phys- ics and materials sciences. It covers diverse range of topics including inorganic/organic/hybrid magnetic molecular ma- terials, multifunctional and/or switchable magnetic molecu- lar materials, molecular nanomagnets, nanostructural mo- lecular magnets, molecular spintronics and biomagnetism. Much research on molecular magnetism has been carried out in China both before and after we organized the Interna- tional Conference on Molecule-Based Magnets 2010 （ICMM 2010） in Beijing.展开更多
基金Projects(50474038 50674048) supported by the National Natural Science Foundation of China
文摘The organic gel-thermal reduction process was used for the preparation of ferromagnetic metal Ni, Co and Fe fine fibers from the raw materials of citric acid, lactic acid and metal salts. The structure, thermal decomposition process and morphologies of the gel precursors and fibers derived from thermal reduction of these gel precursors were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermo-gravimetric/differential scanning calorimetry and scanning electron microscopy. The results show that spinnability of gel largely depends on molecular structure of metal-carboxylate complex that is a linear-type structure formed in the gel. As a result, the gels exhibit a good spinnability. Metal Ni, Co and Fe fine fibers are featured with diameters of around 1 μm and a high aspect ratio up to 1×106.
文摘Permanent magnets with high energy products are widely used in a variety of electromagnetic devices. Such devices can be found in marine, aerospace, and robotic applications which require the minimization of weight and volume of the electromagnetic device. During the magnetizing process, the magnet may not be perfectly magnetized. Therefore, it needs to be demagnetized. Because of high coercivity of some permanent magnets, the demagnetization process requires the intense magnetic fields in close proximity with the magnetic material. The fields must be produced for a short period of time （millisecond range） and they also must be bidirectional in order to overcome the coercivity of magnetic material. Different parameters have been known to affect the demagnetizer operation such as the core shape, core material, turn number, cross section of air gap, magnet type and so on. The amplitude and waveform of the fixture current is obtained from PSPICE simulations and also from experimental measurement. A 2D finite element analysis is developed to simulate the magnetic fields and the mechanical forces. In this paper, the main parameters affecting the optimal design of the demagnetizer are discussed. Simulation results show that the core structure, air gap width, and turn numbers are the most important parameters when designing such a device.
基金supported by the State Key Project of Fundamental Research of the Ministry of Science and Technology(Grant No. 2010CB934400)the National Natural Science Foundation of China (Grant Nos.11104338,10934099,and 51021061)+1 种基金the International Collaborative Research Programs between NSFC and EPSRC of the United Kingdom(Grant No.10911130234)between NSFC and ANR of France(Grant No.F040803)
文摘Organic spintronics refers to control spin dependent transport through organic materials.In the last two decades,extraordinary development has been achieved for organic-spintronics.A series of theoretical and experimental studies have been done to reveal the mechanisms of spin dependent transport properties.The theoretical analysis is based on the non-equilibrium Green's function formalism provides a mathematical framework for solving the transmission coefficients in the Landauer formula from atomistic first principles without any phenomenological parameters.In this article,we provide a brief theoretical review on organic spintronics devices and device physics therein.
基金This work was financially supported by the National Natural Science Foundation of China(21875190)Polymer Electromagnetic Functional Materials Innovation Team of Shaanxi Sanqin Scholars,the Natural Science Basic Research Plan in Shaanxi Province of Distinguished Young Scholar(2018JC-008)China Postdoctoral Science Foundation(2018M643724).
文摘Advanced electromagnetic(EM)wave absorbing materials with strong absorption and broad bandwidth are important for military stealth and elimination of microwave pollution in consumers’electronics.Metal organic framework(MOF)-derived metal/carbon hybrids with ordered structure are significantly urgent in this field.In this contribution,we presented a design strategy of hollow cage-like or solid box-like magnetic/dielectric Fe/Co/C and dielectric Fe/Mn/C EM wave absorbing nanomaterials via pyrolyzing Prussian blue’s analogs with controllable topology and phase composition.The solid box-like Fe/Co/C and hollow cage-like Fe/Mn/C showed favorable absorption property with a broad effective absorption bandwidth(EAB)and a low reflection loss(RL).Especially,the EAB of 8.8 GHz at a thickness of 2.5 mm for solid box-like Fe/Co/C nanocomplex prepared at 900℃is a new record for this type of materials.The design and tuning strategy for EM wave absorbers derived from topology-controllable MOF is important for EM functional materials possessing great potential in military stealth and consumers’electronics.
文摘In the past three decades, molecular magnetism has been a rapidly growing interdisciplinary field in chemistry, phys- ics and materials sciences. It covers diverse range of topics including inorganic/organic/hybrid magnetic molecular ma- terials, multifunctional and/or switchable magnetic molecu- lar materials, molecular nanomagnets, nanostructural mo- lecular magnets, molecular spintronics and biomagnetism. Much research on molecular magnetism has been carried out in China both before and after we organized the Interna- tional Conference on Molecule-Based Magnets 2010 （ICMM 2010） in Beijing.
