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有机无机(RNH_3)_2CuBr_4系列晶体的合成及结构表征
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作者 王亚珍 余翔 《分析仪器》 CAS 2011年第3期75-79,共5页
本文以溴化铜(CuBr2)为主要研究对象,通过变换有机组元并采用分步合成法制备了三种结构相似的层状类钙钛矿结构的晶体化合物。用扫描电子显微镜(SEM)、X射线衍射分析(XRD)和红外光谱(FTIR)分别对三种晶体的无机组元、有机组元和晶体结... 本文以溴化铜(CuBr2)为主要研究对象,通过变换有机组元并采用分步合成法制备了三种结构相似的层状类钙钛矿结构的晶体化合物。用扫描电子显微镜(SEM)、X射线衍射分析(XRD)和红外光谱(FTIR)分别对三种晶体的无机组元、有机组元和晶体结构进行了详细分析和探讨。实验结果均表明,当有机组元为丙胺和丁胺时,层状结构非常明显,而当有机组元为苯胺时,层状结构略差。这种层状结构的形成与有机组元的碳链长短和是否有苯环结构相关联,由于有机无机组元间主要是以分子间力(主要是氢键)相结合,因此有机组元的结构对层状材料的形成至关重要。 展开更多
关键词 溴化铜 有机组元 层状类钙钛矿 合成与表征
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Extraction and Characterization of Humic Acids and Humin Fractions from a Black Soil of China 被引量:47
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作者 XINGBao-Shan LIUJu-Dong +1 位作者 LIUXiao-Bing HANXiao-Zeng 《Pedosphere》 SCIE CAS CSCD 2005年第1期1-8,共8页
Twenty-three progressive extractions were performed to study individual humic acids (HAs) and humin fractions from a typical black soil (Mollisol) in Heilongjiang Province, China using elemental analysis and spectrosc... Twenty-three progressive extractions were performed to study individual humic acids (HAs) and humin fractions from a typical black soil (Mollisol) in Heilongjiang Province, China using elemental analysis and spectroscopic techniques. After 23 HA extractions the residue was separated into high and low organic carbon humin fractions. HA yield was the highest for the first extraction and then gradually decreased with further extractions. Organic carbon (OC) of the humin fractions accounted for 58% of total OC … 展开更多
关键词 elemental composition humic acid HUMIN soil organic matter spectroscopic analysis
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Effect of Exogenous Organic Matter Application on Soil and Plant Elemental Composition in Pot Experiments
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作者 Eubica Pospislova Magdalena Habova +2 位作者 Eva Dolezelova Ida Drapelova Veronika Renciukova 《Journal of Life Sciences》 2016年第3期153-160,共8页
Content of macro- and microelements in plant and soil was studied after biochar, compost, digestate, lignite, and lignohumate application. Pot experiments were carried out in Phytotron CLF Plant Master (Wertingen, Ge... Content of macro- and microelements in plant and soil was studied after biochar, compost, digestate, lignite, and lignohumate application. Pot experiments were carried out in Phytotron CLF Plant Master (Wertingen, Germany). As tested plant lettuce (Lactucasativa) was used. Elemental composition was determined by AAS and XRF spectroscopy. Macronutrients content (Ca, Mg, K, and P) was determined by Mehlich III. Total content of carbon and nitrogen were determined by LECO TruSpec CN analyser. Results showed that different exogenous organic amendments statistically significantly influenced macro and micronutrients content in soil and plant. Satisfactory C/N ratio for soil microorganisms was measured only after compost and digestate application. As concerns hazardous elements, no legislation limits were overstepped after application of the tested organic amendments. Bioavailability and their uptake by plants followed the order: Cd 〉 Mn 〉 Zn 〉 Fe. 展开更多
关键词 Haplic Cambisol macro and micro elements AAS XRF spectroscopy.
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Dynamic Simulation of Novel Small Wind Turbine Generation System with SynRG
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作者 Shohei Tokunaga Katsumi Kesamaru 《Journal of Energy and Power Engineering》 2012年第10期1611-1618,共8页
This paper describes a small wind turbine generation system with SynRG (synchronous reluctance generator). SynRGs are robust and inexpensive. In addition, SynRG has no cogging torque. Hence, wind turbine generation ... This paper describes a small wind turbine generation system with SynRG (synchronous reluctance generator). SynRGs are robust and inexpensive. In addition, SynRG has no cogging torque. Hence, wind turbine generation system with SynRG can achieve smooth start at low wind velocity. The rotor design of proposed SynRG is multi flux barrier type. With FEA (finite element analysis) software, the characteristics of SynRG are brought out, and the performance of wind turbine generation system with SynRG including copper loss and iron loss is simulated by FEA coupled with the motion equation of the wind turbine generation system under the maximum power point tracking control. In this paper, the constant wind test and the quasi-natural wind test are conducted. In conclusion, the results of these simulations indicate that the wind turbine generation system with SynRG has good performance, especially in starting phenomena. 展开更多
关键词 Small wind turbine generation system wind turbine generator SynRG (synchronous reluctance generator) finite element analysis coupled analysis.
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Numerical simulation of cutting process of the slice components cutting machine
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作者 索来春 刘平平 +1 位作者 王晓群 苏健 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2010年第1期127-130,共4页
By the use of ANSYS/LS-DYNA FEA software,numerical simulation on the cutting process of cutting plates with a reamer was carried out in the paper. The logical improvement was brought forward and the phenomenon of stre... By the use of ANSYS/LS-DYNA FEA software,numerical simulation on the cutting process of cutting plates with a reamer was carried out in the paper. The logical improvement was brought forward and the phenomenon of stress concentration was deceased by weighted analysis. The effects of different cut velocities and cutting thickness on life-spans of reamers were investigated, and the cutting parameters were optimized to satisfy the cutting precision and cutting efficiency. The study will provide a guide for the practical production. 展开更多
关键词 cutting process numerical simulation stress cutting parameters
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Simulation of solidification microstructure of Fe-6.5%Si alloy using cellular automaton-finite element method
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作者 SONG Wei ZHANG Jiong-ming +2 位作者 WANG Shtm-xi WANG Bo HAN Li-lei 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第9期2156-2164,共9页
3D microstructures of Fe–6.5%Si(mass fraction) alloys prepared under different cooling conditions were simulated via finite element-cellular automaton(CAFE) method. The simulated results were compared to experimental... 3D microstructures of Fe–6.5%Si(mass fraction) alloys prepared under different cooling conditions were simulated via finite element-cellular automaton(CAFE) method. The simulated results were compared to experimental results and found to be in accordance. Variations in the temperature field and solid-liquid region, which plays important roles in determining solidification structures, were also examined under various cooling conditions. The proposed model was utilized to determine the effects of Gaussian distribution parameters to find that the lower the mean undercooling, the higher the equiaxed crystal zone ratio; also, the larger the maximum nucleation density, the smaller the grain size. The influence of superheat on solidification structure and columnar to equiaxed transition(CET) in the cast ingot was also investigated to find that decrease in superheat from 52 K to 20 K causes the equiaxed crystal zone ratio to increase from 58.13% to 65.6%, the mean gain radius to decrease from 2.102 mm to 1.871 mm, and the CET to occur ahead of schedule. To this effect, low superheat casting is beneficial to obtain finer equiaxed gains and higher equiaxed dendrite zone ratio in Fe–6.5%Si alloy cast ingots. 展开更多
关键词 finite element-cellular automaton Fe-6.5%Si alloy MICROSTRUCTURE temperature field Gaussian distribution parameters
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