A new and simple microwave-assisted alkaline degradation （MAAD） method for the elimination of organoehlorine-pesticide interference on the determination of polychlorinated biphenyls （PCBs） in soil by GC is present...A new and simple microwave-assisted alkaline degradation （MAAD） method for the elimination of organoehlorine-pesticide interference on the determination of polychlorinated biphenyls （PCBs） in soil by GC is presented. Under the optimal conditions, the interference of α- HCH, β- HCH, γ -HCH,δ -HCH, o. p＇ - DDT, p. p＇ - DDD and p. p＇ - DDT could be eliminated completely, and p. p＇ - DDE, Aldrin and Dieldrin could be partially eliminated; however, Dieldrin could be completely eliminated by using concentrated sulphurie acid. The method was evaluated by analyzing the spiked-soil sample. The mean recovery obtained was 84. 1% and the Relative Standard Deviation （RSD） was 2. 7%. Experimental results also indicate that the degradation of the interference and the extraction of the target analytes, PCBs, could be carried out simuhaneously. Compared with the traditional methods, the MAAD method is a rapid, efficient and solvent-saving method,展开更多
Climate change is the main problem of mankind, especially because of it＇s increasing speed and by specialists＇ forecast the situation will become worse. Climatic changes are correlated with the degradation of biosph...Climate change is the main problem of mankind, especially because of it＇s increasing speed and by specialists＇ forecast the situation will become worse. Climatic changes are correlated with the degradation of biosphere. It is a question of saving life on authors planet. The authors should begin taking strong measures, else Earth has a chance to repeat the destiny of Mars and Venus, as some scientists are afraid of. So reasoning like ＂When will it be and will it be at all＂ is for lazy, careless and selfish people. Now, because of the industrial emission of greenhouse gases, the temperature of the atmosphere is growing, the climate is changing： sudden temperature differences, snowfalls where it used to be impossible, thickness of arctic ice decrease is about 40% （a great ice-hole has been found on the north pole）, repetition of droughts has increased in 8 times, power of hurricanes-2 times, increased power of floods. This is the result of lack of foresight, over-materialism and greediness, unwillingness to see the consequences because of the momentary advantages. How it is possible to trap CO2, SO2 and other gases？ Commercially gas purification at thermoelectric power stations, ferrous and non-ferrous metallurgy plants, cement and chemical plants is being made with filters and cyclones that trap solid parts, and using different absorptive and adsorptive methods. Unfortunately at present there is no effective method of COE trapping.展开更多
基金Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholar State Education Ministry (Grant No.415409) and the Scien-tific Research Foundation for Doctors, Guangdong Natural Science Foundation (Grant No.974078).
文摘A new and simple microwave-assisted alkaline degradation （MAAD） method for the elimination of organoehlorine-pesticide interference on the determination of polychlorinated biphenyls （PCBs） in soil by GC is presented. Under the optimal conditions, the interference of α- HCH, β- HCH, γ -HCH,δ -HCH, o. p＇ - DDT, p. p＇ - DDD and p. p＇ - DDT could be eliminated completely, and p. p＇ - DDE, Aldrin and Dieldrin could be partially eliminated; however, Dieldrin could be completely eliminated by using concentrated sulphurie acid. The method was evaluated by analyzing the spiked-soil sample. The mean recovery obtained was 84. 1% and the Relative Standard Deviation （RSD） was 2. 7%. Experimental results also indicate that the degradation of the interference and the extraction of the target analytes, PCBs, could be carried out simuhaneously. Compared with the traditional methods, the MAAD method is a rapid, efficient and solvent-saving method,
文摘Climate change is the main problem of mankind, especially because of it＇s increasing speed and by specialists＇ forecast the situation will become worse. Climatic changes are correlated with the degradation of biosphere. It is a question of saving life on authors planet. The authors should begin taking strong measures, else Earth has a chance to repeat the destiny of Mars and Venus, as some scientists are afraid of. So reasoning like ＂When will it be and will it be at all＂ is for lazy, careless and selfish people. Now, because of the industrial emission of greenhouse gases, the temperature of the atmosphere is growing, the climate is changing： sudden temperature differences, snowfalls where it used to be impossible, thickness of arctic ice decrease is about 40% （a great ice-hole has been found on the north pole）, repetition of droughts has increased in 8 times, power of hurricanes-2 times, increased power of floods. This is the result of lack of foresight, over-materialism and greediness, unwillingness to see the consequences because of the momentary advantages. How it is possible to trap CO2, SO2 and other gases？ Commercially gas purification at thermoelectric power stations, ferrous and non-ferrous metallurgy plants, cement and chemical plants is being made with filters and cyclones that trap solid parts, and using different absorptive and adsorptive methods. Unfortunately at present there is no effective method of COE trapping.
