基于潮流有解充分条件的新能源场站静态电压稳定评估方法

由于电流限幅等因素导致新能源电压支撑能力较弱,场站静态电压稳定风险较高,而现有的分析结果缺乏直观性。对此,提出一种基于潮流有解充分条件的新能源场站静态电压稳定分析方法,通过求解场站外电网平衡节点最小电压幅值来判断新能源场站潮流解的存在性和电压稳定性。首先,针对单机无穷大系统静态电压稳定问题,利用平衡节点最小电压解析解分析了新能源变流器外部电压幅值对最大传输功率的影响;其次,针对辐射状的多机系统静态电压稳定问题,利用Distflow潮流模型及其凸松弛形式计算外电网平衡节点电压幅值的下限,以此确定静态电压稳定裕度。所提方法能够提供维持新能源场站静态电压稳定的最小外电网等值电压幅值,在实际运行中可通过比较外电网等值电压和所计算的最小等值电压高效评估系统静态电压稳定性。

N数码问题直接解及优化研究

对于N数码问题,一般解法都使用搜索算法,但是由于其搜索空间巨大,虽然已经应用并改进了很多的搜索方法[1-4],求解的效率一般仍然很低。对于24数码问题,一般搜索方法通常至少需要十分钟以上[5]。更高阶数码搜索时间会呈指数增加,而且往往得不到解。提出N数码问题有解性判定并对有解的问题给出一种直接解法。解法能在很短时间内给出N数码的一个解,不过这个解通常不是最优解。然后再使用搜索算法,以直接解来改变搜索方向,使搜索算法更快收敛于一个较优解。最后通过实验验证算法的有效性。

Decomposition of Different Organic Materials and Variation of Active Organic Carbon and Nitrogen Contents in Tobacco-planted Soil

The oilseed cake, vetch, rapeseed straw, wheat straw and corn straw were buried in tobacco-planted soil. The decomposition rates, the variation of active organic C and N contents in the residues and the relationship between active organic C and N contents and decomposition rate were investigated. The results showed the decomposition rates of different organic materials were all high in the early period and then low in the late period. Among the organic materials, the decomposition rates ranked as oilseed cake 〉 vetch 〉 wheat straw and rapeseed straw 〉 corn straw. The decomposition rate was positively related to total N content （P〈0.01）, but was negatively related to the active organic C/N ratio （P〈0.01）. However, there was no significant relationship between decomposition ratio and active organic C content. With the proceeding of decomposition, the active organic C content and the total N content in rapeseed straw, vetch, wheat straw and corn straw all trended to increase, but the active organic C/N ratio trended to decrease. However, the variation of active organic C content, total N content and active organic C/N ratio in oilseed cake was on the contrary.

三阶非线性模糊差分方程动力学行为分析

研究一类三阶非线性模糊差分方程正解的存在性及渐近行为xn+1=xn-2/A+xn-2xn-1xn,n=0,1,…其中(xn)是正模糊数数列,A及初始值x-2,x-1,x0是正模糊数.最后给出数值例子以验证理论结论的正确性.

On the Existence of Periodic Solutions of a Class Nonlinear Differential Systems

One method to show the existence of ω-periodic system is given. This method is based on the ultimately boundedness of the solution of the systems. By using comparing theorem and discussing some one dimensional equations the main results are obtained.

Ozonation and Biodegradability of Lignin in Water

To convert the non biodegradable sodium lignin sulfonate into biodegradable substances, the sodium lignin sulfonate in the water was ozonized and the pH value, dissolved organic carbon(DOC), ultraviolet absorbency at λ =254 nm(UVA) and the biodegradability of the ozonation effluent were measured. The non biodegradable sodium lignin sulfonate can be partly converted into biodegradable substances by ozonation (about 38 76%). In the ozonation process, there is little DOC decrease, but much UVA decrease and obvious pH drop.

一种交直流混联电力系统潮流计算的研究

高压直流输电与传统交流输电相比,有着跨区域远距离输电、系统间非同步互联等方面的优势。由于输电性质的不同,系统分析对象就由纯交流系统发展为交直流混联电力系统,分析理论也应在原有的交流理论上修正。对交直流混联电力系统的潮流计算进行研究,基于线性N维空间有解性原理,提出扩展变量法扩展交流系统雅可比矩阵,使直流系统和交流系统统一联立,求解交直流系统的潮流参数。

Lagrangian stability of a class of second-order periodic systems with nonlinear damping term

By the iteration of the KAM, the following second- order differential equation （ Фp （x′））′ ＋ F（x, x′, t） ＋ ω^PФp （x′） ＋α│x│^l ＋e（x, t） =0 is studied, where Фp（S） = │S│^p-2s, p 〉 1, α〉 0 and ω 〉 0 are positive constants, and l satisfies - 1 〈ω 〈p ＋ 2. Under some assumptions on the parities of F（x, x′, t） and e （x, t）, by a small twist theorem of reversible mapping, the existence of quasi-periodic solutions and boundedness of all the solutions are obtained.

Preparation of porous Mg electrode by electrodeposition

In order to obtain a porous Mg electrode with a stable skeleton, organic Mg fuel cell （OMFC）, the electrochemical behavior of Mg deposition on Cu and Ni metallic substrates in 1 mol/L EtMgBr/THF solution was investigated by SEM, EDS and electrochemical methods. The experimental results show that Mg can be electrodeposited on both substrates, as a continuous layer on a Cu substrate. Accordingly, an approach for producing a porous Mg electrode with a stable skeleton of OMFC was proposed by means of electrodeposition of Mg on a foamed Ni substrate with a layer of Cu pre-plating. The discharge performance of this porous Mg electrode of OMFC is superior to that of a planar Mg electrode.

Effect of Dissolved Organic Matter on Chlorotoluron Sorption and Desorption in Soils

A batch equilibrium techniques was used to examine the effect of dissolved organic matter （DOM） extracted from both non-treated sludge （NTS） and heat-expanded sludge （HES） on the sorption and desorption of chlorotoluron （3-（3-chloro-p-tolyl）-1,1-dimethylurea） in two types of soils, a yellow fluvo-aquic and a red soil from China. Without DOM,sorption of chlorotoluron was significantly greater （P 〈 0.05） in the red soil than in the yellow fluvo-aquic soil. However,with DOM the effect was dependent on the soil type and nature of DOM. Chlorotoluron sorption was lower in the yellow fluvo-aquic soil than in the red soil, suggesting that with the same DOM levels the yellow fluvo-aquic soil had a lower sorption capacity for this herbicide. Application of DOM from both NTS and HES led to a general decrease in sorption to the soils and an increase in desorption from the soils. Desorption of chlorotoluron also significantly increased （P 〈 0.05） with an increase in the DOM concentration. Additionally, for sorption and desorption, at each DOM treatment level the NTS treatments were significantly lower （P 〈 0.05） than the HES treatments. This implied that non-treated sludge had a greater effect on the sorption and desorption of chlorotoluron than heat-expanded sludge.

A high performance non-noble metal electrocatalyst for the oxygen reduction reaction derived from a metal organic framework

The development of a non-precious metal electrocatalyst （NPME） with a performance superior to commercial Pt/C for the oxygen reduction reaction （ORR） is important for the commercialization of fuel cells. We report the synthesis of a NPME by heat-treating Co-based metal organic frameworks （ZIF-67） with a small average size of 44 nm. The electrocatalyst pyrolyzed at 600 ~C showed the best performance and the performance was enhanced when it was supported on BP 2000. The resulting electrocatalyst was composed of 10 nm Co nanoparticles coated by 3-12 layers of N doped graphite layers which as a whole was embedded in a carbon matrix. The ORR performance of the electrocatalyst was tested by rotating disk electrode tests in O2-saturated 0.1 mol/L KOH under ambient conditions. The electrocatalyst （1.0 mg/cm~] showed an onset potential of 1.017 V （[vs. RHE] and a half-wave potential of 0.857 V （vs. RHE], which showed it was as good as the commer- cial Pt/C （20 BgPt/cm2）. Furthermore, the electrocatalyst possessed much better stability and re- sistance to methanol crossover than Pt/C.

Design of metal-organic frameworks(MOFs)-based photocatalyst for solar fuel production and photo-degradation of pollutants

Metal organic frameworks(MOFs)is a research hotspot in the solar fuel production and photo-degradation of pollutants field due to high surface area,rich metal/organic species,large pore volume,and adjustability of structures and compositions.Therefore,in this review,we first summarized the design factors of photocatalytic materials based on MOF from the perspective of"star"MOF.The modification strategies of MOFs-based photocatalysts were discussed to improve its photocatalytic activity and specific applications were summarized as well,including photocatalytic CO_(2)reduction,photocatalytic water splitting and photo-degradation of pollutants.Finally,the advantages and disadvantages of MOFs-based photocatalysts were discussed,the current challenges were highlighted,and suggestions for future research directions were proposed.

Characteristics of Phosphorous Adsorption and Desorption by Organo-Mineral Colloidal Complexes of Purple Paddy Soils

The kinetic characteristics of P adsorption and desorption by organo-mineral colloidal complexes (OMC)were studied using acid, calcareous and neutral purple paddy soils taken from Chongqing and Sichuan, China.The results showed that the P adsorption capacity of the organo-mineral colloidal complexes differed with the soil types, being higher for the acid and calcareous purple soils than for the neutral purple soils. Partial removal of the organic matter increased the adsorption capacity of the colloidal complexes. A very significant positive correlation was found between the amounts of P desorbed from OMC and the P saturation degrees.The P adsorption reaction was quick at the early stage and slowed later. The raise of temperature increased P adsorption capacity and P adsorption rate of the colloidal complexes. The adsorption processes could be described by the Elovich equation.

Recent developments in the use of single-atom catalysts for water splitting

Electrochemical water splitting is regarded as the most promising approach to produce hydrogen.However,the sluggish electrochemical reactions occurring at the anode and cathode,namely,the oxygen evolution reaction(OER)and the hydrogen evolution reaction(HER),respectively,consume a tremendous amount of energy,seriously hampering its wide application.Recently,single-atom catalysts(SACs)have been proposed to effectively enhance the kinetics of these two reactions.In this minireview,we focus on the recent progress in SACs for OER and HER applications.Three classes of SACs have been reviewed,i.e.,alloy-based SACs,carbon-based SACs and SACs supported on other compounds.Different factors affecting the activities of SACs are also highlighted,including the inherent element property,the coordination environment,the geometric structure and the loading amount of metal atoms.Finally,we summarize the current problems and directions for future development in SACs.

Multifractal Decomposition of Generalized Digraph Recursive Sets with the Finite Intersection Property

By using measures of Markov type, we proved that under the finite intersection property, multifractal decomposition still hold for a large class of recursive fractals which allow appropriate overlapping.

P Fractions in Drainage Waters from the Broadbalk Continuous Wheat Experiment at Rothamsted

Total P (TP), total participate P (PP), total dissolved P (TDP), molybdatereactive P (MRP) and dissolved organic P (DOP) were determined in waters from pipe-drains (at 65-cmdepth) from the Broadbalk Experiment at Rothamsted Research, UK. Average TPand PP exceeded 1 mgL^(-1) in about half of the 12 plots receiving superphosphate for the 5 measurements taken betweenDecember 2000 and April 2001. Ranging between 33.8% and 87.3% of TP, PP was the largest P fractionin drainage waters, with DOP, ranging from 0.5% to 26.2% of TP, being the smallest fraction Meanproportions of PP, MRP and DOP in TP in drainage waters were 63.4%, 32.5% and 4.1%, respectively.These findings support previous findings that P losses from soil to drainage waters were muchlargerthan previously thought, and could therefore make a significant contribution to eutrophication.

Finite Symmetry Transformation Groups and Some Exact Solutions to(2+1)-Dimensional Cubic Nonlinear Schrdinger Equantion

Making use of the direct method proposed by Lou et al. and symbolic computation, finite symmetry transformation groups for a （2＋ l）-dimensional cubic nonlinear Schrodinger （NLS） equation and its corresponding cylindrical NLS equations are presented. Nine related linear independent infinitesimal generators can be obtained from the finite symmetry transformation groups by restricting the arbitrary constants in infinitesimal forms. Some exact solutions are derived from a simple travelling wave solution.

New Explicit Rational Solitary Wave Solutions for Discretized mKdV Lattice Equation

In this letter, we study discretized mKdV lattice equation by using a new generalized ansatz. As a result,many explicit rational exact solutions, including some new solitary wave solutions, are obtained by symbolic computation code Maple.

Boundedness of Solutions for Elliptic Variational Inequalities

The boundedness is proved under more general structural conditions to solutions of elliptic variational inequalities and a priori estimates are obtained to maximum modulus of solutions for some special cases.

Resolution of Ibuprofen Ester by Catalytic Antibodies in Water-miscible Organic-solvents

The asymmetric hydrolysis of racemic ibuprofen ester is one of the most important methods for chiral separation of ibuprofen. In this work, a catalytic antibody that accelerates the rate of enantioselective hydrolysis of ibuprofen methyl ester was obtained against an immunogen consisting of tetrahedral phosphonate hapten attached to bovine serum albumin (BSA). The catalytic activity of the catalytic antibody in the water-miscible organic-solvent system composed of a buffer solution and N, N-dimethylformamide (DMF) was studied. With 6% DMF in the buffer solution (containing catalytic antibody 0.25 μmol, 0.2 mol·L-1 phosphate buffer, pH 8) at 37°C for 10 h, a good conversion (48.7%) and high enantiomeric excess (>99%) could be reached. The kinetic analysis of the cata-lytic antibody-catalyzed reaction showed that the hydrolysis in the water-miscible organic-solvent system with DMF in buffer solution followed the Michaelis-Menten kinetics. The catalytic efficiency (Kcat/Km) was enhanced to 151.91 L·mmol-1·min-1, twice as large as that for the buffer solution only.