We present a fully quantum solution to the Gibbs paradox (GP) with an illustration based on a gedanken experiment with two particles trapped in an infinite potential well. The well is divided into two cells by a solid...We present a fully quantum solution to the Gibbs paradox (GP) with an illustration based on a gedanken experiment with two particles trapped in an infinite potential well. The well is divided into two cells by a solid wall, which could be removed for mixing the particles. For the initial thermal state with correct two-particle wavefunction according to their quantum statistics, the exact calculations show the entropy changes are the same for boson, fermion and non-identical particles. With the observation that the initial unmixed state of identical particles in the conventional presentations actually is not of a thermal equilibrium, our analysis reveals the quantum origin of the paradox, and confirms Jaynes' observation that entropy increase in Gibbs mixing is only due to the including more observables. To further show up the subtle role of the quantum mechanism in the GP, we study the different finite size effect on the entropy change and show the work performed in the mixing process is different for various types of particles.展开更多
In this article, we apply the Generalized Uncertainty Principle （GUP）, which is consistent with quantum gravity theories to an elementary particle in a finite potential well, and study the quantum behavior in this s...In this article, we apply the Generalized Uncertainty Principle （GUP）, which is consistent with quantum gravity theories to an elementary particle in a finite potential well, and study the quantum behavior in this system. The generalized Hamiltonian contains two additional terms, which are proportional to ap3 （the result of the maximum momentum assumption） and a2p4 （the result of the minimum length assumption）, where a - 1/MpIc is the GUP parameter. On the basis of the work by Ali et al., we solve the generaiized Schrodinger equation which is extended to include the a2 correction term, and find that the length L of the finite potentiai well must be quantized. Then a generalization to the double-square-well potential is discussed. The result shows that all the measurable lengths especially the distance between the two potential wells are quantized in units of aolp1 in GUP scenario.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos. 11121403,10935010 and 11074261)
文摘We present a fully quantum solution to the Gibbs paradox (GP) with an illustration based on a gedanken experiment with two particles trapped in an infinite potential well. The well is divided into two cells by a solid wall, which could be removed for mixing the particles. For the initial thermal state with correct two-particle wavefunction according to their quantum statistics, the exact calculations show the entropy changes are the same for boson, fermion and non-identical particles. With the observation that the initial unmixed state of identical particles in the conventional presentations actually is not of a thermal equilibrium, our analysis reveals the quantum origin of the paradox, and confirms Jaynes' observation that entropy increase in Gibbs mixing is only due to the including more observables. To further show up the subtle role of the quantum mechanism in the GP, we study the different finite size effect on the entropy change and show the work performed in the mixing process is different for various types of particles.
基金Supported by National Natural Science Foundation of China under Grant Nos.10865003 and 11464005
文摘In this article, we apply the Generalized Uncertainty Principle （GUP）, which is consistent with quantum gravity theories to an elementary particle in a finite potential well, and study the quantum behavior in this system. The generalized Hamiltonian contains two additional terms, which are proportional to ap3 （the result of the maximum momentum assumption） and a2p4 （the result of the minimum length assumption）, where a - 1/MpIc is the GUP parameter. On the basis of the work by Ali et al., we solve the generaiized Schrodinger equation which is extended to include the a2 correction term, and find that the length L of the finite potentiai well must be quantized. Then a generalization to the double-square-well potential is discussed. The result shows that all the measurable lengths especially the distance between the two potential wells are quantized in units of aolp1 in GUP scenario.
