Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their ...Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.展开更多
The effects of inclusions on microstructure, mechanical property, corrosion behavior of Mg-10Gd-3Y （GW103K） alloys by unrefining, MgO ceramic filtering and JDMJ flux refining were investigated, respectively. The res...The effects of inclusions on microstructure, mechanical property, corrosion behavior of Mg-10Gd-3Y （GW103K） alloys by unrefining, MgO ceramic filtering and JDMJ flux refining were investigated, respectively. The results indicate that with decreasing significantly the number and size grade of inclusions for the alloy refined with JDMJ flux, tensile strength and elongation increase; however, the yield strength is less than that of the alloy refined with MgO ceramic filter and unrefined alloy. With the decrease of the inclusions contents, the corrosion rate of the alloys quickly vary from 2.419 mg/（cm 2 ·d） to 1.265 mg/（cm 2 ·d）. After inclusion content is reduced to 0.385%, the corrosion rate has almost no changes. Finally, the relationship between the volume fraction of inclusions and service properties of GW103K alloy under different conditions are established quantitatively.展开更多
基金National Natural Science Foundation of China (52072088, 52072089)Natural Science Foundation of Heilongjiang Province (LH2023E061)+1 种基金Scientific and Technological Innovation Leading Talent of Harbin Manufacturing (2022CXRCCG001)Fundamental Research Funds for the Central Universities (3072023CFJ1003)。
文摘Hexagonal boron nitride(h-BN)ceramics have become exceptional materials for heat-resistant components in hypersonic vehicles,owing to their superior thermal stability and excellent dielectric properties.However,their densification during sintering still poses challenges for researchers,and their mechanical properties are rather unsatisfactory.In this study,SrAl_(2)Si_(2)O_(8)(SAS),with low melting point and high strength,was introduced into the h-BN ceramics to facilitate the sintering and reinforce the strength and toughness.Then,BN-SAS ceramic composites were fabricated via hot press sintering using h-BN,SrCO_(3),Al_(2)O_(3),and SiO_(2) as raw materials,and effects of sintering pressure on their microstructure,mechanical property,and thermal property were investigated.The thermal shock resistance of BN-SAS ceramic composites was evaluated.Results show that phases of as-preparedBN-SAS ceramic composites are h-BN and h-SrAl_(2)Si_(2)O_(8).With the increase of sintering pressure,the composites’densities increase,and the mechanical properties shew a rising trend followed by a slight decline.At a sintering pressure of 20 MPa,their bending strength and fracture toughness are(138±4)MPa and(1.84±0.05)MPa·m^(1/2),respectively.Composites sintered at 10 MPa exhibit a low coefficient of thermal expansion,with an average of 2.96×10^(-6) K^(-1) in the temperature range from 200 to 1200℃.The BN-SAS ceramic composites prepared at 20 MPa display higher thermal conductivity from 12.42 to 28.42 W·m^(-1)·K^(-1) within the temperature range from room temperature to 1000℃.Notably,BN-SAS composites exhibit remarkable thermal shock resistance,with residual bending strength peaking and subsequently declining sharply under a thermal shock temperature difference ranging from 600 to 1400℃.The maximum residual bending strength is recorded at a temperature difference of 800℃,with a residual strength retention rate of 101%.As the thermal shock temperature difference increase,the degree of oxidation on the ceramic surface and cracks due to thermal stress are also increased gradually.
基金Project(2007CB613701)supported by the National Basic Research Program of ChinaProject(20100470125)by National Science Foundation for Post-doctoral Scientists of ChinaProject(2009021028)supported by Science and Technique Foundation for Young Scholars of Shanxi Province
文摘The effects of inclusions on microstructure, mechanical property, corrosion behavior of Mg-10Gd-3Y （GW103K） alloys by unrefining, MgO ceramic filtering and JDMJ flux refining were investigated, respectively. The results indicate that with decreasing significantly the number and size grade of inclusions for the alloy refined with JDMJ flux, tensile strength and elongation increase; however, the yield strength is less than that of the alloy refined with MgO ceramic filter and unrefined alloy. With the decrease of the inclusions contents, the corrosion rate of the alloys quickly vary from 2.419 mg/（cm 2 ·d） to 1.265 mg/（cm 2 ·d）. After inclusion content is reduced to 0.385%, the corrosion rate has almost no changes. Finally, the relationship between the volume fraction of inclusions and service properties of GW103K alloy under different conditions are established quantitatively.
