By means of X ray and gas chromatography analysis, the crystalline structure of untreated wood , alkali treated wood and benzylated wood and their liquefaction in toluene and tetrahydrofufan with HCl as a catalyst we...By means of X ray and gas chromatography analysis, the crystalline structure of untreated wood , alkali treated wood and benzylated wood and their liquefaction in toluene and tetrahydrofufan with HCl as a catalyst were studied .The upper solution of benzylated wood was also studied by GC MS analysis. It proved that the introduction of bulky benzyl group in wood significantly changed the crystalline structure of wood ,enlarging the free volume which facilitated the penetration of solvent into the matrix of treated wood, thus tremendously enhancing thesolubility in solvent,compared to untreated wood and alkali treated wood. The percentage of residue decreased and the combined solvent increased with the increase of weight gain revealed that the liquefaction process became easy. Furthermore, the factors that influenced the liquefaction of benzylated wood were investigated. It showed that the liquefaction performance was improved with the increase of liquefaction time and the amount of catalyst when toluene was used as a solvent, especially in the presence of THF as solvent, there existed the optimum liquefaction time and the amount of catalyst .展开更多
Utilization of oily keruing wood for laminated wood product has not been optimal yet because of the appearance of extractive substance as oil on wood surface and hence disturbing the bonding process. A study has been ...Utilization of oily keruing wood for laminated wood product has not been optimal yet because of the appearance of extractive substance as oil on wood surface and hence disturbing the bonding process. A study has been conducted by manufacturing laminated wood from oily keruing wood （Dipterocarpus hasseltii） after extracting its oil by boiling the wood in the mixture of water and ethanol solution in several proportions. The assessment on the treated wood and the resulting laminated wood covered some characteristics i.e., wettability, static bending, bonding strength, ethanol-water solution can improve wetting properties significantly and delamination. The results show that boiling treatment in The extractive does not affect mechanical characteristics of the laminated wood. Increasing of water proportion in ethanol-water solution causes the decreasing of the bonding strength and increasing delamination value of the laminated wood. The result also shows that oily keruing wood after the treatment can be used as material for laminated wood.展开更多
文摘By means of X ray and gas chromatography analysis, the crystalline structure of untreated wood , alkali treated wood and benzylated wood and their liquefaction in toluene and tetrahydrofufan with HCl as a catalyst were studied .The upper solution of benzylated wood was also studied by GC MS analysis. It proved that the introduction of bulky benzyl group in wood significantly changed the crystalline structure of wood ,enlarging the free volume which facilitated the penetration of solvent into the matrix of treated wood, thus tremendously enhancing thesolubility in solvent,compared to untreated wood and alkali treated wood. The percentage of residue decreased and the combined solvent increased with the increase of weight gain revealed that the liquefaction process became easy. Furthermore, the factors that influenced the liquefaction of benzylated wood were investigated. It showed that the liquefaction performance was improved with the increase of liquefaction time and the amount of catalyst when toluene was used as a solvent, especially in the presence of THF as solvent, there existed the optimum liquefaction time and the amount of catalyst .
文摘Utilization of oily keruing wood for laminated wood product has not been optimal yet because of the appearance of extractive substance as oil on wood surface and hence disturbing the bonding process. A study has been conducted by manufacturing laminated wood from oily keruing wood （Dipterocarpus hasseltii） after extracting its oil by boiling the wood in the mixture of water and ethanol solution in several proportions. The assessment on the treated wood and the resulting laminated wood covered some characteristics i.e., wettability, static bending, bonding strength, ethanol-water solution can improve wetting properties significantly and delamination. The results show that boiling treatment in The extractive does not affect mechanical characteristics of the laminated wood. Increasing of water proportion in ethanol-water solution causes the decreasing of the bonding strength and increasing delamination value of the laminated wood. The result also shows that oily keruing wood after the treatment can be used as material for laminated wood.
