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杨木乙醇木素羟甲基化改性反应的研究 被引量:6
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作者 周景辉 丁雪峰 +1 位作者 梁洁 石海强 《大连工业大学学报》 CAS 北大核心 2009年第5期339-342,共4页
用甲醛对杨木乙醇木素进行羟甲基化改性并对其反应机理和反应条件进行了研究。通过测定改性后产物的羟甲基含量值,确定了杨木乙醇木素羟甲基化改性的最优条件:甲醛用量7.37 mmol.g-1(对木素),pH值10.0,反应温度65℃,反应时间90 min。在... 用甲醛对杨木乙醇木素进行羟甲基化改性并对其反应机理和反应条件进行了研究。通过测定改性后产物的羟甲基含量值,确定了杨木乙醇木素羟甲基化改性的最优条件:甲醛用量7.37 mmol.g-1(对木素),pH值10.0,反应温度65℃,反应时间90 min。在该条件下对杨木乙醇木素进行羟甲基化改性,测得改性后木素的羟甲基质量分数可达到12.84%。 展开更多
关键词 乙醇木素 羟甲基化 木素改性
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Performance characterization, of rigid polyurethane foam with refined alkali lignin and modified alkali lignin 被引量:6
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作者 刘志明 于菲 +1 位作者 方桂珍 杨慧君 《Journal of Forestry Research》 SCIE CAS CSCD 2009年第2期161-164,I0003,I0004,共6页
The two kinds of rigid polyurethane (PU) foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in... The two kinds of rigid polyurethane (PU) foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight. The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams. The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples. The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently. Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples. The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field. 展开更多
关键词 refined alkali lignin modified alkali lignin rigid PU foam mechanic performance thermal stability
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