Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR s...Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.展开更多
The experimental orchard on calcareous soils in the Tikves region has been established in 1999, in order to investigate the influence of the rootstocks on the behaviour of the peach trees. In the experiment we evaluat...The experimental orchard on calcareous soils in the Tikves region has been established in 1999, in order to investigate the influence of the rootstocks on the behaviour of the peach trees. In the experiment we evaluated next rootstocks： Nemaguard （Prunus persica × Prunus davidiana）, seedlings of GF 677 （Prunus persica ×Prunus amygdalus）, hybrids BMVA 1, BMVA 2, VAF 215 and Autochthones type and GF 677 （Prunus persica × Prunus amygdalus） clonal. As control rootstocks in our experiment was used seedlings from vineyard peach （Prunus persica）. The experiment was established with one year old trees from Redhaven variety. Agronomical characteristics （vegetative growth, occurrence of leaf chlorosis, tree mortality, yield, productivity and fruit quality） of the trees on different rootstocks have been measured over a twelve-year period （1999-2010）. Significant differences on the level of P 〈 0.05 have been observed on vigour of the trees. The most vigorous trees were those on GF 677 clonal, GF 677 seedling and BMVA 2. The trees on Vineyard peach and Nemaguard was the weakest ones. The highest cumulative yield was recorded on GF-677 clonal rootstock, and the lowest on Nemaguard. Occurrence of chlorosis was the highest at Vineyard peach, Nemaguard and Autochthones hybrid, GF 677 clonal was the only rootstock without iron chlorosis. The percent of tree mortality to twelfth year was the highest at Autochthones hybrid （33.3）, and at GF 677 clonal and BMVA 1 had not tree mortality.展开更多
基金This study was sponsored by the Research Funding for Key Laboratory of Cellulose and Ligno cellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences (No. LCLC-2004-158)the National Natural Science Foundation of Fujian(No. Z0513015)
文摘Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.
文摘The experimental orchard on calcareous soils in the Tikves region has been established in 1999, in order to investigate the influence of the rootstocks on the behaviour of the peach trees. In the experiment we evaluated next rootstocks： Nemaguard （Prunus persica × Prunus davidiana）, seedlings of GF 677 （Prunus persica ×Prunus amygdalus）, hybrids BMVA 1, BMVA 2, VAF 215 and Autochthones type and GF 677 （Prunus persica × Prunus amygdalus） clonal. As control rootstocks in our experiment was used seedlings from vineyard peach （Prunus persica）. The experiment was established with one year old trees from Redhaven variety. Agronomical characteristics （vegetative growth, occurrence of leaf chlorosis, tree mortality, yield, productivity and fruit quality） of the trees on different rootstocks have been measured over a twelve-year period （1999-2010）. Significant differences on the level of P 〈 0.05 have been observed on vigour of the trees. The most vigorous trees were those on GF 677 clonal, GF 677 seedling and BMVA 2. The trees on Vineyard peach and Nemaguard was the weakest ones. The highest cumulative yield was recorded on GF-677 clonal rootstock, and the lowest on Nemaguard. Occurrence of chlorosis was the highest at Vineyard peach, Nemaguard and Autochthones hybrid, GF 677 clonal was the only rootstock without iron chlorosis. The percent of tree mortality to twelfth year was the highest at Autochthones hybrid （33.3）, and at GF 677 clonal and BMVA 1 had not tree mortality.
