The CuO/γ-Al2O3/cordierite catalyst, after being sulfated by sulfur dioxide (SO2) at 673 K, exhibits high activities for selective catalytic reduction (SCR) of nitrogen oxide (NO) with ammonia (NH3) at 573-723 K. The...The CuO/γ-Al2O3/cordierite catalyst, after being sulfated by sulfur dioxide (SO2) at 673 K, exhibits high activities for selective catalytic reduction (SCR) of nitrogen oxide (NO) with ammonia (NH3) at 573-723 K. The intrinsic kinetics of SCR of NO with NH3 over CuO/γ-Al2O3/cordierite catalyst has been measured in a fixed-bed reactor in the absence of internal and external diffusions. The experimental results show that the reaction rate can be quantified by a first-order expression with activation energy Eá of 94.01 kJ·mol-1 and the corresponding p re-exponential factor A′ of 3.39×108 cm3·g-1·s-1 when NH3 is excessive. However, when NH3 is not enough, an E ley-Rideal kinetic model based on experimental data is derived with Ea of 105.79 kJ·mol-1, the corresponding A of 2 .94×109 cm3·g-1·s-1, heat of adsorption-Hads of 87.90 kJ·mol-1 and the corresponding Aads of 9.24 cm3·mol-1. The intrinsic kinetic model obtained was incorporated in a 3D mathematical model of monolithic reactor, and the agreement of the prediction with experimental data indicates that the present kinetic model is adequate for the reac-tor design and engineering scale-up.展开更多
Based on statistical damage mechanics,the constitutive model of a rock underthree-dimensional stress was established by the law that the statistical strength of rockmicro-element obeys Weibull distribution.The acousti...Based on statistical damage mechanics,the constitutive model of a rock underthree-dimensional stress was established by the law that the statistical strength of rockmicro-element obeys Weibull distribution.The acoustic emission (AE) evolution model ofrock failure was put forward according to the view that rock damage and AE were consistent.Moreover,in the failure process of rock under three-dimensional stress,the change inrelationship between stress condition parameter and the characteristic parameters of AE,such as the event number and its change rate,were studied.Also,the rock AE characteristicunder uniaxial compression was analyzed in theory and verified with examples.Theresults indicate that the cumulative event number and change rate of AE in rock failure aredetermined by stress state parameter F.Along with the gradual increase of F,first the cumulativeevent number increases gradually,then rapidly,and then slowly after the stresspeak.The form of change rate of an event by increasing F is consistent with the distributionform of rock micro-element strength.The model explained the phenomenon that a relativelyquiet period of AE appears before rock rupture that is observed by many researchersin experiments.Verification examples indicate that the AE evolution model is consistentwith the test results,so the model is reasonable and correct.展开更多
This work aims to investigate the intrinsic kinetics of thermal dimerization of C_5 fraction in the reactive distillation process. Experiments are conducted in an 1000-m L stainless steel autoclave under some selected...This work aims to investigate the intrinsic kinetics of thermal dimerization of C_5 fraction in the reactive distillation process. Experiments are conducted in an 1000-m L stainless steel autoclave under some selected design conditions. By means of the weighted least squares method, the intrinsic kinetics of thermal dimerization of C_5 fraction is established, and the corresponding pre-exponential factor as well as the activation energy are determined. For example, the pre-exponential factor A is equal to 4.39×105 and the activation energy E4 a is equal to 6.58×10J/mol for the cyclopentadiene dimerization reaction. The comparison between the experimental and calculated results shows that the kinetics model derived in this work is accurate and reliable, which can be used in the design of reactive distillation columns.展开更多
We extend the concept of invariant eigen-operator to pseudo-invariant eigen-operator case through analyzing the standard Jaynes-Cummings model. We find the pseudo-invariant eigen-operator in terms of supersymmetric ge...We extend the concept of invariant eigen-operator to pseudo-invariant eigen-operator case through analyzing the standard Jaynes-Cummings model. We find the pseudo-invariant eigen-operator in terms of supersymmetric generators of this model, which diretly leads to the energy-level gap for Jaynes Cummings Hamiltonian.展开更多
Deformation characteristics and constitutive model of seafloor massive sulfide(SMS)were selected as the research object.Uniaxial/triaxial compression test were carried out on the mineral samples,and the deformation ch...Deformation characteristics and constitutive model of seafloor massive sulfide(SMS)were selected as the research object.Uniaxial/triaxial compression test were carried out on the mineral samples,and the deformation characteristics of specimens under various conditions were studied.According to characteristics of the mineral,a new three stages constitutive equation was proposed.The conclusions are as follows:The axial strain,peak strain and maximum strength of seafloor massive sulfide increase with the confining pressure.The elastic modulus of the metal sulfide samples is decreased sharply with the increase of confining pressure.According to characteristics of seafloor massive sulfide,the constitutive equation is divided into three parts,the comparison between theoretical curves and experimental data shows that both of them are in good agreement,which also proves the correctness of the constitutive equation for uniaxial compression.展开更多
For the purpose of describing the deformation characteristics of rocks,the effect of volume changes on mechanical properties of rocks should be taken into account with relation to the development of constitutive model...For the purpose of describing the deformation characteristics of rocks,the effect of volume changes on mechanical properties of rocks should be taken into account with relation to the development of constitutive model.Firstly,rocks are divided into three parts,i.e.,voids,a damaged part and an undamaged part in the course of loading.The void ratio was applied to describing the changes of voids or pores during the deformation process.Then,using statistical damage theory,a constitutive model was developed for rocks to describe their strain softening and hardening on the basis of investigating the relationship between the net stress and apparent stress,in which the influence of volume changes on rock behavior was correctly taken into account,such as the initial phase of compaction and the latter stage of dilation.Thirdly,a method of determining model parameters was also presented.Finally,this model was used to compare the theoretical results with those observed from experiments under conventional triaxial loading conditions.展开更多
基金Supported by the National Natural Science Foundation of China （20821004 20736001 21076008） the Research Fund for the Doctoral Program of Higher Education of China （2090010110002）
文摘The CuO/γ-Al2O3/cordierite catalyst, after being sulfated by sulfur dioxide (SO2) at 673 K, exhibits high activities for selective catalytic reduction (SCR) of nitrogen oxide (NO) with ammonia (NH3) at 573-723 K. The intrinsic kinetics of SCR of NO with NH3 over CuO/γ-Al2O3/cordierite catalyst has been measured in a fixed-bed reactor in the absence of internal and external diffusions. The experimental results show that the reaction rate can be quantified by a first-order expression with activation energy Eá of 94.01 kJ·mol-1 and the corresponding p re-exponential factor A′ of 3.39×108 cm3·g-1·s-1 when NH3 is excessive. However, when NH3 is not enough, an E ley-Rideal kinetic model based on experimental data is derived with Ea of 105.79 kJ·mol-1, the corresponding A of 2 .94×109 cm3·g-1·s-1, heat of adsorption-Hads of 87.90 kJ·mol-1 and the corresponding Aads of 9.24 cm3·mol-1. The intrinsic kinetic model obtained was incorporated in a 3D mathematical model of monolithic reactor, and the agreement of the prediction with experimental data indicates that the present kinetic model is adequate for the reac-tor design and engineering scale-up.
基金Supported by the Key Program of National Basic Research Program(973)of China(2005CB221505)the National Natural Science Foundation of China(2005E041503)
文摘Based on statistical damage mechanics,the constitutive model of a rock underthree-dimensional stress was established by the law that the statistical strength of rockmicro-element obeys Weibull distribution.The acoustic emission (AE) evolution model ofrock failure was put forward according to the view that rock damage and AE were consistent.Moreover,in the failure process of rock under three-dimensional stress,the change inrelationship between stress condition parameter and the characteristic parameters of AE,such as the event number and its change rate,were studied.Also,the rock AE characteristicunder uniaxial compression was analyzed in theory and verified with examples.Theresults indicate that the cumulative event number and change rate of AE in rock failure aredetermined by stress state parameter F.Along with the gradual increase of F,first the cumulativeevent number increases gradually,then rapidly,and then slowly after the stresspeak.The form of change rate of an event by increasing F is consistent with the distributionform of rock micro-element strength.The model explained the phenomenon that a relativelyquiet period of AE appears before rock rupture that is observed by many researchersin experiments.Verification examples indicate that the AE evolution model is consistentwith the test results,so the model is reasonable and correct.
文摘This work aims to investigate the intrinsic kinetics of thermal dimerization of C_5 fraction in the reactive distillation process. Experiments are conducted in an 1000-m L stainless steel autoclave under some selected design conditions. By means of the weighted least squares method, the intrinsic kinetics of thermal dimerization of C_5 fraction is established, and the corresponding pre-exponential factor as well as the activation energy are determined. For example, the pre-exponential factor A is equal to 4.39×105 and the activation energy E4 a is equal to 6.58×10J/mol for the cyclopentadiene dimerization reaction. The comparison between the experimental and calculated results shows that the kinetics model derived in this work is accurate and reliable, which can be used in the design of reactive distillation columns.
基金The project supported by National Natural Science Foundation of China under Grant No. 10475056
文摘We extend the concept of invariant eigen-operator to pseudo-invariant eigen-operator case through analyzing the standard Jaynes-Cummings model. We find the pseudo-invariant eigen-operator in terms of supersymmetric generators of this model, which diretly leads to the energy-level gap for Jaynes Cummings Hamiltonian.
基金Project(2012AA091291)supported by the National High-tech Research and Development Program of ChinaProject(51074179)supported by the National Natural Science Foundation of ChinaProjects(JCYJ20130401160614378,JCYJ20140506150310437)supported by Shenzhen Science and Technology Innovation Basic Research Foundation,China
文摘Deformation characteristics and constitutive model of seafloor massive sulfide(SMS)were selected as the research object.Uniaxial/triaxial compression test were carried out on the mineral samples,and the deformation characteristics of specimens under various conditions were studied.According to characteristics of the mineral,a new three stages constitutive equation was proposed.The conclusions are as follows:The axial strain,peak strain and maximum strength of seafloor massive sulfide increase with the confining pressure.The elastic modulus of the metal sulfide samples is decreased sharply with the increase of confining pressure.According to characteristics of seafloor massive sulfide,the constitutive equation is divided into three parts,the comparison between theoretical curves and experimental data shows that both of them are in good agreement,which also proves the correctness of the constitutive equation for uniaxial compression.
基金Project(2006AA11Z104) supported by the National High-Tech Research and Development Program of China
文摘For the purpose of describing the deformation characteristics of rocks,the effect of volume changes on mechanical properties of rocks should be taken into account with relation to the development of constitutive model.Firstly,rocks are divided into three parts,i.e.,voids,a damaged part and an undamaged part in the course of loading.The void ratio was applied to describing the changes of voids or pores during the deformation process.Then,using statistical damage theory,a constitutive model was developed for rocks to describe their strain softening and hardening on the basis of investigating the relationship between the net stress and apparent stress,in which the influence of volume changes on rock behavior was correctly taken into account,such as the initial phase of compaction and the latter stage of dilation.Thirdly,a method of determining model parameters was also presented.Finally,this model was used to compare the theoretical results with those observed from experiments under conventional triaxial loading conditions.
