In order to solve the drifting away of thermal fog droplets during thermal spraying and the incompatibility between fog droplet carrier and conventional com- mercial agro-chemicals, the fog droplet carrier, surfactant...In order to solve the drifting away of thermal fog droplets during thermal spraying and the incompatibility between fog droplet carrier and conventional com- mercial agro-chemicals, the fog droplet carrier, surfactant, condensation nucleus ma- terial and antifreeze, dispersant, thickener and defoamer were screened and assem- bled to develop a thermal fog sedimentation stabilizer in this study, thereby provid- ing technical support for application and promotion of thermal spraying technology in pest and disease control in crops.展开更多
Icing on the surface of aircraft will not only aggravate its quality and affect flight control,but even cause safety accidents,which is one of the important factors restricting all-weather flight.Bio-inspired anti-ici...Icing on the surface of aircraft will not only aggravate its quality and affect flight control,but even cause safety accidents,which is one of the important factors restricting all-weather flight.Bio-inspired anti-icing surfaces have gained great attention recently due to their low-hysteresis,non-stick properties,slow nucleation rate and low ice adhesion strength.These bio-inspired anti-icing surfaces,such as superhydrophobic surfaces,slippery liquid-infused porous surfaces and quasi-liquid film surfaces,have realized excellent anti-icing performance at various stages of icing.However,for harsh environment,there are still many problems and challenges.From the perspective of bioinspiration,the mechanism of icing nucleation,liquid bounce and ice adhesion has been reviewed together with the application progress and bottleneck issues about anti-icing in view of the process of icing.Subsequently,the reliability and development prospect of active,passive and active-passive integrated anti-icing technology are discussed,respectively.展开更多
The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electro...The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electron spectroscopy in air). Furthermore, ESR (electron spin resonance) and AFM (atomic force microscopy) were used to investigate the surface morphology and molecular orientation, respectively. ESR analysis indicated the molecular orientation of the P3HT crystalline in the blend thin films, which the crystalline oriented normal to the substrate with distribution of 35°. AFM images indicated that the surface morphology of P3HT film was affected by the presence of PCBM nanoparticles. Solution-processed OTFTs (organic thin-film transistors) based on P3HT/PCBM blend thin film in a top source-drain contact structure was fabricated, and the electrical characteristics of the devices were also investigated. A unipolar property with p-channel characteristics were obtained in glove box measurement.展开更多
A pot experiment was conducted to investigate the action mechanisms phorus (P) uptake of Capsicum annuum L. in a sterilized fossil Oxisol of arbuscular mycorrhizal (AM) fungi in phos- Three P levels of 0, 10 and 2...A pot experiment was conducted to investigate the action mechanisms phorus (P) uptake of Capsicum annuum L. in a sterilized fossil Oxisol of arbuscular mycorrhizal (AM) fungi in phos- Three P levels of 0, 10 and 200 mg kg-1 soil (P0, P10 and P200, respectively) without and with AM fungal inoculation were applied as Ca(H2PO4)2-H20. Shoot dry matter yields and shoot P uptake increased significantly (P 〉 0.05) by the inoculation of AM fungi at P0 and P10. Root length and P concentration in soil solution increased with the inoculation of AM fungi but the root:shoot ratio decreased or remained constant. Around 50% roots of inoculated plants were infected by AM and the external hyphae amounted to 20 m g^-1 soil at P10 and P200. The hyphae surface area of the infected root cylinder amounted to 11 and 2 cm^2 cm^-2 root at P0 and P10, respectively. The increased P uptake of inoculated plants was mainly because of an up to 5 times higher P influx of the infected root. Model calculations showed that the root alone could not have achieved the measured P influx in both infected and non-infected roots. But the P influx for hyphae calculated by the model was even much higher than the measured one. The P uptake capacity of hyphae introduced in the model was too high. Model calculations further showed that the depletion zone around roots or hyphae was very narrow. In the case of the root only 7% of the soil volume would contribute P to the plant, while in the case of hyphae it would be 100%. The results together with the model calculations showed that the increased P uptake of AM inoculated plants could be explained partly by the increased P concentration in the soil solution and by the increased P absorbing surface area coming from the external hyphae.展开更多
Hydrogen sulphide(H2 S)is a common air pollutant,which is produced in various industry processes.Therefore,it is of crucial importance to detect H2 S in real time.Many fluorescent sensors were reported aiming at detec...Hydrogen sulphide(H2 S)is a common air pollutant,which is produced in various industry processes.Therefore,it is of crucial importance to detect H2 S in real time.Many fluorescent sensors were reported aiming at detecting H2 S in solution;however,the fluorescence sensing of gaseous H2 S has not yet been reported.In this work,we utilized the post-functionalized fluorescent film,MIL-100(In)@Eu3+/Cu2+film,realizing fluorescence turn-on sensing of gaseous H2 S at room temperature for the first time with the limit of detection as low as 0.535 ppm,which is comparable to some reported fluorescent probes for S2-ions and semiconductor based gaseous H2 S sensors.The sensor was designed due to the strong affinity of H2 S with Cu2+.With the formation of CuS,the"antenna effect"between the ligand and Eu3+recovered,resulting in the fluorescence turn-on of Eu3+emission.Additionally,we proposed a new method to realize multi-colour anti-counterfeiting patterns with lanthanide ions ink,taking advantage of the extraordinary smooth surface and uncoordinated carboxylate groups within the MIL-100(In)film.展开更多
Silver nanoparticles(Ag NPs)are synthesized with chemical method,which are introduced into the traditional organic photovoltaic(OPV)structure.The experimental results show that both the optical and photoelectric prope...Silver nanoparticles(Ag NPs)are synthesized with chemical method,which are introduced into the traditional organic photovoltaic(OPV)structure.The experimental results show that both the optical and photoelectric properties are en-hanced because of localized surface plasmon(LSP)effects of Ag NPs.The advantage of adding Ag NPs behind active layer in incident direction is discussed.We believe this route can avoid absorption shadow and enhance the reusing of transmitted light of active layer.The average short-circuit current(J SC)of the optimum device can be raised from 9.23mA/cm2 to 10.84mA/cm2,and the energy converting efficiency(PCE)can be raised from 3.22% to 3.85%.展开更多
The surface of nanocrystals plays a dominant role in many of their physical and chemical properties.However,controllability and tunability of nanocrystal surfaces remain unsolved.Herein,we report that the surface chem...The surface of nanocrystals plays a dominant role in many of their physical and chemical properties.However,controllability and tunability of nanocrystal surfaces remain unsolved.Herein,we report that the surface chemistry of nanocrystals,such as near-infrared Ag_(2)Se quantum dots(QDs),is sizedependent and composition-tunable.The Ag_(2)Se QDs tend to form a stable metal complex on the surface to minimize the surface energy,and therefore the surface chemistry can be varied with particle size.Meanwhile,changes in surface inorganic composition lead to reorganization of the surface ligands,and the surface chemistry also varies with composition.Therefore,the surface chemistry of Ag_(2)Se QDs,responsible for the photoluminescence(PL)quantum yield and photostability,can be tuned by changing their size or composition.Accordingly,we demonstrate that the PL intensity of the Ag_(2)Se QDs can be tuned reversely by adjusting the degree of surface Ag^(+) enrichment via light irradiation or the addition of AgNO_(3).This work provides insight into the control of QD surface for desired PL properties.展开更多
基金Supported by Anhui Agricultural Science and Technology Innovation Fund(16A1132)Science and Technology Major Project of Anhui Province(15CZZ03132)Special Fund for Talent Development in Anhui Province(13C1109)~~
文摘In order to solve the drifting away of thermal fog droplets during thermal spraying and the incompatibility between fog droplet carrier and conventional com- mercial agro-chemicals, the fog droplet carrier, surfactant, condensation nucleus ma- terial and antifreeze, dispersant, thickener and defoamer were screened and assem- bled to develop a thermal fog sedimentation stabilizer in this study, thereby provid- ing technical support for application and promotion of thermal spraying technology in pest and disease control in crops.
基金financially supported by the National Natural Science Foundation of China(Nos.T2121003,51725501,51935001,52205297).
文摘Icing on the surface of aircraft will not only aggravate its quality and affect flight control,but even cause safety accidents,which is one of the important factors restricting all-weather flight.Bio-inspired anti-icing surfaces have gained great attention recently due to their low-hysteresis,non-stick properties,slow nucleation rate and low ice adhesion strength.These bio-inspired anti-icing surfaces,such as superhydrophobic surfaces,slippery liquid-infused porous surfaces and quasi-liquid film surfaces,have realized excellent anti-icing performance at various stages of icing.However,for harsh environment,there are still many problems and challenges.From the perspective of bioinspiration,the mechanism of icing nucleation,liquid bounce and ice adhesion has been reviewed together with the application progress and bottleneck issues about anti-icing in view of the process of icing.Subsequently,the reliability and development prospect of active,passive and active-passive integrated anti-icing technology are discussed,respectively.
文摘The mixed P3HT (poly(3-hexylthiophene)) and [6,6]-PCBM (phenyl C61-butyric acid methyl ester) organic thin films were investigated for electronic structure using UV-Vis spectrophotometer and PESA (photo-electron spectroscopy in air). Furthermore, ESR (electron spin resonance) and AFM (atomic force microscopy) were used to investigate the surface morphology and molecular orientation, respectively. ESR analysis indicated the molecular orientation of the P3HT crystalline in the blend thin films, which the crystalline oriented normal to the substrate with distribution of 35°. AFM images indicated that the surface morphology of P3HT film was affected by the presence of PCBM nanoparticles. Solution-processed OTFTs (organic thin-film transistors) based on P3HT/PCBM blend thin film in a top source-drain contact structure was fabricated, and the electrical characteristics of the devices were also investigated. A unipolar property with p-channel characteristics were obtained in glove box measurement.
基金Supported by the Higher Education Commission of Pakistan
文摘A pot experiment was conducted to investigate the action mechanisms phorus (P) uptake of Capsicum annuum L. in a sterilized fossil Oxisol of arbuscular mycorrhizal (AM) fungi in phos- Three P levels of 0, 10 and 200 mg kg-1 soil (P0, P10 and P200, respectively) without and with AM fungal inoculation were applied as Ca(H2PO4)2-H20. Shoot dry matter yields and shoot P uptake increased significantly (P 〉 0.05) by the inoculation of AM fungi at P0 and P10. Root length and P concentration in soil solution increased with the inoculation of AM fungi but the root:shoot ratio decreased or remained constant. Around 50% roots of inoculated plants were infected by AM and the external hyphae amounted to 20 m g^-1 soil at P10 and P200. The hyphae surface area of the infected root cylinder amounted to 11 and 2 cm^2 cm^-2 root at P0 and P10, respectively. The increased P uptake of inoculated plants was mainly because of an up to 5 times higher P influx of the infected root. Model calculations showed that the root alone could not have achieved the measured P influx in both infected and non-infected roots. But the P influx for hyphae calculated by the model was even much higher than the measured one. The P uptake capacity of hyphae introduced in the model was too high. Model calculations further showed that the depletion zone around roots or hyphae was very narrow. In the case of the root only 7% of the soil volume would contribute P to the plant, while in the case of hyphae it would be 100%. The results together with the model calculations showed that the increased P uptake of AM inoculated plants could be explained partly by the increased P concentration in the soil solution and by the increased P absorbing surface area coming from the external hyphae.
基金supported by the National Natural Science Foundation of China(U1609219,51632008,61721005,51432001and 51772268)Zhejiang Provincial Natural Science Foundation(LD18E020001)
文摘Hydrogen sulphide(H2 S)is a common air pollutant,which is produced in various industry processes.Therefore,it is of crucial importance to detect H2 S in real time.Many fluorescent sensors were reported aiming at detecting H2 S in solution;however,the fluorescence sensing of gaseous H2 S has not yet been reported.In this work,we utilized the post-functionalized fluorescent film,MIL-100(In)@Eu3+/Cu2+film,realizing fluorescence turn-on sensing of gaseous H2 S at room temperature for the first time with the limit of detection as low as 0.535 ppm,which is comparable to some reported fluorescent probes for S2-ions and semiconductor based gaseous H2 S sensors.The sensor was designed due to the strong affinity of H2 S with Cu2+.With the formation of CuS,the"antenna effect"between the ligand and Eu3+recovered,resulting in the fluorescence turn-on of Eu3+emission.Additionally,we proposed a new method to realize multi-colour anti-counterfeiting patterns with lanthanide ions ink,taking advantage of the extraordinary smooth surface and uncoordinated carboxylate groups within the MIL-100(In)film.
基金supported by the National Natural Science Foundation of China(Nos.60876046and60976048)the Tianjin Natural Science Foundation(Nos.10ZCKFGX01900,10SYSYJC28100and12JCQNJC01300)+1 种基金the Scientific Developing Foundation of Tianjin Education Commission(No.20100723)the Tianjin Key Discipline of Material Physics and Chemistry
文摘Silver nanoparticles(Ag NPs)are synthesized with chemical method,which are introduced into the traditional organic photovoltaic(OPV)structure.The experimental results show that both the optical and photoelectric properties are en-hanced because of localized surface plasmon(LSP)effects of Ag NPs.The advantage of adding Ag NPs behind active layer in incident direction is discussed.We believe this route can avoid absorption shadow and enhance the reusing of transmitted light of active layer.The average short-circuit current(J SC)of the optimum device can be raised from 9.23mA/cm2 to 10.84mA/cm2,and the energy converting efficiency(PCE)can be raised from 3.22% to 3.85%.
基金supported by the National Natural Science Foundation of China(91859123)the National Key R&D Program of China(2019YFA0210103)。
文摘The surface of nanocrystals plays a dominant role in many of their physical and chemical properties.However,controllability and tunability of nanocrystal surfaces remain unsolved.Herein,we report that the surface chemistry of nanocrystals,such as near-infrared Ag_(2)Se quantum dots(QDs),is sizedependent and composition-tunable.The Ag_(2)Se QDs tend to form a stable metal complex on the surface to minimize the surface energy,and therefore the surface chemistry can be varied with particle size.Meanwhile,changes in surface inorganic composition lead to reorganization of the surface ligands,and the surface chemistry also varies with composition.Therefore,the surface chemistry of Ag_(2)Se QDs,responsible for the photoluminescence(PL)quantum yield and photostability,can be tuned by changing their size or composition.Accordingly,we demonstrate that the PL intensity of the Ag_(2)Se QDs can be tuned reversely by adjusting the degree of surface Ag^(+) enrichment via light irradiation or the addition of AgNO_(3).This work provides insight into the control of QD surface for desired PL properties.