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NEW TYPE OF LINEAR ULTRASONIC MOTOR WITH TWO DEGREES OF FREEDOM USING LONGITUDINAL AND BENDING MODE 被引量:2
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作者 李志荣 刘俊标 +1 位作者 黄卫清 赵淳生 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2004年第1期7-12,共6页
A new type of linear ultrasonic motor with two degrees of freedom (DOF) motion is presented. The concept of the new typical motor is based on the combination of a longitudinal and two bending modes. The construction a... A new type of linear ultrasonic motor with two degrees of freedom (DOF) motion is presented. The concept of the new typical motor is based on the combination of a longitudinal and two bending modes. The construction and the operational principle of motor are described, and the elliptical motion of the driving point of the actuator is proved. Meanwhile, a prototype linear motor is designed by using the finite element method (FEM) and is constructed for experiments. The vibration modes are tested with the laser doppler vibrometer (PSV-300F), and the experimental results prove that the design requirements on the mode shape of the actuator and nature frequency are satisfied. The test run of the motor indicates that the operational principle of the motor and the design results are correct, and the output properties are also tested. 展开更多
关键词 ultrasonic motor two DOF motion linear motion elliptical motion mode shape
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美军多域作战实施方案及其直升机性能升级计划 被引量:1
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作者 杨婧 席艳 《直升机技术》 2019年第4期60-66,共7页
科技的发展不断推动着作战概念的演变和升级,美军于2016年提出的"多域战"概念经过近两年的发展与完善,已经正式确定为"多域作战"。该概念进一步拓展了作战的范围,内容也更加丰富具体。文章对多域作战的实施背景、... 科技的发展不断推动着作战概念的演变和升级,美军于2016年提出的"多域战"概念经过近两年的发展与完善,已经正式确定为"多域作战"。该概念进一步拓展了作战的范围,内容也更加丰富具体。文章对多域作战的实施背景、实施原则与目标、具体的实施方案进行了详细介绍,最后阐述了美军为顺应新的作战理念而制定的直升机性能升级计划。 展开更多
关键词 多域作战 反介入/区域拒止系统 机动自由 直升机
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Kinematics and dynamics analysis of a three-degree-of-freedom parallel manipulator 被引量:6
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作者 刘善增 朱真才 +1 位作者 孙肇鹏 曹国华 《Journal of Central South University》 SCIE EI CAS 2014年第7期2660-2666,共7页
Kinematics and dynamics analyses were performed for a spatial 3-revolute joint-revolute joint-clylindric pair(3-RRC) parallel manipulator.This 3-RRC parallel manipulator is composed of a moving platform,a base platfor... Kinematics and dynamics analyses were performed for a spatial 3-revolute joint-revolute joint-clylindric pair(3-RRC) parallel manipulator.This 3-RRC parallel manipulator is composed of a moving platform,a base platform,and three revolute joint-revolute joint-column pair chains which connect the moving platform and the base platform.Firstly,kinematics analysis for 3-RRC parallel manipulator was conducted.Next,on the basis of Lagrange formula,a simply-structured dynamic model of 3-RRC parallel manipulator was derived.Finally,through a calculation example,the variation of motorial parameters of this 3-RRC parallel manipulator,equivalent moment of inertia,driving force/torque and energy consumption was discussed.The research findings have important significance for research and engineering projects such as analyzing dynamic features,mechanism optimization design and control of 3-RRC parallel manipulator. 展开更多
关键词 KINEMATICS DYNAMICS parallel manipulator Lagrange formula
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An effective algorithm for needle tip displacement compensation in robot-assisted percutaneous surgery 被引量:1
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作者 Sun Yinshan Wu Dongmei Du Zhijiang Sun Lining 《High Technology Letters》 EI CAS 2010年第3期306-310,共5页
This paper presents an automatic compensation algorithm for needle tip displacement in order to keep the needle tip always fixed at the skin entry point in the process of needle orientation in robot-assisted percutane... This paper presents an automatic compensation algorithm for needle tip displacement in order to keep the needle tip always fixed at the skin entry point in the process of needle orientation in robot-assisted percutaneous surgery. The algorithm, based on a two-degree-of-freedom (2-DOF) robot wrist (not the mechanically constrained remote center of motion (RCM) mechanism) and a 3-DOF robot ann, firstly calculates the needle tip displacement caused by rotational motion of robot wrist in the arm coordinate frame using the robotic forward kinematics, and then inversely compensates for the needle tip displace- ment by real-time Cartesian motion of robot arm. The algorithm achieves the function of the RCM and eliminates many mechanical and virtual constraints caused by the RCM mechanism. Experimental result demonstrates that the needle tip displacement is within 1 inm in the process of needle orientation. 展开更多
关键词 robot-assisted percutaneous surgery needle insertion robot needle tip displacement compensation remote center of motion (RCM) virtual remote center of motion (VRCM) medical robot
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Dynamics of mechanical system for electromechanical integrated toroidal drive under electric disturbance 被引量:1
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作者 许立忠 郝秀红 《Journal of Central South University》 SCIE EI CAS 2014年第4期1296-1306,共11页
Based on electromagnetics and mechanics, electromechanical coupled dynamic equations for the drive were developed. Using method of perturbation, free vibrations of the mechanical system under electric disturbance were... Based on electromagnetics and mechanics, electromechanical coupled dynamic equations for the drive were developed. Using method of perturbation, free vibrations of the mechanical system under electric disturbance were investigated. The forced responses of the mechanical system to mechanical excitation under electric disturbance were also presented. It is known that for the system with electric disturbance, as time grows, beat occurs. When electric disturbing frequency is near to the natural frequencies of the mechanical system or their integer multiple, resonance vibrations occur. The forced responses of the mechanical system to mechanical excitation under electric disturbance are compound vibrations decided by mechanical excitation, electric disturbance and parameters of the system. The coupled resonance vibration caused by electric disturbance and mechanical excitation was discussed as well. The conditions under which above coupled resonance occurs were presented. The results show that when the difference of the excitation frequency and the perturbation frequency is equal to some order of natural frequency, coupled resonance vibrations occur. 展开更多
关键词 toroidal drive electromechanical integration dynamics free vibration forced response
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Kinematic analysis of a humanoid robot CHP-1 and selection of motors in consideration of cooperative motion
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作者 KIM Do-un HWANG Sang-wook +1 位作者 KANG Hyo-jung HONG Dae Sun 《Journal of Central South University》 SCIE EI CAS 2012年第11期3094-3099,共6页
A lower-part humanoid robot CHP-1 with 12 degree-of-freedom of motion has been developed for cooperative motion,such as pushing or lifting an object.The capability of the robot is mainly dependent on the performance o... A lower-part humanoid robot CHP-1 with 12 degree-of-freedom of motion has been developed for cooperative motion,such as pushing or lifting an object.The capability of the robot is mainly dependent on the performance of the motors,thus the motors need to be properly selected.For the purpose,the kinematics of the robot was analyzed,and a number of simulations for two kinds of cooperative motions were carried out.The torques required at each motor of the robot under external forces were obtained.Here,the external forces were also estimated through simulation and literature survey.On the basis of the torques found,the selection of motors was finally suggested,and the motors are to be installed to the humanoid robot. 展开更多
关键词 humanoid robot motor selection cooperative motion KINEMATICS
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Asymmetric vibration characteristics of two-cylinder four-stroke single-piston hydraulic free piston engine 被引量:5
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作者 任好玲 谢海波 +1 位作者 杨华勇 郭剑飞 《Journal of Central South University》 SCIE EI CAS 2014年第10期3762-3768,共7页
The structure and working principle of a two-cylinder four-stroke single-piston hydraulic free piston engine(HFPE) were introduced. The basic vibration equation of free piston assembly(FPA) was established based upon ... The structure and working principle of a two-cylinder four-stroke single-piston hydraulic free piston engine(HFPE) were introduced. The basic vibration equation of free piston assembly(FPA) was established based upon the energy conversion between the injected fuel and the friction together with the load. Both the theoretical and numerical results show that the vibration system of FPA is a nonlinear conservative autonomous system in one cycle. The FPA vibration is symmetric with constant amplitude when FPA is only driven by the compression pressure in the compression accumulator and that in the combustion chamber. When considering the friction and load, FPA could still achieve a stable vibration after a few cycles' adjustment whether the input energy is equal to the consumed energy or not. The vibration characteristics are different when FPA vibrates in the compression stroke and the expansion stroke, which is the unique feature of the single-piston HFPE. 展开更多
关键词 hydraulic free piston engine free piston assembly vibration system nonlinear conservative autonomous system asymmetry
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Novel Hyper-Redundant Manipulator-. Design, Study and Experiment
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作者 李彦明 马培荪 +3 位作者 秦昌俊 曹志奎 王建滨 朱海鸿 《Journal of Donghua University(English Edition)》 EI CAS 2003年第4期118-122,共5页
A novel hyper-redundant manipulator named RT1 is designed and studied. The unique feature of RT1 is all degrees of freedom (DOF) are actuated with only one motor via special designed hinge bar universal joints. The me... A novel hyper-redundant manipulator named RT1 is designed and studied. The unique feature of RT1 is all degrees of freedom (DOF) are actuated with only one motor via special designed hinge bar universal joints. The mechanisms of RT1 are introduced in detail. Some experiments are carried out in order to test the movability and adaptability of the manipulator. RT1 is actuated by pulse string and acts discretely. The discrete working space of RT1 is described and the parameter optimization for kinematical redundancy resolution is studied also. The optimization criterion is altering the design parameter as little as possible during manipulator's motion from the initial position to the expected position. An optimization example is given that is realized with Matlab optimize tool-box. 展开更多
关键词 hyper-redundant manipulator discrete manipulator optimize
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THE PATHOGENESIS OF EXPERIMENTAL MODEL OF MITOCHONDRIAL MYOPATHY INDUCED BY GERMANIUM DIOXIDE
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作者 李晓东 高枫 陈清棠 《Chinese Medical Sciences Journal》 CAS CSCD 2001年第3期157-160,共4页
Objective. The purpose of the study was to build up an animal model of mitochondrial myopathy in order to analyse the pathogenesis of the disease. Methods. The skeletal muscles from Wistar rats treated with germanium ... Objective. The purpose of the study was to build up an animal model of mitochondrial myopathy in order to analyse the pathogenesis of the disease. Methods. The skeletal muscles from Wistar rats treated with germanium dioxide for 24 weeks were analysed by histopathologic and electron- microscopic studies. A quantitative analysis was carried out in mitochondrial DNAs of these samples. The biological function of the model was determined. Results. An animal model of mitochondrial myopathy was built up, in which oxygen free radicals were increased and mitochondrial DNA copies were decreased contrasted with controls. Conclusion. It suggested that environmental toxin may play a role in the pathogenesis of mitochondrial myopathy. The increase of oxygen free radicals is an important link causing the disease. 展开更多
关键词 mitochondrial myopathy Wistar rat animal model
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Inverse kinematics of a heavy duty manipulator with 6-DOF based on dual quaternion 被引量:7
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作者 王恒升 占德友 +1 位作者 黄平伦 陈伟锋 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第7期2568-2577,共10页
An iterative method is introduced successfully to solve the inverse kinematics of a 6-DOF manipulator of a tunnel drilling rig based on dual quaternion, which is difficult to get the solution by Denavit-Hartenberg(D-H... An iterative method is introduced successfully to solve the inverse kinematics of a 6-DOF manipulator of a tunnel drilling rig based on dual quaternion, which is difficult to get the solution by Denavit-Hartenberg(D-H) based methods. By the intuitive expression of dual quaternion to the orientation of rigid body, the coordinate frames assigned to each joint are established all in the same orientation, which does not need to use the D-H procedure. The compact and simple form of kinematic equations, consisting of position equations and orientation equations, is also the consequence of dual quaternion calculations. The iterative process is basically of two steps which are related to solving the position equations and orientation equations correspondingly. First, assume an initial value of the iterative variable; then, the position equations can be solved because of the reduced number of unknown variables in the position equations and the orientation equations can be solved by applying the solution from the position equations, which obtains an updated value for the iterative variable; finally, repeat the procedure by using the updated iterative variable to the position equations till the prescribed accuracy is obtained. The method proposed has a clear geometric meaning, and the algorithm is simple and direct. Simulation for 100 poses of the end frame shows that the average running time of inverse kinematics calculation for each demanded pose of end-effector is 7.2 ms on an ordinary laptop, which is good enough for practical use. The iteration counts 2-4 cycles generally, which is a quick convergence. The method proposed here has been successfully used in the project of automating a hydraulic rig. 展开更多
关键词 heavy-duty manipulator dual quaternion robotic kinematics inverse kinematics(IK) iterative algorithm tunnel drilling rig
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Oxidation of Pyridine Bases by Hydrogen Peroxide 被引量:1
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作者 Ali-zadeh Nahmad Islam Nagieva Inara Tofik +2 位作者 Babaeva Badam Tofik Magerramov Abel Mamedali Nagiev Tofik Murtuza 《Journal of Chemistry and Chemical Engineering》 2011年第1期82-88,共7页
The interfering kinetics of the coherent synchronous reactions of hydrogen peroxide decomposition and the oxidation of pyridine derivatives have been studied experimentally. The regions of the selective oxidation of t... The interfering kinetics of the coherent synchronous reactions of hydrogen peroxide decomposition and the oxidation of pyridine derivatives have been studied experimentally. The regions of the selective oxidation of the pyridine derivatives have been found, and the optimal conditions for the production of4-vynilpyridine, 4-vynilpyridine N-monoxide, 2, 2-dipyridyl, and pyridine have been determined. The most probable synchronization mechanism is suggested for hydrogen peroxide decomposition and the free-radical chain oxidation of pyridine derivatives. The HO2 -radical plays the key role in this mechanism. The activation energies are calculated for the elementary steps of 4-ethylpyridine dehydrogenation. 展开更多
关键词 Free radical coherent synchronized CONJUGATION N-monooxidation determinant.
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Study of Properties in Superconducting Nanowires
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作者 梁芳营 王建华 张志刚 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第4期777-781,共5页
We consider a simple approach of standard Ginzburg-Landan free-energy functional for a wire to study the properties of superconducting nanowires, and analyze the problem of quantum and thermally activated phase slips.... We consider a simple approach of standard Ginzburg-Landan free-energy functional for a wire to study the properties of superconducting nanowires, and analyze the problem of quantum and thermally activated phase slips. In such systems one can consider a possibility for phase slips to be created not only due to thermal but also due to quantum fluctuations of a superconducting order parameter. We obtain some expressions of the free energy, the entropy, the specific heat and the bias current, respectively. The bias current I is a function of the temperature and the length of superconducting nanowires, and has a quantum phase slip. We obtain the stochastic dynamics of superconductiveresistive switching in hysteretic current-biased superconducting nanowires undergoing phase-slip fluctuations, and obtain the distribution of switching currents. Our results can be verified in modern experiments with superconducting nanowires. 展开更多
关键词 superconducting nanowires transport properties THERMODYNAMICS
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Mechanism and Kinetic of Free Radical Reactions for Propane Using theoretical Calculations 被引量:1
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作者 Abbas A- Ali Drea Nadia Izet 《Journal of Chemistry and Chemical Engineering》 2012年第6期563-573,共11页
Quantum calculation method has been used to understand and investigate the free radical reactions of propane with hydroxyl radical in vacuum through modem quantum mechanics that is package on hyperchem 8.02 program. O... Quantum calculation method has been used to understand and investigate the free radical reactions of propane with hydroxyl radical in vacuum through modem quantum mechanics that is package on hyperchem 8.02 program. Optimized structures and structural reactivates have been studied through bond stability and angles using DFT calculation based on the basis set 6-31G*. Energetic properties have been calculated like total energy, Gibbs free energy, entropy, heat of formation, and rate constant for all chemical species that's participate in the suggested reaction mechanism. Reaction mechanism and rate determining step had been suggested according to calculation of energy barrier values, and compares between the suggested competitive reactions for each probable reaction step. Suggested structures and the probable transition states have been studied. 展开更多
关键词 Free radicals reaction mechanism theoretical chemistry quantum mechanics rate determining step.
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CYLINDER-SPHERE 3-DOF ULTRASONIC MOTOR AND ITS CONTROL
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作者 HUANGWei-qing ZHANFeng-jiang ZHAOChun-sheng 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2004年第4期272-276,共5页
A three degree-of-freedom (DOF) ultrasonic motor (USM) with a cylinder-shaped stator and a spherical rotor is introduced, which uses one first order longitudinal and two second order bending nature vibration modes of ... A three degree-of-freedom (DOF) ultrasonic motor (USM) with a cylinder-shaped stator and a spherical rotor is introduced, which uses one first order longitudinal and two second order bending nature vibration modes of the cylinder. Control strategies for the two DOF trajectory following are studied and applied to the prototype USM. Vibration amplitude control is employed for speed regulation. The first trajectory following strategy is a step-by-step interpolation. The second strategy is vector decomposition control. Three pulse width modulation (PWM) methods for the exciting voltage regulation are investigated. These methods are compared and verified by several experiments. The key is to keep the phase differences of the three vibration constants and small exciting voltage distortion while the exciting voltages are changed for simplifing the control process and obtaining good control performance. The vector control method has advantages of small trajectory following error, smooth moving and low noise. 展开更多
关键词 MULTI-DEGREE-OF-FREEDOM ultrasonic motor CONTROL
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深水通信
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作者 潘启刚 《情报指挥控制系统与仿真技术》 2003年第8期25-28,共4页
近一百多年来,对于一个海军指挥官来说,潜艇已经发展成为可以使用的最有效的武器平台之一,它在传感器、武器、动力装置、续航力和船体等方面都有显著的提高.然而在将上述进展集成为对水面舰队的直接支持方面,可说是成效甚微.这有许多方... 近一百多年来,对于一个海军指挥官来说,潜艇已经发展成为可以使用的最有效的武器平台之一,它在传感器、武器、动力装置、续航力和船体等方面都有显著的提高.然而在将上述进展集成为对水面舰队的直接支持方面,可说是成效甚微.这有许多方面的原因,但是最令战术家们感到灰心的是缺乏实时通信能力.当然,随着大量设备获得使用许可,在潜艇通信方面已经取得了很大进展.然而,几乎所有当前系统的技术规格都不符合潜艇对自由机动的要求,特别是在深水通信中.遗憾的是,当潜艇要返回到潜望深度听清楚它的广播电信时,除了使用"通信路由"或定时通信外,另无选择地这会失去许多使用权限.两次听清楚广播时间间隔可长达18~24小时,最糟的情况下可能意味着全体人员几乎一整天不知道战争爆发或作战方案的改变. 展开更多
关键词 潜艇 深水通信 无线电通信 水下电话 一次性通信浮标 声信号 自由机动
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Structural Synthesis, Dynamic Modeling and Analysis of a 3-DOF Asymmetric Parallel Mechanism
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作者 Rynaldo Zanotele Hemerly de Almeida and Tarcisio Antonio Hess-Coelho 《Journal of Mechanics Engineering and Automation》 2011年第6期481-490,共10页
Most research papers about parallel kinematic chainmechanisms investigate symmetric robot manipulators, in which all the limbs connecting the end-effector to the fixed based are composed by the same sequence of links ... Most research papers about parallel kinematic chainmechanisms investigate symmetric robot manipulators, in which all the limbs connecting the end-effector to the fixed based are composed by the same sequence of links and joints. Contrarily, in some manipulation tasks the velocity and stiffness requirements are anisotropic. In such cases, the asymmetric parallel kinematic chain mechanisms may offer advantages. This work objective is to present the synthesis, dynamic modeling and analysis of a 3-dof asymmetric parallel chain mechanism, conceived as a robot manipulator for pick-and-place operations. Firs't, a structural synthesis, resulting in a three translations end-effector, and a kinematic modeling are carried out. Then, the inverse dynamic modeling is developed by employing the virtual work principle. Based on the model equations and on the saturation of the mechanism actuators, a maximum acceleration analysis is performed and shows that although the mechanism has a parallel architecture its actuators influences on the 3-dof are quite decoupled. 展开更多
关键词 PARALLEL ASYMMETRIC SYNTHESIS DYNAMIC modeling.
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Effect of Force Adaptation in Mechanics
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作者 Konstantin Samson Ivanov 《Journal of Mechanics Engineering and Automation》 2011年第3期163-180,共18页
Discovery of effect of force adaptation in mechanics is presented. The discovery is based on use of the mobile closed mechanical contour for force transfer from the mechanism input link to an output link, According to... Discovery of effect of force adaptation in mechanics is presented. The discovery is based on use of the mobile closed mechanical contour for force transfer from the mechanism input link to an output link, According to discovery the motion transfer can be carried out by Assur structural group in the form of the mobile closed contour, and the output link is the link with one degree of freedom. The received mechanical system includes an input link, an output link and the closed contour placed between them as fourth class Assur structural group. The kinematic chain has two degrees of freedom. However the closed contour imposes an additional constraint on relative motion of its links. The carried out discovery allows providing the variable transfer ratio only due to the variable external load. Mechanical properties of the closed contour allow providing the required transfer ratio independently, smart and automatically. 展开更多
关键词 Force adaptation closed contour constraint.
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Fluid dynamic modeling of a free piston engine with labyrinth seals 被引量:4
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作者 Jaakko Larjola Juha Honkatukia +1 位作者 Petri Sallinen Jari Backman 《Journal of Thermal Science》 SCIE EI CAS CSCD 2010年第2期141-147,共7页
Preliminary design and simulation of a free piston engine suitable for small-scale energy production in distributed energy systems is presented in this paper.The properties,particularly the properties of gas seals of ... Preliminary design and simulation of a free piston engine suitable for small-scale energy production in distributed energy systems is presented in this paper.The properties,particularly the properties of gas seals of the engine are simulated using a simulation program developed for this case,and the results are utilized in preliminary main design parameter selection.The engine simulation program was developed by combining and modifying the source codes of the simulation and calculation programs obtained from Helsinki University of Technology,Tampere University of Technology,and Lappeenranta University of Technology.Because of the contact-free labyrinth seal used in the piston,the efficiency of the motor is lower than the efficiency of a conventional motor with oil lubricated piston rings.On the other hand,the lack of bearing losses,and the lack of losses associated with a crankshaft system and a gearbox,as well as the lack of lubrication oil expenses,compensates this effect.As a net result,this new motor would perform slightly better than the conventional one.Being completely oil-free,it is very environmentally friendly,and its exhaust gases are completely free of oil residuals which are causing problems in normal gas motors. 展开更多
关键词 free piston engine distributed energy systems SIMULATION labyrinth seal
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Design,fabrication and kinematics of a bio-inspired robotic bat wing 被引量:2
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作者 YIN Dong Fu ZHANG Zhi Sheng 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2016年第12期1921-1930,共10页
The current work is oriented toward the development of a novel biologically inspired bat aerial robot with morphing wings. Based on the flight characteristics data of natural bats(Eptesicus fuscus), a novel four degre... The current work is oriented toward the development of a novel biologically inspired bat aerial robot with morphing wings. Based on the flight characteristics data of natural bats(Eptesicus fuscus), a novel four degrees of freedom robotic bat wing was developed to emulate the movements of bat wing. The design, fabrication, programing and wind tunnel experiments of the robot bat wing are described in this paper. Based on this robotic wing, the influence of flap amplitude, wind speed, flight frequency, downstroke ratio and stroke plane angle as well as the contributions of flap, elbow, sweep and wrist motions on the aerodynamic force and mechanical power were studied and analyzed. Results of wind tunnel experiments validated that higher lift would bring greater power consumption, and the flap motion would generate the most force and need more energy expenditure compared with other motions of bat. The experimental results suggest that the flap and fold motions are indispensable to make a robotic bat wing that has a better flight performance. This study provides some implications and a better understanding for the future robotic bat. 展开更多
关键词 bio-inspiration wing robotic bat flight kinematics wrist motion
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Theoretical study of mechanism and kinetics for the addition of hydroxyl radical to phenol
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作者 WU PengZhen LI Jian +1 位作者 LI ShuJin TAO Fu-Ming 《Science China Chemistry》 SCIE EI CAS 2012年第2期270-276,共7页
The reaction mechanism and kinetics for the addition of hydroxyl radical (OH) to phenol have been investigated using the hybrid density functional (B3LYP) method with the 6-31++G(2dp, 2dr) basis set and the co... The reaction mechanism and kinetics for the addition of hydroxyl radical (OH) to phenol have been investigated using the hybrid density functional (B3LYP) method with the 6-31++G(2dp, 2dr) basis set and the complete basis set (CBS) method using APNO basis sets, respectively. The equilibrium geometries, energies, and thermodynamics properties of all the stationary points along the addition reaction pathway are calculated. The rate constants and the branching ratios of each channel are evaluated using classical transition state theory (TST) in the temperature range of 210 to 360 K, to simulate temperatures in all parts of the troposphere. The ortho addition pathway is dominant and accounts for 99.8%-96.7% of the overall adduct products from 210 to 360 K. The calculated rate constants are in good agreement with existing experimental values. The addition reaction is irreversible. 展开更多
关键词 PHENOL hydroxyl radical addition reaction quantum chemistry calculation transition state theory
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