To degrade the organic compounds in the electroplating wastewater,magnetic field was tentatively introduced into electrocatalytic oxidation on Ti-PbO2 anode.The magnetic field assisted electrocatalytic oxidation can p...To degrade the organic compounds in the electroplating wastewater,magnetic field was tentatively introduced into electrocatalytic oxidation on Ti-PbO2 anode.The magnetic field assisted electrocatalytic oxidation can promote anion movement and the generation of active species,resulting more organic compounds to be oxidized and degraded.Oxidation parameters such as treatment time,current density and initial pH of the wastewater were systematically discussed and optimized.The mineralization of organic compounds is improved by over 15% under a magnetic density of 22 mT while the current density is 50 A/m2,pH is 1.8 and the reaction time is 1.5 h.The results indicate that the magnetic field assisted electrocatalytic oxidation has considerable potential in electroplating wastewater treatment.展开更多
Based on the literature review of environmental anti-pollution researches, this paper analyzes the administra- tive mechanism of Huaihe River anti-pollution with game theory. Based on the quantitative analysis on thre...Based on the literature review of environmental anti-pollution researches, this paper analyzes the administra- tive mechanism of Huaihe River anti-pollution with game theory. Based on the quantitative analysis on three correspond- ing game models with four players including local residents, enterprises, local governments and competent authorities at higher levels, this paper demonstrates four main shortcomings of current administrative mechanism of Huaihe River anti-pollution system, including low emission cost, low connivance cost, overemphasis on heavy fine of the enterprises, neglect of the punishment on the local departments and intersected administrative mechanism. This paper sets up anti- pollution administrative mechanism, combining economic method with noneconomic method, government control with market mechanism, and introducing public participation. At last, this paper proposes policies, such as implementing emissions trading system, reforming public participation system, and reforming government’s environmental protection mechanism to promote law enforcement.展开更多
Persistent organic pollutants (POPs) in soils are an environmental concern due to their long-term bioavailability, which could be reduced by adding adsorbents. However, testing of these adsorbents is necessary prior...Persistent organic pollutants (POPs) in soils are an environmental concern due to their long-term bioavailability, which could be reduced by adding adsorbents. However, testing of these adsorbents is necessary prior to widespread field application. The effects of three adsorbents, nano-organic montmorillonite, nano-organic silicon dioxide (SiOs), and activated carbon, on hexachlorobenzene (HCB) and pentachlorobenzene (PeCB) accumulation in rice (Oryza sativa L.) plants were tested in a greenhouse experiment using two soils, a Hydragric Acrisol (Ac) and a Gleyi-Stagnic Anthrosol (An). The bioconcentration factors (BCFs) of HCB and PeCB to rice roots were 2.3-3.7 and 2.0 3.0 times those to rice shoots, respectively. The applications of the three adsorbents decreased HCB and PeCB extractability in Ac, while only the application of activated carbon decreased their extractability in An. The bioavailability of HCB and PeCB to rice plants in Ac was higher than that in An. In Ac, the applications of nano-organic SiOs and activated carbon decreased the BCF of HCB to rice roots by 16.1% and 26.8%, respectively, whereas only the application of activated carbon decreased the BCF of PeCB to rice roots by 31.4%, compared to the control. In An, only the application of activated carbon decreased the BCFs of HCB and PeCB to rice roots by 22.9% and 18.2%, respectively, compared to the control. However, the application of nano-organic montmorillonite inhibited rice growth in both soils. The results of this study suggested that the effectiveness of adsorbents would vary with pollutant and soil types, providing a reference point for developing efficient adsorbents to reduce the ecological risk of POPs.展开更多
基金Project(2008ZX07101-006-09) supported by the Major Science and Technology Program for Water Pollution Control and Treatment of China
文摘To degrade the organic compounds in the electroplating wastewater,magnetic field was tentatively introduced into electrocatalytic oxidation on Ti-PbO2 anode.The magnetic field assisted electrocatalytic oxidation can promote anion movement and the generation of active species,resulting more organic compounds to be oxidized and degraded.Oxidation parameters such as treatment time,current density and initial pH of the wastewater were systematically discussed and optimized.The mineralization of organic compounds is improved by over 15% under a magnetic density of 22 mT while the current density is 50 A/m2,pH is 1.8 and the reaction time is 1.5 h.The results indicate that the magnetic field assisted electrocatalytic oxidation has considerable potential in electroplating wastewater treatment.
文摘Based on the literature review of environmental anti-pollution researches, this paper analyzes the administra- tive mechanism of Huaihe River anti-pollution with game theory. Based on the quantitative analysis on three correspond- ing game models with four players including local residents, enterprises, local governments and competent authorities at higher levels, this paper demonstrates four main shortcomings of current administrative mechanism of Huaihe River anti-pollution system, including low emission cost, low connivance cost, overemphasis on heavy fine of the enterprises, neglect of the punishment on the local departments and intersected administrative mechanism. This paper sets up anti- pollution administrative mechanism, combining economic method with noneconomic method, government control with market mechanism, and introducing public participation. At last, this paper proposes policies, such as implementing emissions trading system, reforming public participation system, and reforming government’s environmental protection mechanism to promote law enforcement.
基金supported by the Open Fund Project of Jiangsu Key Laboratory of Agricultural Meteorology, Nanjing University of Information Science and Technology, China (No. JKLAM1605)
文摘Persistent organic pollutants (POPs) in soils are an environmental concern due to their long-term bioavailability, which could be reduced by adding adsorbents. However, testing of these adsorbents is necessary prior to widespread field application. The effects of three adsorbents, nano-organic montmorillonite, nano-organic silicon dioxide (SiOs), and activated carbon, on hexachlorobenzene (HCB) and pentachlorobenzene (PeCB) accumulation in rice (Oryza sativa L.) plants were tested in a greenhouse experiment using two soils, a Hydragric Acrisol (Ac) and a Gleyi-Stagnic Anthrosol (An). The bioconcentration factors (BCFs) of HCB and PeCB to rice roots were 2.3-3.7 and 2.0 3.0 times those to rice shoots, respectively. The applications of the three adsorbents decreased HCB and PeCB extractability in Ac, while only the application of activated carbon decreased their extractability in An. The bioavailability of HCB and PeCB to rice plants in Ac was higher than that in An. In Ac, the applications of nano-organic SiOs and activated carbon decreased the BCF of HCB to rice roots by 16.1% and 26.8%, respectively, whereas only the application of activated carbon decreased the BCF of PeCB to rice roots by 31.4%, compared to the control. In An, only the application of activated carbon decreased the BCFs of HCB and PeCB to rice roots by 22.9% and 18.2%, respectively, compared to the control. However, the application of nano-organic montmorillonite inhibited rice growth in both soils. The results of this study suggested that the effectiveness of adsorbents would vary with pollutant and soil types, providing a reference point for developing efficient adsorbents to reduce the ecological risk of POPs.