The effects of oxidation-reduction treatment and mechanical activation on the hydrochloric acid leaching performance of Panxi ilmenite concentration were investigated.The results show that both of oxidation-reduction ...The effects of oxidation-reduction treatment and mechanical activation on the hydrochloric acid leaching performance of Panxi ilmenite concentration were investigated.The results show that both of oxidation-reduction treatment and mechanical activation significantly accelerate the extraction of Fe,Ca and Mg from Panxi ilmenite concentration;however,the CaO and MgO contents of the calcined residues obtained from oxidized-reduced ilmenite concentration are higher than the standard values required by chlorination process.The Ca and Mg in oxidized-reduced ilmenite concentration can be leached much faster after mechanical activation,yielding a synthetic rutile which meets the requirements of chlorination process containing 90.50% TiO2 and 1.37% total iron as well as combined CaO and MgO of 1.00%.The optimum oxidation and reduction conditions are as follows：oxidization at 900 ℃ in the presence of oxygen for 15 min and reduction at 750 ℃ by hydrogen for 30 min.展开更多
The characterization and H2SO4 leaching behavior of a Nigerian ilmenite ore following mechanical activation and alkali roasting were investigated. The effects of NaOH/ore ratio, H2SO4 concentration, leaching and roast...The characterization and H2SO4 leaching behavior of a Nigerian ilmenite ore following mechanical activation and alkali roasting were investigated. The effects of NaOH/ore ratio, H2SO4 concentration, leaching and roasting temperature on the Ti recovery from the milled ore were examined. The results show that mechanical activation significantly enhances the dissolution of ilmenite ore. Under the leaching conditions of 90 °C, 60% （v/v） H2SO4 and 4 h, about 72% Ti extraction was obtained from a milled ore roasted at 850 °C with 60% NaOH. X-ray diffraction （XRD） phase analysis of the roasted mass, water treated residue and leach residue supports the reaction mechanism and experimental results.展开更多
The effect of mechanical activation on the granulometric parameters,microstructure,and leaching efficiency of chalcopyrite was evaluated,and the occurrence/transition of agglomeration and aggregation was discussed.The...The effect of mechanical activation on the granulometric parameters,microstructure,and leaching efficiency of chalcopyrite was evaluated,and the occurrence/transition of agglomeration and aggregation was discussed.The results showed that in 8 h of milling treatment,the agglomeration and the microstructure did not affect each other.However,with prolonging milling time,the crystallite size tended to reach a saturation value,and the stagnating microstructural changes led to the replacement of agglomeration by aggregation.The leaching results indicated that the mechanical activation can strongly enhance the reactivity of chalcopyrite and the hindering effect of aggregation on leaching was considerably greater than that of agglomeration.Consequently,after 8 h of milling,the maximum Cu leaching rate of 80.13%was achieved after 4 h of acid leaching.展开更多
According to the different engineering mechanical states of top coal caving andnormal stoping of gaseous loose thick coal seams,the dialectical relation between thiscaving method and dynamic disasters was analyzed by ...According to the different engineering mechanical states of top coal caving andnormal stoping of gaseous loose thick coal seams,the dialectical relation between thiscaving method and dynamic disasters was analyzed by simulating the change of stressstates in the process of top coal initial caving with different mining and caving ratios basedon the ANSYS10.0.The variation of elastic energy and methane expansion energy duringfirst top coal caving was analyzed by first weighting and periodic weighting and combiningwith coal stress and deformation distribution of top coal normal stoping as well as positiveand negative examples in top coal caving of outburst coal seam.The research shows thatthe outburst risk increases along with the increase of the caving ratio in the initial miningstage.In the period of normal stoping,when the mining and caving ratio is smaller than1:3 and hard and massive overlying strata do not exist (periodic weighting is not obvious),it is beneficial to control ground stress leading type outburst.Thus,it is unreasonable toprohibit top coal caving in dangerous and outburst prone areas.展开更多
A mechanochemical method with SiO_(2)as the grinding aid was used to enhance the leaching efficiencies of Co and Li from spent lithium batteries(LIBs).Experiment results show that the optimal leaching efficiencies of ...A mechanochemical method with SiO_(2)as the grinding aid was used to enhance the leaching efficiencies of Co and Li from spent lithium batteries(LIBs).Experiment results show that the optimal leaching efficiencies of 94.91%for Co and 97.22%for Li were obtained under the parameters of SiO_(2)/LiCoO_(2)mass ratio of 1:1,grinding speed of 500 r/min and grinding time of 30 min in citric acid.Characterization results indicate that the surficial properties of LiCoO_(2)were changed after mechanochemical grinding treatment due to the newly generated surfaces on LiCoO_(2).Meanwhile,the incompletely coordinated atomic structure and defective lattice structure lead to the activation of LiCoO_(2).The reduction effect of carbon black on Co^(3+)under the action of mechanical forces increases its leaching efficiencies in the citric acid solution.The proposed process was found efficiently to recover Co and Li from LiCoO_(2).展开更多
基金supports from the National Natural Science Foundation of China (No.52264030)the Yunnan Fundamental Research Projects,China (No.202201BE070001-048)the Special Fund Projects of Central Government Guiding Local Science and Technology Development,China (No.202107AA110002).
基金Project(2009FJ3082)supported by Research Project of Science and Technology in Hunan Province,ChinaProject(2007CB613606)supported by the National Basic Research Program of China
文摘The effects of oxidation-reduction treatment and mechanical activation on the hydrochloric acid leaching performance of Panxi ilmenite concentration were investigated.The results show that both of oxidation-reduction treatment and mechanical activation significantly accelerate the extraction of Fe,Ca and Mg from Panxi ilmenite concentration;however,the CaO and MgO contents of the calcined residues obtained from oxidized-reduced ilmenite concentration are higher than the standard values required by chlorination process.The Ca and Mg in oxidized-reduced ilmenite concentration can be leached much faster after mechanical activation,yielding a synthetic rutile which meets the requirements of chlorination process containing 90.50% TiO2 and 1.37% total iron as well as combined CaO and MgO of 1.00%.The optimum oxidation and reduction conditions are as follows：oxidization at 900 ℃ in the presence of oxygen for 15 min and reduction at 750 ℃ by hydrogen for 30 min.
基金the Institute of Minerals and Materials Technology,Bhubaneswar-751013,India,for providing facilities used for this research
文摘The characterization and H2SO4 leaching behavior of a Nigerian ilmenite ore following mechanical activation and alkali roasting were investigated. The effects of NaOH/ore ratio, H2SO4 concentration, leaching and roasting temperature on the Ti recovery from the milled ore were examined. The results show that mechanical activation significantly enhances the dissolution of ilmenite ore. Under the leaching conditions of 90 °C, 60% （v/v） H2SO4 and 4 h, about 72% Ti extraction was obtained from a milled ore roasted at 850 °C with 60% NaOH. X-ray diffraction （XRD） phase analysis of the roasted mass, water treated residue and leach residue supports the reaction mechanism and experimental results.
基金the Special Fund for the National Natural Science Foundation of China(U1608254)the National Key R&D Program of China(2018YFC1902002).
文摘The effect of mechanical activation on the granulometric parameters,microstructure,and leaching efficiency of chalcopyrite was evaluated,and the occurrence/transition of agglomeration and aggregation was discussed.The results showed that in 8 h of milling treatment,the agglomeration and the microstructure did not affect each other.However,with prolonging milling time,the crystallite size tended to reach a saturation value,and the stagnating microstructural changes led to the replacement of agglomeration by aggregation.The leaching results indicated that the mechanical activation can strongly enhance the reactivity of chalcopyrite and the hindering effect of aggregation on leaching was considerably greater than that of agglomeration.Consequently,after 8 h of milling,the maximum Cu leaching rate of 80.13%was achieved after 4 h of acid leaching.
文摘According to the different engineering mechanical states of top coal caving andnormal stoping of gaseous loose thick coal seams,the dialectical relation between thiscaving method and dynamic disasters was analyzed by simulating the change of stressstates in the process of top coal initial caving with different mining and caving ratios basedon the ANSYS10.0.The variation of elastic energy and methane expansion energy duringfirst top coal caving was analyzed by first weighting and periodic weighting and combiningwith coal stress and deformation distribution of top coal normal stoping as well as positiveand negative examples in top coal caving of outburst coal seam.The research shows thatthe outburst risk increases along with the increase of the caving ratio in the initial miningstage.In the period of normal stoping,when the mining and caving ratio is smaller than1:3 and hard and massive overlying strata do not exist (periodic weighting is not obvious),it is beneficial to control ground stress leading type outburst.Thus,it is unreasonable toprohibit top coal caving in dangerous and outburst prone areas.
基金financially supported by the Key-Area Research and Development Program of Guangdong Province,China(No.2020B090919003)the National Natural Science Foundation of China(Nos.51574234,51904295)+2 种基金the Special Fund(Social Development)Project of Key Research and Development Plan of Jiangsu Province,China(No.BE2019634)the Science Foundation of Jiangsu Province,China(No.BK20180647)the Postdoctoral Science Foundation of China(No.2018M640538)。
文摘A mechanochemical method with SiO_(2)as the grinding aid was used to enhance the leaching efficiencies of Co and Li from spent lithium batteries(LIBs).Experiment results show that the optimal leaching efficiencies of 94.91%for Co and 97.22%for Li were obtained under the parameters of SiO_(2)/LiCoO_(2)mass ratio of 1:1,grinding speed of 500 r/min and grinding time of 30 min in citric acid.Characterization results indicate that the surficial properties of LiCoO_(2)were changed after mechanochemical grinding treatment due to the newly generated surfaces on LiCoO_(2).Meanwhile,the incompletely coordinated atomic structure and defective lattice structure lead to the activation of LiCoO_(2).The reduction effect of carbon black on Co^(3+)under the action of mechanical forces increases its leaching efficiencies in the citric acid solution.The proposed process was found efficiently to recover Co and Li from LiCoO_(2).
