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机械剪切剥离法制备石墨烯研究进展 被引量:5
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作者 王家涛 魏镜弢 +2 位作者 钱杰 吴张永 王庭有 《电子科技》 2020年第12期44-48,66,共6页
石墨烯优异的电学、光学和力学性能掀起了多领域的研究热潮,其制备方法也成为重点研究方向。机械剪切剥离法成本低,操作简单,且不会破坏石墨烯本征特性等特性,备受研究者关注。文中介绍了石墨烯的性质和剥离机理,并阐述了机械剥离法中... 石墨烯优异的电学、光学和力学性能掀起了多领域的研究热潮,其制备方法也成为重点研究方向。机械剪切剥离法成本低,操作简单,且不会破坏石墨烯本征特性等特性,备受研究者关注。文中介绍了石墨烯的性质和剥离机理,并阐述了机械剥离法中低能纯剪法、三辊磨剥法和球磨法,比较了各方法的特点及面临的问题。由于球磨法是目前最有望大规模制造石墨烯的方法,故文中优化了球磨工艺,提出了一种磨盘式结构球磨机。该球磨机有效避免了磨球之间的撞击力,保护石墨晶格免于破环,提高了剪切效率。 展开更多
关键词 石墨烯 剥离机理 剪切 机械剥离制备 球磨设备 磨盘式研磨
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2D materials via liquid exfoliation:a review on fabrication and applications 被引量:27
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作者 Chengxue Huo Zhong Yan +1 位作者 Xiufeng Song Haibo Zeng 《Science Bulletin》 SCIE EI CAS CSCD 2015年第23期1994-2008,共15页
Since graphene was discovered, the study of two-dimensional(2D) materials with atomic thickness has become a hot spot. To prepare different 2D materials,different methods have been groped, such as mechanical exfoliati... Since graphene was discovered, the study of two-dimensional(2D) materials with atomic thickness has become a hot spot. To prepare different 2D materials,different methods have been groped, such as mechanical exfoliation, chemical vapor deposition(CVD), liquid-phase exfoliation. This review mainly introduced the sonication liquid-phase exfoliation, an effective method to prepare 2D materials. Compared with mechanical exfoliation and CVD methods, liquid-phase exfoliation is convenient and costeffective and provides high yield. We focused on both theoretical and experimental details of this method. This method was reviewed according to the development of 2D materials from graphene, h-BN to transition metal chalcogenides(TMDs) and black phosphorus nanosheets.We discussed the applications of liquid-exfoliated 2D materials including micro- and nanoelectrical devices,photoelectric devices, and energy storage devices. 展开更多
关键词 Liquid exfoliation · 2D materials ·Graphene · Black phosphorene · Antimonene
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