电子装备机电耦合研究的现状及发展研究

在一些比较极端的天气情况下,电子装备的机电耦合问题就会变得非常突出,而这项问题也严重制约了电子装备自身的发展.高精度的电子装备适运用于多个领域,其特点就是机电耦合,其中电磁和机械之间存在着某些特殊的联系.本文首先分析了电子装备机电耦合的现状,重点探讨了高精度电子设备在未来的发展趋势,以期为相关人员提供参考.

论高性能电子装备机电耦合技术现状与发展

高性能电子装备被广泛应用于陆、海、空、天等领域中的雷达、深空探测、射电天文、通信、导航、遥感等方面,其设计与制造水平是国家整体科技水平与实力的重要体现。系统回顾了高性能电子装备机电一体化技术的发展历程,论述机电分离、机电综合、机电耦合等三个不同发展阶段的特征与内涵,进而明确机电一体化技术鲜明的代际演进,并揭示电子装备机电耦合技术的内涵与特征。在此基础上,结合反射面天线、平面裂缝天线、有源相控阵天线等典型实例,建立电子装备电磁场-位移场-温度场的场耦合理论模型,揭示非线性机械结构因素对平板裂缝天线、有源相控阵天线等电子装备电性能的影响机理。最后,面向未来高性能电子装备的发展趋势,探讨机电耦合理论与技术需应对的新挑战。

Photovoltaic Performance of Triphenylamine Dyes-sensitized Solar Cells Employing Cobalt Redox Shuttle and Influence of π-conjugated Spacers

Developing photosensitizers suitable for the cobalt electrolyte and understanding the structure-property relationship of organic dyes is warranted for the dye-sensitized solar cells （DSSCs）. The DSSCs incorporating tris（1,10-phenanthroline）eobalt（Ⅱ/Ⅲ）-based redox elec- trolyte and four synthesized organic dyes as photosensitizers are described. The photovoltaic performance of these dyes-sensitized solar cells employing the cobalt redox shuttle and the influences of the w-conjugated spacers of organic dyes upon the photovoltage and photocur- rent of mesoscopic titania solar cells are investigated. It is found that organic dyes with thiophene derivates as linkers are suitable for DSSCs employing cobalt electrolytes. DSSCs sensitized with the as-synthesized dyes in combination with the cobalt redox shuttle yield an overall power conversion efficiency of 6.1% under 100 mW/cm2 AM1.5 G illumination.

SrTiO3/BiOI heterostructure: Interfacial charge separation, enhanced photocatalytic activity, and reaction mechanism

Heterostructured photocatalysts provide an effective way to achieve enhanced photocatalytic performances through efficient charge separation.Although both wide-and narrow-band-gap photocatalysts have been widely investigated,the charge separation and transfer mechanism at the contacting interface of the two has not been fully revealed.Here,a novel SrTiO3/BiOI(STB)heterostructured photocatalyst was successfully fabricated by using a facile method.The heterostructure in the photocatalyst extends the photoabsorption to the visible light range,and thus,high photocatalytic NO removal performance can be achieved under visible light irradiation.A combination of experimental and theoretical evidences indicated that the photogenerated electrons from the BiOI semiconductor can directly transfer to the SrTiO3 surface through a preformed electron delivery channel.Enhanced electron transfer was expected between the SrTiO3 and BiOI surfaces under light irradiation,and leads to efficient ROS generation and thus a high NO conversion rate.Moreover,in situ diffused reflectance infrared Fourier transform spectroscopy revealed that STB can better inhibit the accumulation of the toxic intermediate NO2 and catalyze the NO oxidation more effectively.This work presents a new insight into the mechanism of the interfacial charge separation in heterostructures and provides a simple strategy to promote the photocatalytic technology for efficient and safe air purification.

Recovering metals from printed circuit board scrap by a mechanical separation process

A mechanical separation process was developed for recovering metals from printed circuit board(PCB) scrap;it included three steps:impact crushing,sieving and fluidization separation.The mechanism of the technique was based on the difference in the crushabilities of metallic and nonmetallic materials in the PCBs that led to the concentrated distribution of metals in particles of larger sizes and nonmetals mostly in particles of smaller sizes.It was found that crushed PCB particles from 0.125 mm to 1.000 mm contained about 80% of metals in the PCBs.Metals acquired satisfactory liberation in particles smaller than 0.800 mm.The crushed PCB particles were sieved into fractions of different size ranges.Each fraction separately went through a gas-solid fluidized bed operating at a selected optimal gas velocity for the specific size range.Approximately 95% of metals in printed circuit board particles from 0.125 mm to 0.800 mm was recovered by the gas-fluidized bed separator at the selected optimal gas velocity.However,separation of metals from particles smaller than 0.125 mm was not satisfactory.Further study is needed on metal recovery from fine particles.

All-organic covalent organic frameworks/perylene diimide urea polymer S-scheme photocatalyst for boosted H_(2) generation

Conjugated covalent organic frameworks(COFs)hold great promise in photocatalytic hydrogen evolution owing to their high crystallinity,large surface area,and distinct structure.However,COFs exhibit poor charge separation.Therefore,investigating highly effective COF-based photocatalysts is crucial.For the first time,conjugated COF/perylene diimide urea polymer(PUP)all-organic heterostructure with S-scheme interfacial charge-transfer channels was successfully developed and manufactured via in situ coupling of the two-dimensional triazine-based imine-linked COF(denoted as TATF-COF)with PUP.The optimal photocatalytic hydrogen-evolution rate of 94.5 mmol h^(-1) g^(-1) for TATF-COF/PUP is 3.5 times that of pure TATF-COF and is comparable to or even higher than that of the previously reported COF-based photocatalysts,resulting in an apparent quantum efficiency of up to 19.7%at 420 nm.The improved directional S-scheme charge transfer driven by the tuned built-in electric field and enhanced oxidation and reduction reaction rates of the photogenerated carriers contribute synergistically to the boosted photocatalytic H_(2) evolution.Experiments and theoretical studies reveal plausible H_(2) evolution and spatial S-scheme charge-separation mechanisms under visible-light irradiation.This study provides advanced methods for constructing all-organic S-scheme high-efficiency photocatalysts by the modulation of band structures.

Recovery of Dyestuffs from Dilute Solution with Two-phase Electrophoresis

Two-phase electrophoresis was used to separate the dyestuffs from their dilute solutions. Several dyestuffs (naphthol green B, acid-chrome blue K, methyl blue and direct fast torquoise blue GL, and n-butanol) were treated in a self-designed experimental setup and the mass transfer characteristics in this process were studied. The results confirm the potential of this technique for recovering dyestuffs from their dilute solutions.

New finding on out-of-step separation configuration of large-scale power systems

In this paper,two new concepts—“main out-of-step mode” and “minor out-of-step mode”—are proposed for power system reliability analysis. Large-scale power system studies found that out-of-step generator groups may have characteristics of the main out-of-step mode and the minor out-of-step mode. The generator groups with main out-of-step modes can determine the out-of-step interface of the large-scale power system,while generators with the minor out-of-step modes cannot play such a role. Therefore,the method of capturing the out-of-step interface by seeking the lowest voltage point(the out-of-step center) can only group the generators with the main out-of-step modes,and may fail to combine the generators with the minor out-of-step modes into proper coherent generator groups. Thus,it is necessary in engineering applications to equip the generators that are likely to have the characteristics of the minor out-of-step modes with separation devices based on off-line simulation studies in order to reduce the risk of further accidents caused by these generators after system separation.

Electrochemical mechanism of rusticyanin (Rus.) isolated from A.ferrooxidans measured by Rus.-ZnS-QDs/L-Cys/Au electrode

Electrochimcal behaviors of rusticyanin （Rus.） isolated from Acidithiobacillus ferrooxidans were investigated through Rus.-ZnS-QDs/L-Cys/Au electrode. The cyclic voltammetric results indicate that rusticyanin immobilized on the surface of Rus.-ZnS-QDs/L-Cys/Au electrode can undergo a direct quasi-reversible electrochemical reaction. The immobilized rusticyanin is not denatured and still retains its activity in the temperature range of 19-43 ℃. The reduction ability of the protein increases and its oxidation ability becomes weak with the increase of pH from 6.0 to 7.8. Fe^2＋ ions in the solution can promote the electron transfer kinetics of the immobilized rusticyanin and make its peak potentials （φp） markedly move negatively.

Estimation of Separation of Electrolytes and Organic Compounds by Nanofiltration Membranes Using an Irreversible Thermodynamic Modei

Nanofiltration separation has become a popular technique for removing largeorganic molecules and inorganic substances from water. It is achieved by a combination of threemechanisms: electrostatic repulsion, sieving and diffusion. In the present work, a model based onirreversible thermodynamics is extended and used to estimate rejection of inorganic salts andorganic substances. Binary systems are modeled, where the feed contains an ion that is much lesspermeable to the membrane as compared with the other ion. The two model parameters are estimated byfitting the model to the experimental data. Variation of these parameters with the composition ofthe feed is described by an empirical correlation. This work attempts to describe transport throughthe nanofiltration membranes by a simple model.

电子装备机电耦合研究的现状与发展

高精度电子装备被广泛应用于陆、海、空、天等各个领域.针对高性能、高精度电子装备中普遍存在的机电耦合问题,本文系统地介绍了国内外电子装备研制的机电分离、机电综合与机电耦合三个阶段的情况,重点讨论了机电耦合的概念、理论与方法,进而阐述了机电耦合研究的现状与内涵、主要进展、研究内容、研究热点及发展趋势.

Substituent Effects on the Photocatalytic Properties of a Symmetric Covalent Organic Framework

Symmetric covalent organic framework(COF)photocatalysts generally suffer from inefficient charge separation and short-lived photoexcited states.By performing density functional theory(DFT)and time-dependent density functional theory(TDDFT)calculations,we find that partial substitution with one or two substituents(N or NH_(2))in the linkage of the representative symmetric COF(N_(0)-COF)gives rise to the separation of charge carriers in the resulting COFs(i.e.,N_(1)-COF,N_(2)-COF,(NH_(2))1-N_(0)-COF,and(NH_(2))2-N_(0)-COF).Moreover,we also find that the energy levels of the highest occupied crystal orbital(HOCO)and the lowest unoccupied crystal orbital(LUCO)of the N_(0)-COF can shift away from or toward the vacuum level,depending on the electron-withdrawing or electron-donating characters of the substituent.Therefore,we propose that partial substitution with carefully chosen electron-withdrawing or electron-donating substituents in the linkages of symmetric COFs can lead to efficient charge separation as well as appropriate HOCO and LUCO positions of the generated COFs for specific photocatalytic reactions.The proposed rule can be utilized to further boost the photocatalytic performance of many symmetric COFs.

Flexible PDMS-based triboelectric nanogenerator for instantaneous force sensing and human joint movement monitoring

Flexible wearable sensors with excellent electric response and self-powered capability have become an appealing hotspot for personal healthcare and human-machine interfaces.Here,based on triboelectric nanogenerator(TENG),a flexible self-powered tactile sensor composed of micro-frustum-arrays-structured polydimethylsiloxane(PDMS)film/copper(Cu)electrodes,and poly(vinylidenefluoride-trifluoroethylene)(P(VDF-TrFE))nanofibers has been demonstrated.The TENG-based self-powered tactile sensor can generate electrical signals through the contact-separation process of two triboelectric layers under external mechanical stimuli.Due to the uniform and controllable micro-frustum-arrays structure fabricated by micro-electro-mechanical system(MEMS)process and the P(VDF-TrFE)nanofibers fabricated by electrostatic spinning,the flexible PDMS-based sensor presents high sensitivity of 2.97 V kPa^-1,stability of 40,000 cycles(no significant decay),response time of 60 ms at 1 Hz,low detection pressure of a water drop(~4 Pa,35 mg)and good linearity of 0.99231 in low pressure region.Since the PDMS film presents ultra-flexibility and excellent-biocompatibility,the sensor can be comfortably attached on human body.Furthermore,the tactile sensor can recognize various types of human body movements by the corresponding electrical signals.Therefore,the as-prepared TENGs are potential on the prospects of gesture detection,health assessment,human-machine interfaces and so on.

Investigation of micro vortex generators on controlling flow separation over SCCH high-lift configuration

For the problem that the flow separation on the flap lowers the aerodynamic performance of high lift system,an investigation was carried out on using micro vortex generators(VGs) to control the separation on flap of the swept constant chord half-model(SCCH) high-lift configuration,at a small to medium angle of attack,by experimental and numerical methods.The basic flow characteristics of SCCH landing configuration were analyzed by using numerical method to provide required information for the design of micro VGs.Then,by keeping the cruise configuration intact,the preliminary design procedure and design methods of micro VGs were established.In addition,the micro VGs were designed.The effects of VG's arrangement and geometric parameters,such as the arrangement mode,chordwise position,arrangement angle,height and spanwise distance,on controlling efficiency were investigated by using numerical method.Then the parameters of preliminary VGs were adjusted as the basis configuration for wind tunnel test.The experiments were accomplished in NH-2 wind tunnel for validating the numerical method,as well as obtaining the design principles and methods of micro VGs.The parameters of VGs were also optimized based on the experiments.The experimental results showed that the numerical design method can serve as an efficient and accurate design tool.The lift and drag were increased by 10% and 14%,respectively in landing state,which satisfied the requirements for landing.Finally,it was concluded that the established design principles and methods for micro VGs in this investigation can be used in engineering application.

Large enhancement of transient photovoltage induced by the absorption of the metal Al

The transient photovoltage of ITO/CuPc/AI is studied. The transient photovoltage under the Al side illumination is much greater than that under ITO side illumination. It is not negligible while light is almost completely absorbed by the Al layer. It seems that the light absorption of the Al layer could enhance the generation of the photoinduced carriers in the organic layer, which is further shown by the transient photovoltage study of ITO/Al/NPB/Au. A possible mechanism proposed is that the holes generated in the Al are because of light absorption that is injected from the AI to organic materials. This results in further charge separation by the internal built-in electric field.

Advanced 3D nanohybrid foam based on graphene oxide: Facile fabrication strategy, interfacial synergetic mechanism, and excellent photocatalytic performance

Herein,a unique nanohybrid foam was fabricated with titanium dioxide(TiO2)-carbon quantum dots(CQDs)nanoparticles intercalated between graphene oxide(GO)layers via a facile and low-cost solvothermal method.Compared with pure GO foam,the fabricated GO-TiO2-CQDs foam displayed high degradation rate towards methyl orange(MO),methylene blue(MB),and rhodamine B(Rh B),respectively,under the Xenon lamp irradiation.The composite foam can be used for several times and remain a high degradation rate without structural damage.The photochemical property was attributed to the 3D porous structure of GOTiO2-CQDs foam,in which ultrafine hydrogenated TiO2-CQDs nanoparticles were densely anchored on the GO sheets.This paper provides an efficient strategy to tune the charge transport and thus enhance the photocatalytic performance by combining the semi-conductive GO and quantum dots.

Unmanned air vehicle flow separation control using dielectric barrier discharge plasma at high wind speed

The present paper described an experimental investigation of separation control of an Unmanned Aerial Vehicle(UAV)at high wind speeds.The plasma actuator was based on Dielectric Barrier Discharge(DBD)and operated in a steady manner.The flow over a wing of UAV was performed with smoke flow visualization in theΦ0.75 m low speed wind tunnel to reveal the flow structure over the wing so that the locations of plasma actuators could be optimized.A full model of the UAV was experimentally investigated in theΦ3.2 m low speed wind tunnel using a six-component internal strain gauge balance.The effects of the key parameters,including the locations of the plasma actuators,the applied voltage amplitude and the operating frequency,were obtained.The whole test model was made of aluminium and acted as a cathode of the actuator.The results showed that the plasma acting on the surface of UAV could obviously suppress the boundary layer separation and reduce the model vibration at the high wind speeds.It was found that the maximum lift coefficient of the UAV was increased by 2.5%and the lift/drag ratio was increased by about 80%at the wind speed of 100 m/s.The control mechanism of the plasma actuator at the test configuration was also analyzed.