也谈《醉翁亭记》

《醉翁亭记》数百年来,脍炙人口。但“醉翁之意”究竟如何,似乎尚无真解。不少评论和赏析文章,抓住“醉翁之意不在酒,在乎山水之间也”一句,就断言此文“表现出当时士大夫娱情山水、悠闲自适的情调”(朱东润主编《中国历代文学作品选》中编第二册第246页)。有的则以肯定语调指出它“以细致的艺术笔触,生动地描写了醉翁亭四周的景色,抒写了他寄情山水的深厚而委婉的感情”(《阅读和欣赏》古典文学部分二第75页),仍然不过是说这篇文章没有多大思想价值。有的则说“虽然这篇散文的社会意义并不强烈。

Trapping Mechanism for Long Waves over Circular Islands with Power Function Profiles

Long waves such as tsunamis can be trapped by islands due to wave refraction,and these trapped waves will cause huge damage even in the sheltered shoreline of the island.That all waves propagating into the topography and finally reaching the coastline are called perfect trapped modes,while any waves escaping from the topography are called leaky modes.Whether these long waves can be trapped is dependent on the depth profile of the island.This paper presents analytic solutions of the ray path for waves propagating into the circular island with power function profiles.Wave height distributions over the island are further investigated based on the principia that crowded rays correspond to large wave height and sparse rays correspond to small wave height.The trapped mechanism for water waves over the island is revealed based on their ray paths.Furthermore,the perfectly trapped criterion is derived,that is,when the slope gradient at the topography toe is greater than twice the ratio of the water depth to the radial distances,all wave rays propagating on the island will finally reach the coastline,and the waves are perfectly trapped.

Energy transfer in organic multilayer quantum well structure and its application to OLEDs

We fabricate a series of samples and OLEDs with organic multilayer quantum well structure, which consist of alternate PBD and Alqy Both PBD and Alq3 are electron-transporting materials, and PBD is used as potential barrier layer, while Alq3 is used as potential well layer and emitting layer. Compared with double-layer structure, the luminescent characteristics of organic samples and diodes with quantum well structure are investigated and the quantum well structure helps the energy transfer between well layer and barrier layer. The quantum well structure makes carriers disperse in the different well layers and then increases the number of excitons to enhance the efficiency of the recombination.

Tris(8-Hydroxyquinoline) Aluminum/2-(4-Biphenylyl)-5-(4-Tertbutylphenyl)-1,3,3-Oxadiazole Organic Multiple Quantum Wells for Electroluminescent Devices

Organic multiple quantum wells(OMQWs) consisting of alternating layers of organic materials have been fabricated from tris(8-hydroxyquinoline) aluminum(Alq)and 2-(4-biphenylyl)-5-(4-tertbutylphenyl)-1,3,3-oxadiazole(PBD) by a multisource-type high-vacuum organic molecular deposition.From the small-angle X-ray diffraction patterns of Alq/PBD OMQWs,a periodically layered structure is confirmed through the entire stack.The Alq layer thickness in the OMQWs was varied from 1 nm to 4 nm.From the optical absorption,photoluminescence and electroluminescence measurements,it is found that the exciton energy shifts to higher energy with decreasing Alq layer thickness,The changes of the exciton energy could be interpreted as the confinement effects of exciton in the Alq thin layers.Narrowing of the emission spectrum has also been observed for the electroluminescent devices (ELDs) with the OMQWs structure at room temperature.

Investigation of spectrum blue shift in organic quantum well electroluminescent devices

In this paper, the organic quantum well devices,which are similar to the type-Ⅱ quantum well of inorganic semiconductor, have been fabricated, in which the NPB (N,N’-Di-[(1-naphthalenyl)-N,N’-diphenyl]-(1,1’-biphenyl)-4,4’-diamine) and Alq3 (Tris-(8-quinolinolato)aluminum) act as the potential barrier layer and the potential well layer, respectively. In the electroluminescence, the blue shift of spectrum with the decreasing of well width is observed for the device with different well width, and this is interpreted by combination of quantum size effect and exciton confinement effect. The blue shift of spectrum with increasing applied voltage is observed for the same device, and this is interpreted in terms of polarization effect and quantum size effect.

Efficient Organic Multi-quantum Well Electroluminescent Devices Using Aluminum as Cathodes

Organic green light emitting devices(LEDs) with multi-quantum well(MQW) structure were fabricated. Aromatic diamine(TPD) was used as hole-transporting layer and potential barrier layer; Tris(8-hydroxyquinoline) aluminum(Alq 3) was acted as electron-transporting emitter and MQW green emitter. Air-stable aluminum(Al) was used as electron-injection contact. The influence of the thickness of potential barrier layer and the number of quantum well on the electroluminescent(EL) efficiencies of the devices was investigated. The organic LEDs with two quantum wells showed enhanced EL efficiencies. Maximum external quantum efficiency and brightness were 1.04 % and 7 000 cd/m 2, respectively.

Fabrication of Alq_3/PBD OMQW Structures and Its Photoluminescence Characteristics

Abstract: Organic multiple quantum well(OMQ) structures consisting of alternating layers of tris(8 - quinolinolato)aluminum( ff) (Alq3) and 2 - (4 - biphenylyl) -5 - (4 - ter - butylphenyl) -(1,3,3- oxadiazole) (PBD) have been fabricated by organic molecular beam deposition (OMBD). The individual layer thickness in the multilayer samples was varied from 6 nm to 20 nm. The multiple quantum well structures were determined by low angle X - ray diffraction, optical absorption and photolumi-nescence(PL). The PL spectra narrow and the emission energy has been observed to shift to higher energy compared with that in the monolayer structure, suggesting a quantum size effect.

Effective Two-State Model and NOON States for Double-Well Bose-Einstein Condensates in Strong-Interaction Regime

The model of double-well Bose-Einstein condensates in the strong-interaction regime is shown to reduce adiabatically to an effective two-state model describing the Rabi oscillations between the two atomic Fock states ｜N, 0〉 and [0, N〉, and the NOON states of arbitrary ultracold atoms can therefore be generated periodically from the initial state of either one of the Foek states.

见义勇为与见义不为

关于见义勇为,《宋史·欧阳修传》中有一段评价,慷慨激昂,荡气回肠:"天资刚劲,见义勇为,虽机阱在前,触发之,不顾;放逐流离,至于再三,气自若也。"见义勇为的人天赋刚健勇猛,不管前方是地雷陷阱还是万丈深渊,都勇往直前、义无反顾。对于见义不为,《论语·为政》则评价:"见义不为,无勇也。"该出手时不出手,属于懦夫行为,可耻!那么,在古代,对见义勇为者有何奖励,法律上又是如何保护的?见义不为者,会不会受到惩罚?法律保障见义勇为者——从孙坚逐海盗说起东汉末年的孙坚,他的发迹就始于见义勇为的英雄事迹。他十七岁的时候,有一次跟父亲一起坐船到钱塘去,走到半路。

Alloy-like ternary polymer solar cells with over 17.2% efficiency

Ternary strategy has been considered as an efficient method to achieve high performance polymer solar cells(PSCs). A power conversion efficiency(PCE) of 17.22% is achieved in the optimized ternary PSCs with10 wt% MF1 in acceptors. The over 8% PCE improvement by employing ternary strategy is attributed to the simultaneously increased JSCof 25.68 mA cm^-2, VOCof 0.853 V and FF of 78.61% compared with Y6 based binary PSCs. The good compatibility of MF1 and Y6 can be confirmed from Raman mapping, contact angle,cyclic voltammetry and morphology, which is the prerequisite to form alloy-like state. Electron mobility in ternary active layers strongly depends on MF1 content in acceptors due to the different lowest unoccupied molecular orbital(LUMO) levels of Y6 and MF1, which can well explain the wave-like varied FF of ternary PSCs. The third-party certified PCE of 16.8% should be one of the highest values for single bulk heterojunction PSCs. This work provides sufficient references for selecting materials to achieve efficient ternary PSCs.

Forming electron traps deactivates self-assembled crystalline organic nanosheets toward photocatalytic overall water splitting

Most biological photoredox reactions occur in sophisticated molecular assemblies consisting of highly organized light-harvesting moieties and catalytic centers.Mimicking these prototypes by creating supramolecular assemblies could be a potentially viable approach toward artificial photosynthesis.Although self-assembled organic materials are known to carry out water splitting reactions,developing self-assembled organic materials for photocatalytic overall water splitting still remains a critical challenge.Herein,we first demonstrate that crystalline organic nanosheets assembled from linear oligo(phenylene butadiynylene)(OPB)are able to catalyze overall water splitting under visible light irradiation.Further investigations reveal that the photocatalytic activity of self-assembled organic structures is closely related to the crystalline structure along with the corresponding electronic structure.Structural disorders in OPB nanosheets and extrinsic factors such as adsorbed water molecules will induce the formation of electron traps which can make the OPB nanosheets thermodynamically unfavorable for photocatalytic overall water splitting.The deactivation mechanism unveiled in this study provides crucial insights into the assembling of artificial organic materials for future solar-to-chemical energy conversion.

Highly efficient organic solar cells enabled by a porous ZnO/PEIE electron transport layer with enhanced light trapping

In this study,a porous inorganic/organic(ZnO/PEIE,where PEIE is polyethylenimine ethoxylated)(P-ZnO)hybrid material has been developed and adopted in the inverted organic solar cells(OSCs).The P-ZnO serving as the electron transport layer(ETL)not only presents an ameliorative work function,but also forms the cratered surface with increased ohmic contact area,revealing suppressed charge recombination and enhanced charge extraction in devices.Particularly,P-ZnO-based OSCs show improved light trapping in the active layer compared with ZnO-based ones.The universality of P-ZnO serving as ETL for efficient OSCs is verified on three photovoltaic systems of PBDB-T/DTPPSe-2 F,PM6/Y6,and PTB7-Th/PC_(71)BM.The enhancements of 8%in power conversion efficiency(PCE)can be achieved in the state-of-the-art OSCs based on PBDB-T/DTPPSe-2F,PM6/Y6,and PTB7-Th/PC_(71)BM,delivering PCEs of 14.78%,16.57%,and 9.85%,respectively.Furthermore,a promising PCE of14.13%under air-processed condition can be achieved for PZnO/PBDB-T/DTPPSe-2F-based OSC,which is among the highest efficiencies reported for air-processed OSCs in the literature.And the P-ZnO/PBDB-T/DTPPSe-2F-based device also presents superior long-term storage stability whether in nitrogen or ambient air-condition without encapsulation,which can maintain over 85%of its initial efficiency.Our results demonstrate the great potential of the porous hybrid PZnO as ETL for constructing high-performance and air-stable OSCs.

A study of the operating parameters and barrier thickness of Al_(0.08)In_(0.08)Ga_(0.84)N/Al_xIn_yGa_(1-x-y)N double quantum well laser diodes

The operating parameters such as the internal quantum efficiency （η）, internal loss （α） and transparent threshold current density （J0） of double quantum well laser diodes were investigated and identified using the program, Integrated System Engineering-Technical Computer Aided Design （ISE-TCAD）. Various thicknesses （6, 7, 8, 10, 12 rim） of AlxInyGa1-x-yN barriers with （3 nm） Al0.08In0.08Ga0.84N wells as an active region were studied. The lowest threshold current （lth）, and the highest output power （Pop） were 116 mA and 196 mW respectively, at barriers thickness of 6 nm, Al mole fraction of 10% and In mole fraction of 1%, at an emission wavelength of 359.6 nm.