PVC树脂杂点产生的原因分析及预防

通过对PVC树脂生产过程中产生杂点的各种因素及生产环节分析,查找出不同工序产生杂点的原因,结合实际生产情况制定了相应的预防措施。

High sensitivity detection of baicalein by N,S co⁃doped carbon dots and their application in biofluids

In this work,p⁃phenylenediamine and L⁃cysteine were used as raw materials,and water⁃soluble N,S co⁃doped carbon dots(N,S⁃CDs)with excellent performance were prepared through a one⁃step solvothermal method.The morphology and structure of N,S⁃CDs were characterized by transmission electron microscope,X⁃ray diffrac⁃tion,Fourier transform infrared spectroscopy,and X⁃ray photoelectron spectroscopy,and the basic photophysical properties were investigated via UV⁃Vis absorption spectra and fluorescence spectra.Meanwhile,the N,S⁃CDs have excellent luminescence stability with pH,ionic strength,radiation time,and storage time.Experimental results illus⁃trated the present sensor platform exhibited high sensitivity and selectivity in response to baicalein with a detection limit of 85 nmol·L-1.The quenching mechanism is proved to be the inner filter effect.In addition,this sensor can also detect baicalein in biofluids(serum and urine)with good accuracy and reproducibility.

Charge-balanced codoping enables exceeding doping limit and ultralow thermal conductivity

Materials with low thermal conductivity are applied extensively in energy management,and breaking the amorphous limits of thermal conductivity to solids has attracted widespread attention from scientists.Doping is a common strategy for achieving low thermal conductivity that can offer abundant scattering centers in which heavier dopants always result in lower phonon group velocities and lower thermal conductivities.However,the amount of equivalent heavyatom single dopant available is limited.Unfortunately,nonequivalent heavy dopants have finite solubility because of charge imbalance.Here,we propose a charge balance strategy for SnS by substituting Sn2+with Ag^(+)and heavy Bi^(3+),improving the doping limit of Ag from 2%to 3%.Ag and Bi codoping increases the point defect concentration and introduces abundant boundaries simultaneously,scattering the phonons at both the atomic scale and nanoscale.The thermal conductivity of Ag0.03Bi0.03Sn0.94S decreased to 0.535 W·m^(−1)·K^(−1)at room temperature and 0.388 W·m^(−1)·K^(−1)at 275°C,which is below the amorphous limit of 0.450 W·m^(−1)·K^(−1)for SnS.This strategy offers a simple way to enhance the doping limit and achieve ultralow thermal conductivity in solids below the amorphous limit without precise structural modification.

基于B样条的弹性点配准方法

为了更好地进行图像弹性点的配准,提出了一种利用Hausdorff距离测度的弹性点配准方法。该方法以B样条为弹性形变模型,并具有较强的抵御杂点影响的能力。在此基础上又提出了序贯更新策略,即通过将源图像和控制点网格进行分块的方法来序贯更新弹性配准参数,从而进一步提高了算法的运算速度。为验证该方法的配准效果,采用该方法进行了合成图像、手写字体和脑部MRI图像的弹性配准实验。实验结果表明,该方法在基于特征的弹性配准应用中具有较好的使用效果。

浮雕灰度图生成精度建模仿真研究

在图像检测过程中,由于采集图像带有噪声,灰度图生成算法会产生许多无效的计算和像素值不准确的问题。为解决上述问题,首先定义了特征杂点,提出了删除特征杂点的算法。然后根据点云的稠密分布不均情况,分别提出了稠密型点云的灰度图生成算法和非稠密型点云的灰度图生成算法。实验证明提出的处理算法能有效地消除点云数据的噪声干扰和提出的灰度图生成算法避免了无效的计算和像素值不准确,提高了灰度图生成精度和效率。研究成果对提升浮雕生产质量具有重要的意义。

基于VRay的渲染画面杂斑处理技法探析

VRay作为3ds max优秀的渲染器插件能渲染出近似摄影场景的光影效果,但渲染的效果画面经常出现杂斑现象。在掌握VRay全局光照技术算法原理基础上,分析渲染图画面容易产生黑斑杂点原因,给出借助VRay渲染引擎的合理搭配取得控制时间与质量的最优平衡办法,进而合理设置面板参数解决画面不洁问题。

面向物联网应用的彩码识别技术研究

随着互联网的普及,二维码已经渗透到人们生活的方方面面。针对二维码识别性能和效率较低的问题,提出了一款基于彩色光学识别的高维标签结构——-彩码。彩码通过颜色和形状承载信息量,包含的信息量是二维码的几百倍,应用也比二维码更加广泛。共设计了两种方案来识别彩码:方案一通过采用轮廓提取与中心点排序算法,实现了彩码ID的输出;方案二则是在方案一的算法基础上进行优化和改进,增加聚类算法和抗干扰算法,解决了色块的偏移和彩码的杂点等问题。结果表明,提出的上述两种方案都顺利实现了对彩码信息的访问。

过程优化控制技术在SPVC干燥过程中的应用

阐述了采用"悬浮干燥过程优化控制技术"改造SPVC干燥装置的情况。运行数据表明,该技术提高了旋风干燥塔塔温控制精度、悬浮树脂成品的优级品率及挥发物指标。

ANALYSIS ON GRAY NODES AND GRAYNESS DEGREE IN COMPLEX NETWORK

Based on the theory of complex network and gray system, the sugesstion that there exist two types of gray nodes in complex networks, Gray Node I and Gray Node II, is concluded. The first one refers to the existent unknown gray nodes, and the second the evolution gray nodes. The relevant definitions are also given. Further- more, grayness degree in complex networks is described and divided into two forms--the relative grayness degree （RGD） and the absolute grayness degree （AGD）, which are proved respectively.

Accumulation of Mutant Genes and Its Pathway with Reproductive Isolation

According to the fitness of heterozygote was lower than homozygote among panmictic population,the process of generational accumulate of mutant gene r was considered.Branch point of r＇s frequency by generational evolution which revealed the hereditary incompatibility between R and r,was worked out,and it was found that genetic drift can make r have higher frequency to surpass the branch point to form reproductive isolation.It was not enough to have the three conditions of mutation,genetic drift and natural selection to be the drive of biological evolution;hybrid weakness,the repelling interaction between the genetic background of original population and the new mutation,were also needed.

不同厂家PVC树脂的性能对比

对比了国内外3种优等品SG5型PVC树脂的白度、诱导时间、静态热老化性能、初期着色性、晶杂点(包括“鱼眼”)等性能。结果表明:①各项性能均为进口树脂C>国产树脂A>国产树脂B;②采用刚果红法测定PVC树脂的热稳定时间时,建议先用有机溶剂洗涤;③PVC树脂企业应制定更为贴近下游应用的性能评价方法。

我们的青春纪念册——数码照片处理我最行

八月，炎热的夏季，悠闲的假期，走出校门的毕业生们一定开始怀念曾经的校园生活，还有同学们之间的深厚友谊。那么，就请你拿出珍藏着的往日照片，一起来做我们的青春纪念册……

夜的诱惑——DC数码相机拍摄夜景的技巧

夜是空灵而美丽的，在五颜六色的灯光映衬下的人、景、物都有着和白天迥然不同的色彩、一些白天让我们司空见惯的景物在夜里也都散发着让人惊动的异样美丽，心痒了吗？那就拿起我们手中的数码相机，用我们的镜头，用我们的心，去捕捉夜色下的美丽瞬间吧。

Bi quantum dots implanted 2D C-doped BiOCl nanosheets: Enhanced visible light photocatalysis efficiency and reaction pathway

The simultaneous integration of heteroatom doping and surface plasmon resonance(SPR) modulation on semiconductor photocatalysts could be capable of improving visible light utilization and charge separation, achieving better solar light conversion and photocatalysis efficiency. For this purpose, we have designed a novel Bi quantum dots(QDs) implanted C-doped BiOCl photocatalyst(C/BOC/B) for NOx removal. The feasibility was firstly evaluated through density functional theory(DFT) calculations methods, which indicates that the enhanced photocatalytic performance could be expected owing to the synergistic effects of doped C heteroatoms and loaded Bi QDs. Then, the C/BOC/B was synthesized via a facile hydrothermal method and exhibited efficient and stable visible light photocatalytic NO removal. The results found that the doped C atoms can serve as electron guides to induce oriented charge transfer from Bi QDs to BiOCl, while the Bi QDs can act as light-capture and electron-donating sites. The reaction pathway and mechanism for NO conversion was unveiled by in situ Fourier-transform infrared spectroscopy combined with DFT calculation. The enhanced adsorption of reactants and intermediates could promote the overall reaction efficiency and selectivity in photocatalytic NO conversion. This work could provide a new perspective on the mechanistic understanding of the synergistic effects toward non-metal doping and SPR effects in semiconductor photocatalysts, and this presented technique could be extended for other semiconductor materials.

Effects of Impurity on the Ground—State Transitions of a Quantum Dot in Strong Magnetic Field

The low-lying spectra of parabolic quantum dots with or without an impurity at the center are investigated.While it has been known that the electron-electron interaction leads to ground-state transitions on magic values of angular momentum in a magnetic field. We show, in this paper, that the implantation of an impurity ion at the center can either enhance or suppress such transitions, depending on whether it is an acceptor or a donor ion.

Boosting the photocatalytic performance of Ag_2CO_3 crystals in phenol degradation via coupling with trace N-CQDs

A series of N‐CQDs/Ag2CO3composite crystals(where N‐CQDs=Nitrogen doped carbon quantumdots)were prepared by adding different volumes of a solution of N‐CQDs during Ag2CO3crystalgrowth.Under irradiation from a350‐W Xe lamp light(with optical filter,λ≥420nm),the performanceof N‐CQDs/Ag2CO3in photocatalytic degradation of phenol was evaluated.The as‐preparedsamples were analyzed by XRD,SEM,TEM,BET,element mapping,UV‐vis DRS,FT‐IR,XPS,transientphotocurrent response and EIS testing.The results showed that after coupling with trace amountsof N‐CQDs,both the photocatalytic activity and stability of Ag2CO3were greatly boosted.The additionof N‐CQDs solution influenced the crystallization of Ag2CO3,resulting in a distinct decrease inAg2CO3crystal size and an obvious increase in surface area.Moreover,the charge transfer resistancewas greatly reduced,and the separation efficiency of photogenerated electrons and holes wasstrongly promoted.The presence of NCQDs on the surface of the catalysts facilitates the transfer ofphotogenerated electrons,slowing the photocorrosion rate of Ag2CO3,and then resulting in higherstability than bare Ag2CO3in degradation.The synergistic effect of the improvement of morphologyand charge transfer rate thus accounted for the superior photocatalytic performance ofN‐CQDs/Ag2CO3.

Cloning and Sequence Analysis of Genome from the Inner Mongolia Strain of the Endogenous Betaretroviruses (enJSRV)

In order to amplify the complete genome of enJSRV from the strain of Inner Mongolia (enJSRV-NM), we used enJSRV-specific and JSRV-specific DNA probes in dot blot hybridization. Seven pairs of primers were designed based on Genbank sequences. Seven fragments were obtained by PCR and were cloned into the PMD19-T vectors. The recombinant plasmids were sequenced and analyzed. The results showed that the genome was 7 942 bp in length and contained four overlapping open reading frames corresponding to the gag, pro, pol and env genes as well as an additional open reading frame (orf-x) that overlaps the 3' end of the pol gene. The nucleotide acid sequences of the enJSRV-NM loci were compared with the sequences of South Africa enJS56A1 strain (Accession No. AF153615) and USA JSRV21 strain (Accession No. AF105220). The nucleotide acid identities were 99.2% and 92.3% respectively. Two zinc fingers were found in the NC region in the predicted amino acid sequence. However, the YXXM motif, which is a reliable molecular marker for the infectious exogenous virus, was not found in the TM region. It was found that the enJSRV-NM region was 90%-98% identical at the amino acid level to its exogenous infectious counterparts in most of the retroviral genome. This is the first nucleotide sequence of enJSRV reported in P.R China. The resource work has provided a wide range of information useful not only for expression genomics and annotation of genomic DNA sequence, but also for further research on the clinical diagnosis of OPA.

Amorphous CoOx coupled carbon dots as a spongy porous bifunctional catalyst for efficient photocatalytic water oxidation and CO2 reduction

Cobalt-based oxides,with high abundance,good stability and excellent catalytic performance,are regarded as promising photocatalysts for artificial photosynthetic systems to alleviate foreseeable energy shortages and global warming.Herein,for the first time,a series of novel spongy porous CDs@CoOx materials were synthesized to act as an efficient and stable bifunctional photocatalyst for water oxidation and CO2 reduction.Notably,the preparation temperatures visibly influence the morphologies and photocatalytic performances of the CDs@CoOx.Under the optimal conditions,a maximum O2 yield of 40.4% and pretty apparent quantum efficiency(AQE)of 58.6% at 460 nm were obtained over CDs@CoOx-300 for water oxidation.Similarly,the optimized sample CDs@CoOx-300 manifests significant enhancement on the CO2-to-CO conversion with a high selectivity of 89.3% and CO generation rate of 8.1μmol/h,which is superior to most previous cobalt-based catalysts for CO2 reduction.The composite CDs@CoOx-300 not only exposes more active sites but also facilitates electron transport,which results in excellent photocatalytic activity.In addition,the boosted photocatalytic behavior is attributed to the synergistic effect between CoOx and CDs,which was verified by the photocatalytic activity control experiments and electrochemical characterization.The work offers a novel strategy to fabricate a high performance bifunctional photocatalyst for water oxidation and CO2 reduction.

Ionic polymer metal composites actuators with enhanced driving performance by incorporating graphene quantum dots

In order to further improve the driving performance of ionic polymer metal composites(IPMCs),Nafion/graphene quantum dots(GQDs)hybrid membranes incorporating GQDs with various contents of 0,0.1 wt.%,0.5 wt.%,1.0 wt.%,2.0 wt.%and 4.0 wt.%were fabricated by solution casting,and then IPMCs were manufactured by electroless plating.The water contents and elastic moduli of the hybrid membranes were tested.The morphology characteristics of the hybrid membranes and the IPMCs were observed,and the current,AC impedance,blocking force and displacement of the IPMCs were measured.The results show that the elastic modulus of the hybrid membranes decreases,the water content increases,and the actuation performance of the IPMCs improves significantly after the addition of GQDs.IPMC with 1.0 wt.%GQDs exhibits the best driving property.Compared with the IPMC without GQDs,the working current,ion conductivity,blocking force,and tip displacement increase by 94.67%,311.11%,53.66%,and 66.07%,respectively.These results lay a solid foundation for the preparation of IPMCs with high performance,and further broaden their applications in biomedical devices and bionic robots.