Similar material simulation test W9-15 101 fully mechanized caving face with was carried out in a geological model of large mining height in the Liuhuanggou Colliery, in Xinjiang Uigur Autonomous Region. The roof over...Similar material simulation test W9-15 101 fully mechanized caving face with was carried out in a geological model of large mining height in the Liuhuanggou Colliery, in Xinjiang Uigur Autonomous Region. The roof overlying strata movement law in the stope of a fully mechanized caving face with large mining height was studied and show that the roof overlying strata in the stope of a fully mechanized caving face with large mining height can be formed into a stable arch structure; the fracture rock beam is formed resembling a ＂bond beam＂, but it has essentially the structure of ＂multi-span beams＂ under the big structure of the stable arch. The roof overlying strata movement law in the stope of a fully mechanized caving face with large mining height is similar to that of the common, fully mechanized caving stope, which is determined by the deformation and instability of the structure of ＂multi-span beams＂. But because of the differences between the mining heights, the peak pressure in the stope of a fully mechanized caving face with large mining height is smaller while the affected area of abutment pressure is wider in the front of the working face; this is the obvious difference in abutment pressure between the stope of a fully mechanized caving face with large mining height and that of the common.展开更多
Hierarchical porous zeolitic imidazolate frameworks （ZIFs） have potential for adsorption, catalysis and chemical sensing applications. Ultrafast synthesis of ZIFs at room temperature and pressure is particularly des...Hierarchical porous zeolitic imidazolate frameworks （ZIFs） have potential for adsorption, catalysis and chemical sensing applications. Ultrafast synthesis of ZIFs at room temperature and pressure is particularly desirable for large-scale industrial production. Here, we developed a green and versatile method using organic amines as supramolecular templates （organic amine-template） to rapidly synthesize hierarchical porous ZIFs （ZIF-8, ZIF-61 and ZIF-90） at room temperature and pressure. The synthesis time was reduced dramatically to within 1 min, and the resulting ZIFs had multimodal hierarchical porous structures with mesopores/ macropores interconnected with micropores. Notably, the space-time yield （STY） of hierarchical porous ZIF-8 was up to 1.29×10^4 kg m^-3 d^-1, which is more than three times higher than that reported using other methods. Furthermore, the morphologies and porosities of the produced ZIFs could be readily tuned by controlling the synthesis time or type of organic amine. The organic amine played two roles in the synthesis： （1） a protonation agent to deprotonate organic ligands, facilitating the formation of ZIF crystals, and （2） an structure directing agent to direct mesopore/macropore formation. The resulting hierarchical porous ZIF-8 exhibited enhanced uptake capacities and diffusion rates for guest molecules relative to its microporous counterpart. This work provides a new direction for the green and efficient synthesis of various hierarchical porous ZIFs with high STYs for a wide range of applications.展开更多
基金Supported by National Natural Science Fundation of China(50674045)
文摘Similar material simulation test W9-15 101 fully mechanized caving face with was carried out in a geological model of large mining height in the Liuhuanggou Colliery, in Xinjiang Uigur Autonomous Region. The roof overlying strata movement law in the stope of a fully mechanized caving face with large mining height was studied and show that the roof overlying strata in the stope of a fully mechanized caving face with large mining height can be formed into a stable arch structure; the fracture rock beam is formed resembling a ＂bond beam＂, but it has essentially the structure of ＂multi-span beams＂ under the big structure of the stable arch. The roof overlying strata movement law in the stope of a fully mechanized caving face with large mining height is similar to that of the common, fully mechanized caving stope, which is determined by the deformation and instability of the structure of ＂multi-span beams＂. But because of the differences between the mining heights, the peak pressure in the stope of a fully mechanized caving face with large mining height is smaller while the affected area of abutment pressure is wider in the front of the working face; this is the obvious difference in abutment pressure between the stope of a fully mechanized caving face with large mining height and that of the common.
基金supported by the National Natural Science Foundation of China (21576094)SRFDP (20130172110012)the Fundamental Research Funds for the Central Universities (2015ZM046)
文摘Hierarchical porous zeolitic imidazolate frameworks （ZIFs） have potential for adsorption, catalysis and chemical sensing applications. Ultrafast synthesis of ZIFs at room temperature and pressure is particularly desirable for large-scale industrial production. Here, we developed a green and versatile method using organic amines as supramolecular templates （organic amine-template） to rapidly synthesize hierarchical porous ZIFs （ZIF-8, ZIF-61 and ZIF-90） at room temperature and pressure. The synthesis time was reduced dramatically to within 1 min, and the resulting ZIFs had multimodal hierarchical porous structures with mesopores/ macropores interconnected with micropores. Notably, the space-time yield （STY） of hierarchical porous ZIF-8 was up to 1.29×10^4 kg m^-3 d^-1, which is more than three times higher than that reported using other methods. Furthermore, the morphologies and porosities of the produced ZIFs could be readily tuned by controlling the synthesis time or type of organic amine. The organic amine played two roles in the synthesis： （1） a protonation agent to deprotonate organic ligands, facilitating the formation of ZIF crystals, and （2） an structure directing agent to direct mesopore/macropore formation. The resulting hierarchical porous ZIF-8 exhibited enhanced uptake capacities and diffusion rates for guest molecules relative to its microporous counterpart. This work provides a new direction for the green and efficient synthesis of various hierarchical porous ZIFs with high STYs for a wide range of applications.
