Effects of initial δ phase(Ni_3Nb) on the hot tensile deformation behaviors and material constants of a Ni-based superalloy were investigated over wide ranges of strain rate and deformation temperature. It is found...Effects of initial δ phase(Ni_3Nb) on the hot tensile deformation behaviors and material constants of a Ni-based superalloy were investigated over wide ranges of strain rate and deformation temperature. It is found that the true stress-true strain curves exhibit peak stress at a small strain, and the peak stress increases with the increase of initial δ phase. After the peak stress, initial δ phase promotes the dynamic softening behaviors, resulting in the decreased flow stress. An improved Arrhenius constitutive model is proposed to consider the synthetical effects of initial δ phase, deformation temperature, strain rate, and strain on hot deformation behaviors. In the improved model, material constants are expressed as the functions of the content of initial δ phase and strain. A good agreement between the predicted and measured results indicates that the improved Arrhenius constitutive model can well describe hot deformation behaviors of the studied Ni-based superalloy.展开更多
As a raw material,kaolin was modified to prepare a high-performance ammonium ion-exchange material.According to cation-exchange capacity (CEC) measurement,the prepared ammonium ion-exchange material has an ammonium io...As a raw material,kaolin was modified to prepare a high-performance ammonium ion-exchange material.According to cation-exchange capacity (CEC) measurement,the prepared ammonium ion-exchange material has an ammonium ion-exchange capacity greater than 75mg/g and can be used to remove ammonia nitrogen in water treatment.A pharmaceutical extruder-rounder was used to study the effects of granulation process.Polyethylene glycol6000 (PEG-6000) was used as the pore-forming agent and calcining temperature of 650℃ was used as the optimal condition.NMR data indicate that 27 Al is mainly converted from hexa-coordinated Al to tetra-coordinated Al during the modification.Compared with 29 Si in the original kaolin,29 Si in the modified kaolin does not have an obvious change.A comparison of the data with Langmuir and Freundlich isotherm models shows a good correlation.The Freundlich model describes the process more accurately,and the adsorption process of ammonia nitrogen in water with the ammonium ion-exchange material closely matches the pseudo-second-order reaction.展开更多
The present work is concerned with the characterization of hardening parameters for an elasto-plastic continuum model, taking into account the memory effect of plastic strain amplitude, in order to predict the hystere...The present work is concerned with the characterization of hardening parameters for an elasto-plastic continuum model, taking into account the memory effect of plastic strain amplitude, in order to predict the hysteretic responses of a ferritic steel. This elasto-plastic three-dimensional model is based on the internal thermodynamic variables which composed of the nonlinear kinematic hardening and isotropic hardening with the plastic strain memorization. The emphasis is put on the determination of strain memory parameters along with other material parameters of the proposed model in order to better simulate the behavior of the material at different strain range. The material parameters are calibrated with the experimental stabilized loops of stress-strain curves available in the literature. The predicted stabilized loops from the simulation with the determined parameters show good agreement with the experimental results signifying the validity of the considered model.展开更多
In this paper, a theory of landslide model testing and application in Three Gorges reservoir area were introduced.Based on geo-mechanical model tests, the similarity ratio of similar material parameters, component of ...In this paper, a theory of landslide model testing and application in Three Gorges reservoir area were introduced.Based on geo-mechanical model tests, the similarity ratio of similar material parameters, component of similar material and the boundary friction coefficient of the 2D earth landslide model test were derived and stated by theoretical and experimental methods.A model test of the Qianjiangping landslide in Three Gorges reservoir area reveal a two-step trigger mechanism of coexistence between retrogressive landslide and thrust load caused land-slide.展开更多
A review is given in the paper for solidification researches with transparent model materials. The effective experimental me- thod was first proposed by Jackson and Hunt in 1965. The transparent model materials for so...A review is given in the paper for solidification researches with transparent model materials. The effective experimental me- thod was first proposed by Jackson and Hunt in 1965. The transparent model materials for solidification researches are a kind of non-faceted crystals known as "plastic crystals" or "globular molecules", which have very low entropy of melting as that of metals. According to Jackson's theory proposed in 1958, entropy of phase transformation will determine whether the phase interface morphology is smooth or rough in atomic scale, which will lead to faceted or nonfacted phase interface in mi- croscopic and macroscopic scales. Succinonitrile (SCN) and its alloys with water, ethanol, acetone, and NH4C1-H:O solution are most commonly used as transparent model materials for solidification researches of dendritic growth, anisotropy of solid-liquid interfacial energy, crystal nucleation, crystal grain formation, directional solidification, eutectic and peritectic so- lidification, solidification defects formation such as bubble, hot tearing, etc. Among these researches, the most impressive work was the critical test of dendritic growth theories with high purity succinonitrile by Glicksman et al., which gave positive answer to the Ivantsov's analysis and negative answer to the ad hoc condition of the maximum velocity hypothesis. The future researches with transparent model materials could be suggested in three aspects: 1) accurate measurement of material proper- ties and alloy phase diagrams in more plastic crystals, especially to find more transparent eutectic and peritectic alloys; 2) accurate measurement of the grain boundary groove shape to obtain precise data of the anisotropy parameters of the interfacial free energy in transparent model materials; 3) to get clear pictures of solidification processes with morphology details in a rela- tively large area, with continuous movement of liquid and particles, in order to give experimental support to numerical simula- tions aimming at accurate description of microstructure formation during solidification of multicomponent alloys under complex conditions of real casting and welding processes.展开更多
基金Projects(5137550251305466) supported by the National Natural Science Foundation of China+2 种基金Project(2015CX002) supported by the Innovation-driven Plan in Central South University,ChinaProject(2013CB035801) supported by the National Basic Research Program of ChinaProject(2015NGQ001) supported by Key Laboratory of Efficient&Clean Energy Utilization,College of Hunan Province,China
文摘Effects of initial δ phase(Ni_3Nb) on the hot tensile deformation behaviors and material constants of a Ni-based superalloy were investigated over wide ranges of strain rate and deformation temperature. It is found that the true stress-true strain curves exhibit peak stress at a small strain, and the peak stress increases with the increase of initial δ phase. After the peak stress, initial δ phase promotes the dynamic softening behaviors, resulting in the decreased flow stress. An improved Arrhenius constitutive model is proposed to consider the synthetical effects of initial δ phase, deformation temperature, strain rate, and strain on hot deformation behaviors. In the improved model, material constants are expressed as the functions of the content of initial δ phase and strain. A good agreement between the predicted and measured results indicates that the improved Arrhenius constitutive model can well describe hot deformation behaviors of the studied Ni-based superalloy.
基金Supported by Natural Science Foundation of Tianjin(No.06YFGPSH04300)
文摘As a raw material,kaolin was modified to prepare a high-performance ammonium ion-exchange material.According to cation-exchange capacity (CEC) measurement,the prepared ammonium ion-exchange material has an ammonium ion-exchange capacity greater than 75mg/g and can be used to remove ammonia nitrogen in water treatment.A pharmaceutical extruder-rounder was used to study the effects of granulation process.Polyethylene glycol6000 (PEG-6000) was used as the pore-forming agent and calcining temperature of 650℃ was used as the optimal condition.NMR data indicate that 27 Al is mainly converted from hexa-coordinated Al to tetra-coordinated Al during the modification.Compared with 29 Si in the original kaolin,29 Si in the modified kaolin does not have an obvious change.A comparison of the data with Langmuir and Freundlich isotherm models shows a good correlation.The Freundlich model describes the process more accurately,and the adsorption process of ammonia nitrogen in water with the ammonium ion-exchange material closely matches the pseudo-second-order reaction.
文摘The present work is concerned with the characterization of hardening parameters for an elasto-plastic continuum model, taking into account the memory effect of plastic strain amplitude, in order to predict the hysteretic responses of a ferritic steel. This elasto-plastic three-dimensional model is based on the internal thermodynamic variables which composed of the nonlinear kinematic hardening and isotropic hardening with the plastic strain memorization. The emphasis is put on the determination of strain memory parameters along with other material parameters of the proposed model in order to better simulate the behavior of the material at different strain range. The material parameters are calibrated with the experimental stabilized loops of stress-strain curves available in the literature. The predicted stabilized loops from the simulation with the determined parameters show good agreement with the experimental results signifying the validity of the considered model.
基金Supported by the National Natural Science Foundation of China(50839004)Key Projects of the National Science & Technology Pillar Program in the 11th Five-year Plan(2008BAC47B03)Scientific Fund of Hubei Provincial Education Department(Q20081305)
文摘In this paper, a theory of landslide model testing and application in Three Gorges reservoir area were introduced.Based on geo-mechanical model tests, the similarity ratio of similar material parameters, component of similar material and the boundary friction coefficient of the 2D earth landslide model test were derived and stated by theoretical and experimental methods.A model test of the Qianjiangping landslide in Three Gorges reservoir area reveal a two-step trigger mechanism of coexistence between retrogressive landslide and thrust load caused land-slide.
基金supported by the National Basic Research Program of China (Grant No. 2011CB610402)the Fund of the State Key Laboratory of Solidification Processing in NWPU (Grant No. 02-TZ-2008)
文摘A review is given in the paper for solidification researches with transparent model materials. The effective experimental me- thod was first proposed by Jackson and Hunt in 1965. The transparent model materials for solidification researches are a kind of non-faceted crystals known as "plastic crystals" or "globular molecules", which have very low entropy of melting as that of metals. According to Jackson's theory proposed in 1958, entropy of phase transformation will determine whether the phase interface morphology is smooth or rough in atomic scale, which will lead to faceted or nonfacted phase interface in mi- croscopic and macroscopic scales. Succinonitrile (SCN) and its alloys with water, ethanol, acetone, and NH4C1-H:O solution are most commonly used as transparent model materials for solidification researches of dendritic growth, anisotropy of solid-liquid interfacial energy, crystal nucleation, crystal grain formation, directional solidification, eutectic and peritectic so- lidification, solidification defects formation such as bubble, hot tearing, etc. Among these researches, the most impressive work was the critical test of dendritic growth theories with high purity succinonitrile by Glicksman et al., which gave positive answer to the Ivantsov's analysis and negative answer to the ad hoc condition of the maximum velocity hypothesis. The future researches with transparent model materials could be suggested in three aspects: 1) accurate measurement of material proper- ties and alloy phase diagrams in more plastic crystals, especially to find more transparent eutectic and peritectic alloys; 2) accurate measurement of the grain boundary groove shape to obtain precise data of the anisotropy parameters of the interfacial free energy in transparent model materials; 3) to get clear pictures of solidification processes with morphology details in a rela- tively large area, with continuous movement of liquid and particles, in order to give experimental support to numerical simula- tions aimming at accurate description of microstructure formation during solidification of multicomponent alloys under complex conditions of real casting and welding processes.