In this study,the microstructure and mechanical properties of a multi-layered 316L-TiC composite material produced by selective laser melting(SLM)additive manufacturing process are investigated.Three different layers,...In this study,the microstructure and mechanical properties of a multi-layered 316L-TiC composite material produced by selective laser melting(SLM)additive manufacturing process are investigated.Three different layers,consisting of 316L stainless steel,316L-5 wt%TiC and 316L-10 wt%TiC,were additively manufactured.The microstructure of these layers was characterized by optical microscopy(OM)and scanning electron microscopy(SEM).X-ray diffraction(XRD)was used for phase analysis,and the mechanical properties were evaluated by tensile and nanoindentation tests.The microstructural observations show epitaxial grain growth within the composite layers,with the elongated grains growing predominantly in the build direction.XRD analysis confirms the successful incorporation of the TiC particles into the 316L matrix,with no unwanted phases present.Nanoindentation results indicate a significant increase in the hardness and modulus of elasticity of the composite layers compared to pure 316L stainless steel,suggesting improved mechanical properties.Tensile tests show remarkable strength values for the 316L-TiC composite samples,which can be attributed to the embedded TiC particles.These results highlight the potential of SLM in the production of multi-layer metal-ceramic composites for applications that require high strength and ductility of metallic components in addition to the exceptional hardness of the ceramic particles.展开更多
Electron beam selective melting (EBSM) is an additive manufacturing technique that directly fabricates three-dimensional parts in a layerwise fashion by using an electron beam to scan and melt metal powder. In recen...Electron beam selective melting (EBSM) is an additive manufacturing technique that directly fabricates three-dimensional parts in a layerwise fashion by using an electron beam to scan and melt metal powder. In recent years, EBSM has been successfully used in the additive manufacturing of a variety of materials. Previous research focused on the EBSM process of a single material. In this study, a novel EBSM process capable of building a gradient structure with dual metal materials was developed, and a powder-supplying method based on vibration was put forward. Two different powders can be supplied individually and then mixed. Two materials were used in this study: Ti6AI4V powder and Ti47AI2Cr2Nb powder. Ti6AI4V has excellent strength and plasticity at room temperature, while Ti47AI2Cr2Nb has excellent performance at high temperature, but is very brittle. A Ti6AI4V/Ti47AI2Cr2Nb gradient material was successfully fabricated by the developed system. The microstructures and chemical compositions were characterized by optical microscopy, scanning microscopy, and electron microprobe analysis. Results showed that the interface thickness was about 300 μm. The interface was free of cracks, and the chemical compositions exhibited a staircase-like change within the interface.展开更多
In this study,nano-graphene reinforced titanium matrix composites(GNPs/Ti)with a honeycomb porous structure were fabricated by selective laser melting(SLM).The effects of graphene on the microstructure,mechanical prop...In this study,nano-graphene reinforced titanium matrix composites(GNPs/Ti)with a honeycomb porous structure were fabricated by selective laser melting(SLM).The effects of graphene on the microstructure,mechanical properties and corrosion performance of the SLM GNPs/Ti were systematically investigated.Results of microstructure characterization show that:1)the density of the SLM GNPs/Ti was improved as compared to that of the SLM Ti;2)abundant TiC particles were formed in the SLM GNPs/Ti.The hardness and compressive strength of the composite increased by 90%(from HV 236 to HV 503)and 14%(from 277 MPa to 316 MPa),respectively,attributed to the uniformly distributed TiC and fine GNPs in the Ti matrix.Electrochemical tests reveal that the corrosion current density of the SLM GNPs/Ti is only 0.328μA/cm^(2),that is about 25%less than that of the SLM Ti.The results indicate that the incorporation of nano-graphene is a potential method to strengthen the Ti by SLM.展开更多
Selective laser melting(SLM)is an emerging layer-wise additive manufacturing technique that can generate complex components with high performance.Particulate-reinforced aluminum matrix composites(PAMCs)are important m...Selective laser melting(SLM)is an emerging layer-wise additive manufacturing technique that can generate complex components with high performance.Particulate-reinforced aluminum matrix composites(PAMCs)are important materials for various applications due to the combined properties of Al matrix and reinforcements.Considering the advantages of SLM technology and PAMCs,the novel SLM PAMCs have been developed and researched in recent years.Therefore,the current research progress about the SLM PAMCs is reviewed.Firstly,special attention is paid to the solidification behavior of SLM PAMCs.Secondly,the important issues about the design and fabrication of high-performance SLM PAMCs,including the selection of reinforcement,the influence of parameters on the processing and microstructure,the defect evolution and phase control,are highlighted and discussed comprehensively.Thirdly,the performance and strengthening mechanism of SLM PAMCs are systematically figured out.Finally,future directions are pointed out on the advancement of high-performance SLM PAMCs.展开更多
In this study, we established a rapid acid digestion for determining Hf-Sr-Nd isotopic ratios of geological samples by using MC-ICP-MS. Conditions of 1600 ℃ for 1 min and 1400 ℃ for 1 min were adopted for fusing int...In this study, we established a rapid acid digestion for determining Hf-Sr-Nd isotopic ratios of geological samples by using MC-ICP-MS. Conditions of 1600 ℃ for 1 min and 1400 ℃ for 1 min were adopted for fusing intrusive rocks and extrusive rocks, respectively. The rapid acid digestion technique is superior in digestion time compared with high-pressure PTFE bomb method. The procedural blanks of the method were also lower than that flux fusion. Replicate analyses of international certified reference materials (CRMs) indicate that isotopic ratios of ^176Hf/^177Hf, ^87Sr/^86Sr and 143Nd/144Nd agree well with previously published data. The external reproducibility (2SD, n = 5) of ten CRMs are ±0.000030 for ^87Sr/^86Sr, ± 0.000030 for ^143Nd/^144Nd, and ±0.000018 for ^176Hf/^177Hf.展开更多
Different organo-montmorillonites (OMMTs) are prepared by modifying montmorillonites (MMTs) with CTAB, PA 1010 salts/CTAB, PEG/CTAB, PVA/CTAB, PVP, PVP/ CTAB and PA 6/CTAB, respectively. These OMMTs were studied b...Different organo-montmorillonites (OMMTs) are prepared by modifying montmorillonites (MMTs) with CTAB, PA 1010 salts/CTAB, PEG/CTAB, PVA/CTAB, PVP, PVP/ CTAB and PA 6/CTAB, respectively. These OMMTs were studied by X-ray diffraction and TG. The gallery sizes of them are all larger than that of sodium MMTs. And the decomposition temperatures of them are all much higher than that of MMT and the processing temperature of PA 66, especially OM - 6 and OM - 7, the decomposition temperatures of which are 451.6℃ and 439.1℃, almost the collapse temperature of the native MMT crystal lattice which is more than 5080C. Then PA 66/Clay nanocomposites were synthesized by mixing these OMMTs with PA 66 matrix via melt intercalation. Experimental results indicate that the tensile and flexural properties increase significantly, especially those of PCN - 08. The combination property of PCN- 08 is the best. TEaM photos show that some clay platelets are present in the matrix as exfollated layers, while most of the clay platelets are present as intercalated layers.展开更多
The microstructure formation and strengthening of an Al-5 wt.%TiO2 composites with additions of 5 wt.%Cu and 2 wt.% stearic acid(as a process control agent, PCA) during mechanical alloying and subsequent thermal expos...The microstructure formation and strengthening of an Al-5 wt.%TiO2 composites with additions of 5 wt.%Cu and 2 wt.% stearic acid(as a process control agent, PCA) during mechanical alloying and subsequent thermal exposure were studied. The powder composites were prepared by high-energy ball milling for up to 10 h. Single line tracks of the powders were laser melted. Optical and scanning electron microscopy, XRD analysis and differential scanning calorimetry were used to study microstructural evolution. The results showed that the Cu addition promotes an effective mechanical alloying of aluminum with Ti O2 from the start of milling, resulting in higher microhardness(up to HV 290), while the PCA, on the contrary, postpones this process. In both cases, the composite granules with uniform distribution of Ti O2 particles were formed. Subsequent heating of mechanically alloyed materials causes the activation of an exothermic reaction of Ti O2 reduction with aluminum, the start temperature of which, in the case of Cu addition,shifts to lower values, that is, the transformation begins in the solid state. Besides, the Cu-added material after laser melting demonstrates a more dispersed and uniform structure which positively affects its microhardness.展开更多
A one-step molten salt electrochemical strategy was proposed to synthesize SiC nanoparticles from ultra-fine silicon dioxide/carbon(SiO_(2)/C)mixtures.The electrosynthesis process and physicochemical properties of the...A one-step molten salt electrochemical strategy was proposed to synthesize SiC nanoparticles from ultra-fine silicon dioxide/carbon(SiO_(2)/C)mixtures.The electrosynthesis process and physicochemical properties of the synthesized products were systematically analyzed via X-ray diffraction,electron microscopy,Raman spectroscopy and photoluminescence spectroscopy,etc.A combined chemical/electrochemical reaction,electrochemical deoxidation,and in-situ carbonization reaction mechanism was proposed to reveal the electrochemical synthesis process of SiC nanoparticles from SiO_(2)/C in molten CaCl_(2).The as-prepared SiC with particle size ranging from 8 to 14 nm possesses a polycrystalline structure.In addition,the SiC nanoparticles demonstrate obvious photoluminescence property due to the synergetic size effect and microstructural characteristics.展开更多
Most of traditional linear poly(ethylene terephthalate)(PET)resins of relatively low molecular mass and narrow molecular mass distribution have low melt strength at foaming temperatures,which are not enough to support...Most of traditional linear poly(ethylene terephthalate)(PET)resins of relatively low molecular mass and narrow molecular mass distribution have low melt strength at foaming temperatures,which are not enough to support and keep cells.An in-situ polymerization-modification process with esterification and polycondensation stages was performed in a 2 L batch stirred reactor using pyromellitic dianhydride(PMDA)or pentaerythritol(PENTA)as modifying monomers to obtain PETs with high melt strength.The influence of amounts of modifying monomers on the properties of modified PET was investigated.It was found that the selected modifying monomers could effectively introduce branched structures into the modified PETs and improve their melt strength.With increasing the amount of the modifying monomer,the melt strength of the modified PET increased.But when the amount of PENTA reached 0.35%or PMDA reached 0.9%,crosslinking phenomenon was observed in the modified PET.Supercritical carbon dioxide(ScCO2)was employed as physical foaming agent to evaluate the foaming ability of modified PETs.The modified PETs had good foaming properties at 14 MPa of CO2pressure with foaming temperature ranging from 265°C to 280°C.SEM micrographs demonstrated that both modified PET foams had homogeneous cellular structures,with cell diameter ranging from 35μm to 49μm for PENTA modified PETs and38μm to 57μm for PMDA modified ones.Correspondingly,the cell density had a range of 3.5×107cells·cm 3to 7×106cells·cm 3for the former and 2.8×107cells·cm 3to 5.8×106cells·cm 3for the latter.展开更多
This work aims to numerically study the melting natural convection in a rectangular enclosure heated by three discreet protruding electronic chips. The beat sources generate heat at a constant and uniform volumetric r...This work aims to numerically study the melting natural convection in a rectangular enclosure heated by three discreet protruding electronic chips. The beat sources generate heat at a constant and uniform volumetric rate. A part of the power generated in the heat sources is dissipated to a phase change material (PCM, n-eicosane with melting temperature, Tm = 36℃). Numerical investigations were carded out in order to examine the effects of the plate thickness on the maximum temperature of electronic components, the percentage contribution of plate heat conduction on the total removed heat and temperature profiles in the plate. Con'elations for the dimensionless secured working time (time to reach the threshold temperature, Tcr = 75℃) and the corresponding liquid fraction were derived.展开更多
文摘In this study,the microstructure and mechanical properties of a multi-layered 316L-TiC composite material produced by selective laser melting(SLM)additive manufacturing process are investigated.Three different layers,consisting of 316L stainless steel,316L-5 wt%TiC and 316L-10 wt%TiC,were additively manufactured.The microstructure of these layers was characterized by optical microscopy(OM)and scanning electron microscopy(SEM).X-ray diffraction(XRD)was used for phase analysis,and the mechanical properties were evaluated by tensile and nanoindentation tests.The microstructural observations show epitaxial grain growth within the composite layers,with the elongated grains growing predominantly in the build direction.XRD analysis confirms the successful incorporation of the TiC particles into the 316L matrix,with no unwanted phases present.Nanoindentation results indicate a significant increase in the hardness and modulus of elasticity of the composite layers compared to pure 316L stainless steel,suggesting improved mechanical properties.Tensile tests show remarkable strength values for the 316L-TiC composite samples,which can be attributed to the embedded TiC particles.These results highlight the potential of SLM in the production of multi-layer metal-ceramic composites for applications that require high strength and ductility of metallic components in addition to the exceptional hardness of the ceramic particles.
基金funding of 2013 Beijing Science and Technology Development Project (D13110400300000 and D131100003013002)
文摘Electron beam selective melting (EBSM) is an additive manufacturing technique that directly fabricates three-dimensional parts in a layerwise fashion by using an electron beam to scan and melt metal powder. In recent years, EBSM has been successfully used in the additive manufacturing of a variety of materials. Previous research focused on the EBSM process of a single material. In this study, a novel EBSM process capable of building a gradient structure with dual metal materials was developed, and a powder-supplying method based on vibration was put forward. Two different powders can be supplied individually and then mixed. Two materials were used in this study: Ti6AI4V powder and Ti47AI2Cr2Nb powder. Ti6AI4V has excellent strength and plasticity at room temperature, while Ti47AI2Cr2Nb has excellent performance at high temperature, but is very brittle. A Ti6AI4V/Ti47AI2Cr2Nb gradient material was successfully fabricated by the developed system. The microstructures and chemical compositions were characterized by optical microscopy, scanning microscopy, and electron microprobe analysis. Results showed that the interface thickness was about 300 μm. The interface was free of cracks, and the chemical compositions exhibited a staircase-like change within the interface.
基金Projects(51504191,51671152,51874225)supported by the National Natural Science Foundation of ChinaProject(2019GY-188)supported by the Key R&D Projects of Shaanxi,China+2 种基金Project(18JC019)supported by the Industrialization Project of Shaanxi Education Department,ChinaProject(PMMSLKL-901)supported by the State Key Laboratory of Metal Porous Materials,ChinaProject(2020ZDLGY13-10)supported by the Science&Technology Project of Shaanxi,China。
文摘In this study,nano-graphene reinforced titanium matrix composites(GNPs/Ti)with a honeycomb porous structure were fabricated by selective laser melting(SLM).The effects of graphene on the microstructure,mechanical properties and corrosion performance of the SLM GNPs/Ti were systematically investigated.Results of microstructure characterization show that:1)the density of the SLM GNPs/Ti was improved as compared to that of the SLM Ti;2)abundant TiC particles were formed in the SLM GNPs/Ti.The hardness and compressive strength of the composite increased by 90%(from HV 236 to HV 503)and 14%(from 277 MPa to 316 MPa),respectively,attributed to the uniformly distributed TiC and fine GNPs in the Ti matrix.Electrochemical tests reveal that the corrosion current density of the SLM GNPs/Ti is only 0.328μA/cm^(2),that is about 25%less than that of the SLM Ti.The results indicate that the incorporation of nano-graphene is a potential method to strengthen the Ti by SLM.
基金Project(GJHZ20190822095418365)supported by Shenzhen International Cooperation Research,ChinaProject(2019011)supported by NTUT-SZU Joint Research Program,China+2 种基金Project(2019040)supported by Natural Science Foundation of Shenzhen University,ChinaProject(JCYJ20190808144009478)supported by Shenzhen Fundamental Research Fund,ChinaProject(ZDYBH201900000008)supported by Shenzhen Bureau of Industry and Information Technology,China。
文摘Selective laser melting(SLM)is an emerging layer-wise additive manufacturing technique that can generate complex components with high performance.Particulate-reinforced aluminum matrix composites(PAMCs)are important materials for various applications due to the combined properties of Al matrix and reinforcements.Considering the advantages of SLM technology and PAMCs,the novel SLM PAMCs have been developed and researched in recent years.Therefore,the current research progress about the SLM PAMCs is reviewed.Firstly,special attention is paid to the solidification behavior of SLM PAMCs.Secondly,the important issues about the design and fabrication of high-performance SLM PAMCs,including the selection of reinforcement,the influence of parameters on the processing and microstructure,the defect evolution and phase control,are highlighted and discussed comprehensively.Thirdly,the performance and strengthening mechanism of SLM PAMCs are systematically figured out.Finally,future directions are pointed out on the advancement of high-performance SLM PAMCs.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41421002, 41427804, and 41373004)the MOST Research Foundation from the State Key Laboratory of Continental Dynamics (Grant Nos. BJ08132-1, 207010021, and 201210004)
文摘In this study, we established a rapid acid digestion for determining Hf-Sr-Nd isotopic ratios of geological samples by using MC-ICP-MS. Conditions of 1600 ℃ for 1 min and 1400 ℃ for 1 min were adopted for fusing intrusive rocks and extrusive rocks, respectively. The rapid acid digestion technique is superior in digestion time compared with high-pressure PTFE bomb method. The procedural blanks of the method were also lower than that flux fusion. Replicate analyses of international certified reference materials (CRMs) indicate that isotopic ratios of ^176Hf/^177Hf, ^87Sr/^86Sr and 143Nd/144Nd agree well with previously published data. The external reproducibility (2SD, n = 5) of ten CRMs are ±0.000030 for ^87Sr/^86Sr, ± 0.000030 for ^143Nd/^144Nd, and ±0.000018 for ^176Hf/^177Hf.
基金Supported by Training Project For Innovitive Talents of Universities of Henan Province and Scientific Starting Funds For Returned Personnel From Abroad of Ministry of Education of China P. R.
文摘Different organo-montmorillonites (OMMTs) are prepared by modifying montmorillonites (MMTs) with CTAB, PA 1010 salts/CTAB, PEG/CTAB, PVA/CTAB, PVP, PVP/ CTAB and PA 6/CTAB, respectively. These OMMTs were studied by X-ray diffraction and TG. The gallery sizes of them are all larger than that of sodium MMTs. And the decomposition temperatures of them are all much higher than that of MMT and the processing temperature of PA 66, especially OM - 6 and OM - 7, the decomposition temperatures of which are 451.6℃ and 439.1℃, almost the collapse temperature of the native MMT crystal lattice which is more than 5080C. Then PA 66/Clay nanocomposites were synthesized by mixing these OMMTs with PA 66 matrix via melt intercalation. Experimental results indicate that the tensile and flexural properties increase significantly, especially those of PCN - 08. The combination property of PCN- 08 is the best. TEaM photos show that some clay platelets are present in the matrix as exfollated layers, while most of the clay platelets are present as intercalated layers.
基金the Ministry of Education and Science of the Russian Federation in the framework of the State Assignment to the Universities(Project No.11.7172.2017/8.9).
文摘The microstructure formation and strengthening of an Al-5 wt.%TiO2 composites with additions of 5 wt.%Cu and 2 wt.% stearic acid(as a process control agent, PCA) during mechanical alloying and subsequent thermal exposure were studied. The powder composites were prepared by high-energy ball milling for up to 10 h. Single line tracks of the powders were laser melted. Optical and scanning electron microscopy, XRD analysis and differential scanning calorimetry were used to study microstructural evolution. The results showed that the Cu addition promotes an effective mechanical alloying of aluminum with Ti O2 from the start of milling, resulting in higher microhardness(up to HV 290), while the PCA, on the contrary, postpones this process. In both cases, the composite granules with uniform distribution of Ti O2 particles were formed. Subsequent heating of mechanically alloyed materials causes the activation of an exothermic reaction of Ti O2 reduction with aluminum, the start temperature of which, in the case of Cu addition,shifts to lower values, that is, the transformation begins in the solid state. Besides, the Cu-added material after laser melting demonstrates a more dispersed and uniform structure which positively affects its microhardness.
基金the National Natural Science Foundation of China(Nos.52022054,51974181,52004157)the Shanghai Rising-Star Program,China(No.19QA1403600)+4 种基金the Shanghai Sailing Program,China(No.21YF1412900)and the Iron and Steel Joint Research Fund of National Natural Science Foundation of China and China Baowu Steel Group Corporation Limited(No.U1860203)the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,China(No.TP2019041)the Shanghai Postdoctoral Excellence Program,China(No.2021160)the“Shuguang Program”supported by the Shanghai Education Development Foundation and the Shanghai Municipal Education Commission,China(No.21SG42).
文摘A one-step molten salt electrochemical strategy was proposed to synthesize SiC nanoparticles from ultra-fine silicon dioxide/carbon(SiO_(2)/C)mixtures.The electrosynthesis process and physicochemical properties of the synthesized products were systematically analyzed via X-ray diffraction,electron microscopy,Raman spectroscopy and photoluminescence spectroscopy,etc.A combined chemical/electrochemical reaction,electrochemical deoxidation,and in-situ carbonization reaction mechanism was proposed to reveal the electrochemical synthesis process of SiC nanoparticles from SiO_(2)/C in molten CaCl_(2).The as-prepared SiC with particle size ranging from 8 to 14 nm possesses a polycrystalline structure.In addition,the SiC nanoparticles demonstrate obvious photoluminescence property due to the synergetic size effect and microstructural characteristics.
基金Supported by the National Natural Science Foundation of China(21176070) the National High Technology Research and Development Program of China(2012AA040211)+2 种基金 the Joint Research Project of Yangtze River Delta(12195810900) the Specialized Research Fund for the Doctoral Program of Higher Education(20120074120019) the Fundamental Research Funds for the Central Universities
文摘Most of traditional linear poly(ethylene terephthalate)(PET)resins of relatively low molecular mass and narrow molecular mass distribution have low melt strength at foaming temperatures,which are not enough to support and keep cells.An in-situ polymerization-modification process with esterification and polycondensation stages was performed in a 2 L batch stirred reactor using pyromellitic dianhydride(PMDA)or pentaerythritol(PENTA)as modifying monomers to obtain PETs with high melt strength.The influence of amounts of modifying monomers on the properties of modified PET was investigated.It was found that the selected modifying monomers could effectively introduce branched structures into the modified PETs and improve their melt strength.With increasing the amount of the modifying monomer,the melt strength of the modified PET increased.But when the amount of PENTA reached 0.35%or PMDA reached 0.9%,crosslinking phenomenon was observed in the modified PET.Supercritical carbon dioxide(ScCO2)was employed as physical foaming agent to evaluate the foaming ability of modified PETs.The modified PETs had good foaming properties at 14 MPa of CO2pressure with foaming temperature ranging from 265°C to 280°C.SEM micrographs demonstrated that both modified PET foams had homogeneous cellular structures,with cell diameter ranging from 35μm to 49μm for PENTA modified PETs and38μm to 57μm for PMDA modified ones.Correspondingly,the cell density had a range of 3.5×107cells·cm 3to 7×106cells·cm 3for the former and 2.8×107cells·cm 3to 5.8×106cells·cm 3for the latter.
文摘This work aims to numerically study the melting natural convection in a rectangular enclosure heated by three discreet protruding electronic chips. The beat sources generate heat at a constant and uniform volumetric rate. A part of the power generated in the heat sources is dissipated to a phase change material (PCM, n-eicosane with melting temperature, Tm = 36℃). Numerical investigations were carded out in order to examine the effects of the plate thickness on the maximum temperature of electronic components, the percentage contribution of plate heat conduction on the total removed heat and temperature profiles in the plate. Con'elations for the dimensionless secured working time (time to reach the threshold temperature, Tcr = 75℃) and the corresponding liquid fraction were derived.