考虑主应力方向影响的正交各向异性土体强度

利用材料组构与应力主轴的方向关系,对椭圆型角隅函数进行修正并引入到Mohr-Coulomb准则,建立了一个适用于正交各向异性土体的三维强度准则.通过所建立的准则,推导了考虑主应力轴方向变化影响的土体峰值应力比与中主应力比关系的计算公式,获得了土体峰值内摩擦角随中主应力比及大主应力偏转角的变化特性.通过与不同沉积面角度条件下的三轴试验及空心圆柱扭剪试验结果对比表明,理论公式预测的内摩擦角与试验结果一致.

True triaxial behavior of sandy soils under both drained and undrained conditions:A discrete element perspective

An advanced discrete element servomechanism that can simultaneously and independently control the evolution equations of six stress and strain components without introducing severe stress concentration is implemented.Such a comprehensive series of discrete element method simulations of both drained and undrained behavior of transversely isotropic sandy soils are successfully conducted in the true triaxial setting.During the simulation process,the evolution patterns of the load-bearing structure of the granular specimen are tracked using a contact-normal-based fabric tensor.The simulation results show that sandy soils exhibit more significant non-coaxiality between the loading direction and the major principal direction of the fabric tensor under extension than under compression.Therefore,the fabric of the sandy soils under extension has a stronger tendency to evolve toward the loading direction than that under compression,causing a more significant disturbance to the load-bearing structure.Consequently,compared with the extension loading condition,the transversely isotropic specimen under compression exhibits a higher shear strength and stronger dilatancy under drained conditions and a stronger liquefaction resistance under undrained conditions.

非均质性对岩石宏观力学特性的影响机制

岩石材料具有材料强度分布不均匀性和材料空间组构随机性的双重特性,从本质上看两种特性都属于岩石材料的非均质性,都对岩石力学性质有深刻影响。在以往的研究中,通常使用有限元法和Weibull分布函数模拟岩石材料强度的非均质特点,用变异系数定义非均质度的大小,得到非均质度与岩石强度力学特性之间的关系,缺少了对材料组构随机性的探索。使用DDA方法和正态分布函数建立非均质脆性岩石单轴压缩数值实验模型,研究了非均质度和材料组构对岩石强度的影响。研究结果表明:随着岩石非均质度的增大,岩石的极限承载力减小;岩石中两接触单元的弹性模量差异越大,应变差异越大,接触面成为易发生破坏的力学薄弱环节。在相同非均质度的岩石样本中,不同组构的样本力学薄弱环节分布不同,导致岩石破裂路径和力学特性也不相同。

Effect of NiAl content on phases and microstructures of TiC-TiB_2-NiAl composites fabricated by reaction synthesis

TiC-TiB2-NiAl composites were fabricated by self-propagating high temperature reaction synthesis（SHS） with Ti, B4C, Ni and Al powders as raw materials. The effects of NiAl content on phase constituents and microstructures were investigated. The results show that the reaction products are composed of TiB2, TiC and NiAl. The content of NiAl increases with the adding of Ni＋Al in green compacts. TiB2, TiC and NiAl grains present in different shapes in the matrix, TiB2 being in hexagonal or rectangular shapes, TiC in spherical shapes, and NiAl squeezed into the gaps of TiC and TiB2 grains. With the increase of NiAl content, the grains of TiC-TiB2-NiAl composites are refined, their density and compressive strength are improved, and the shapes of TiC grains become spherical instead of irregular ones. Finally, the fracture mechanism of the composites transforms from intergranular fracture mode to the compounded fracture mode of intergranular fracture and transgranular fracture.

Microstructure of TA2/TA15 graded structural material by laser additive manufacturing process

TA2/TA15 graded structural material（GSM） was fabricated by the laser additive manufacturing（LAM） process. The chemical composition, microstructure and micro-hardness of the as-deposited GSM were investigated. The results show that the TA2 part of exhibiting near-equiaxed grains was Widmanst？tten α-laths microstructure. The TA15 part containing large columnar grains was fine basket-weave microstructure. The graded zone was divided into four deposited layers with 3000 μm in thickness. As the distance from the TA2 part increases, the alloy element contents and the β phase volume fraction increase, the α phase volume fraction decreases and the microstructure shows the evolution from Widmanst？tten α-laths to basket-weave α-laths gradually. The micro-hardness increases from the TA2 part to the TA15 part due to the solid solution strengthening and grain boundary strengthening.

Hot deformation behaviors of 35% SiC_p/2024Al metal matrix composites

The hot deformation behaviors of 35%SiCp/2024 aluminum alloy composites were studied by hot compression tests using Gleeble-1500D thermo-mechanical simulator at temperatures ranging from 350 to 500 °C under strain rates of 0.01-10 s-1. The true stress-true strain curves were obtained in the tests. Constitutive equation and processing map were established. The results show that the flow stress decreases with the increase of deformation temperature at a constant strain rate, and increases with the increase of strain rate at constant temperature, indicating that composite is a positive strain rate sensitive material. The flow stress behavior of composite during hot compression deformation can be represented by a Zener-Hollomon parameter in the hyperbolic sine form. Its activation energy for hot deformation Q is 225.4 kJ/mol. To demonstrate the potential workability, the stable zones and the instability zones in the processing map were identified and verified through micrographs. Considering processing map and microstructure, the hot deformation should be carried out at the temperature of 500 °C and the strain rate of 0.1-1 s-1.

Microstructure stability of Ti_2Al N/Ti-48Al-2Cr-2Nb composite at 900 °C

Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison. The result showed that in the TiAl alloy,α2 lamellae thinned and were broken down, and became discontinuous with increasing aging time. The decomposition ofα2 lamella toγ which was characterized by parallel decomposition and breakdown ofα2 lamellae led to the degradation of the lamellar structure. While in the composite, lamellar structure remained relatively stable even after aging at 900 ℃ for 100 h. No breakdown ofα2 lamellae except parallel decomposition and precipitation of fine nitride particles was observed. The better microstructural stability of the composite was mainly attributed to the precipitation of Ti2AlN particles at theα2/γ interface which played an important role in retarding the coarsening of lamellar microstructure in the matrix of composite.

Die sinter bonding in air using copper formate preform for formation of full-density bondline

Pressure-assisted sinter bonding was performed in air at 250−350℃ using a preform comprising copper formate particles to form a bondline that is sustainable at high temperatures.H2 and CO generated concurrently by the pyrolysis of copper formate at 210℃ during the sinter bonding removed the native oxide and other oxides grown on bulk Cu finishes,enabling interface bonding.Moreover,Cu produced in situ by the reduction of Cu(II)accelerated the sinter bonding.Consequently,the bonding achieved at 300−350℃ under 5 MPa exhibited sufficient shear strength of 20.0−31.5 MPa after 180−300 min of sinter bonding.In addition,an increase in pressure to 10 MPa resulted in shear strength of 21.9 MPa after an extremely short time of 30 s at 250℃,and a near-full-density bondline was achieved after 300 s.The obtained results indicate the promising potential of the preform comprising copper formate particles for high-speed sinter bonding.

Multistable Mechanical Metamaterials:A Brief Review

Over the past decade,multistable mechanical metamaterials have been widely investigated because of their novel shape reconfigurability and programmable energy landscape.The ability to reversibly reshape among diverse stable states with different energy levels represents the most important feature of the multistable mechanical metamaterials.We summarize main design strategies of multistable mechanical metamaterials,including those based on self-assembly scheme,snap-through instability,structured mechanism and geometrical frustration,with a focus on the number and controllability of accessible stable states.Then we concentrate on unusual mechanical properties of these multistable mechanical metamaterials,and present their applications in a wide range of areas,including tunable electromagnetic devices,actuators,robotics,and mechanical logic gates.Finally,we discuss remaining challenges and open opportunities of designs and applications of multistable mechanical metamaterials.

Microstructure and mechanical properties of TA15/TC11 graded structural material by wire arc additive manufacturing process

A graded structural material(GSM)with a material transition from TA15 to TC11 was fabricated by wire arc additive manufacturing(WAAM)method.The grain morphology,chemical composition,microstructure and mechanical properties of the as-deposited GSM were all characterized to investigate their variations along the deposition direction.The results indicate that from TA15 to TC11,the grain size decreases and a transition from columnar grains to equiaxed grains occurs.The content of alloy element alters greatly within a short distance,and the width of the mutation zone is 800μm.Both TA15 and TC11 regions exhibit basketweave microstructure withα-phase andβ-phase.However,during the transition from TA15 to TC11,theα-lath becomes fine,which leads to an increase in microhardness.The tensile test shows that the bonding strength at the interface is higher than the longitudinal strength of TA15,and the lateral elongation at the interface is higher than that of TA15 and TC11.

Phase composition, transition and structure stability of functionally graded cemented carbide with dual phase structure

The phase composition, phase transition and phase structure transformation of the wire-cut section of functionally graded WC-Co cemented carbide with dual phase structure were investigated by XRD phase analysis. It is shown that the composition of η phase in the core zone is Co_3W_3C (M_6 C type). The structure of cobalt based solid solution binder phase is fcc type. At the cooling stage of the sintering process, the phase transition of η phase, i.e. M_6C→M_12C and the martensitic phase transition of the cobalt based solid solution binder phase, i.e. fcc→hcp are suppressed, which facilitates the strengthening of the alloy. Because the instantaneous temperature of the discharge channel is as high as 10 000 ℃ during the wire cutting process, the processed surface is oxidized. Nevertheless, the oxide layer thickness is in micro grade. In the oxide film, η phase is decomposed into W_2C and CoO, and cobalt based solid solution binder is selectively oxidized, while WC remains stable due to the existence of carbon containing liquid organic cutting medium.

Hybrid terahertz metamaterial structure formed by assembling a split ring resonator with a metal mesh

We propose a novel metamaterial structure operating at the terahertz band. This structure is assembled by a split ring resonator (SRR) with a metal mesh within a unit cell. Our experimental studies on the composite structure indicate that the coupling of the SRR and metal mesh significantly contribute to the transparency at the terahertz range. Moreover, we experimentally demonstrated the verity of transmission peak of this structure by changing the relative positions of the SRR and the metal mesh. The simulated electric field redistributions support the dependence between position of the two components and the transmission response. This study is the first to report a hybrid metamaterial structure consisting of an SRR array and a metal mesh within a unit cell. The designed process and resonance characteristics of this composite structure make it an excellent candidate for developing tunable terahertz components via integration with the MEMS (Micro Electronic Mechanical System) technology.

Uptake of magnetic nanoparticles for adipose-derived stem cells with multiple passage numbers

With the increasingly promising role of nanomaterials in tissue engineering and regenerative medicine, the interaction between stem cells and nanoparticles has become a critical focus. The entry of nanoparticles into cells has become a primary issue for effectively regulating the subsequent safety and performance of nanomaterials in vivo. Although the influence of nanomaterials on endocytosis has been extensively studied, reports on the influence of stem cells are rare.Moreover, the effect of nanomaterials on stem cells is also dependent upon the action mode. Unfortunately, the interaction between stem cells and assembled nanoparticles is often neglected. In this paper, we explore for the first time the uptake of γ-Fe2O3 nanoparticles by adipose-derived stem cells with different passage numbers. The results demonstrate that cellular viability decreases and cell senescence level increases with the extension of the passage number. We found the surface appearance of cellular membranes to become increasingly rough and uneven with increasing passage numbers. The iron content in the dissociative nanoparticles was also significantly reduced with increases in the passage number. However, we observed multiple-passaged stem cells cultured on assembled nanoparticles to have similarly low iron content levels. The mechanism may lie in the magnetic effect of γ-Fe2O3 nanoparticles resulting from the field-directed assembly. The results of this work will facilitate the understanding and translation of nanomaterials in the clinical application of stem cells.

Use of compositional and combinatorial nanomaterial libraries for biological studies

Abstract The rapid development and production of nanomaterials has created some concerns about their potential hazard on the environment, human health and safety. However, since the list of materials that may gen- erate such concerns is very long, it is impossible to test them all. It is therefore usually recommended to use some small compositional nanomaterial libraries to perform ini- tial toxicity screening, based on which combinatorial libraries are then introduced for more in-depth studies. All nanomaterials in the compositional and combinatorial libraries must be rigorously characterized before any bio- logical studies. In this review, several major categories of physicochemical properties that must be characterized are discussed, along with different analytical techniques that are commonly used. Some case studies from the University of California Center for Environmental Implications of Nanotechnology are also chosen to demonstrate the effec- tive use of compositional and combinatorial nanomaterials libraries to identify the role of some key physicochemical properties and to establish true quantitative structure-ac- tivity relationships. Examples on how to use the knowledge generated from those studies to design safer nanomaterials for improved biological applications are also presented.

Recent developments of rare-earth-free hard-magnetic materials

Recent advances in rare-earth-free hard-magnetic materials including magnetic bulk, thin films, nanocomposites and nanostructures are introduced. Since the costs of the rare-earth metals boosts up the price of the high-performance rare-earth permanent magnets, there is a much revived interest in various types of hard-magnetic materials based on rare-earth-free compounds. The 3d transition metals and their alloys with large coercivity and high Curie temperatures(working temperatures) are expected to overcome the disadvantages of rare-earth magnets. Making rare-earth-free magnets with a large energy product to meet tomorrow's energy needs is still a challenge.