[Objective] To screen out a microbial flocculant with good decolorization effect on methyl orange wastewater,and study the effect of different cultural conditions on decolorization effect of methyl orange.[Method] Abs...[Objective] To screen out a microbial flocculant with good decolorization effect on methyl orange wastewater,and study the effect of different cultural conditions on decolorization effect of methyl orange.[Method] Absorbance of methyl orange solution before and after decolorization was determined by spectrophotometer,and the decolorization rate was calculated to compare the effects of different cultural conditions on removal rate of methyl orange.[Result]An optimal actinomycete stain(F-1-2) was screened out,and the best cultural condition was as follows:with sucrose as carbon source and NaNO3 as nitrogen source,cultured in constant temperature oscillator at 150 r/min,30℃ for 72 h.Under the optimal condition,the removal rate against methyl orange could reach 68.4%.[Conclusion]Different culture conditions have great impact on decolorization effect of strain.展开更多
The behaviors of inorganic nitrogen species in three types of bioretention columns under an intermittently wetting regime were investigated. The mean NH+4—N, NO-3—N and total N(TN) removal efficiencies for the conve...The behaviors of inorganic nitrogen species in three types of bioretention columns under an intermittently wetting regime were investigated. The mean NH+4—N, NO-3—N and total N(TN) removal efficiencies for the conventional bioretention column(Col. T1) are 71%, 1% and 41%, for layered bioretention column with less permeable soil layer(Col. T2) the efficiencies are 83%, 84% and 82%, and for the bioretention column with submerged zone(Col. T3) the values are 63%, 31% and 53%, respectively. The best nitrogen removal is obtained using Col. T2 with relatively low infiltration rate. Adsorption during runoff dosing and nitrification during the drying period are the primary NH+4—N removal pathways. Less permeable soil and the elevated outlet promote the formation of anoxic conditions. 30%–70% of NO-3—N applied to columns in a single repetition is denitrified during the draining period, suggesting that the draining period is an important timeframe for the removal of NO-3—N. Infiltration rate controls the contact time with media during the draining periods, greatly influencing the NO-3—N removal effects. Bioretention systems with infiltration rate ranging from 3 to 7 cm/h have a great potential to remove NO-3—N.展开更多
In order to investigate the competition for carbon source between denitrification and phosphorus release processes,simultaneous phosphorus release and denitrification in sludge operated in anoxic,aerobic mode are inve...In order to investigate the competition for carbon source between denitrification and phosphorus release processes,simultaneous phosphorus release and denitrification in sludge operated in anoxic,aerobic mode are investigated by varying the ratio of influent COD to nitrogenous compound concentration under anoxic condition using a lab-scale sequencing batch reactor(SBR).The results show that the nitrate reduction rate is nearly independent of the ratio of influent COD to nitrate under anoxic condition.More NOx^--N in the influent leads to less PO4^3--P release during the feeding period.However, PO4^3--P release proceeds at a low rate simultaneously with denitrification even when the influent NOx^--N concentration is as large as 20 mg·L^-1and its rate is increased obviously when NOx^--N is denitrified to a concentration lower than 0.5 mg·L^-1.The variation of pH during anoxic period gives some information about the biochemical reactions of denitrification and PO4^3--P release.When more nitrate is present in the influent,more acetate uptake in feeding period is used for direct microorganism growth.展开更多
To enhance the nitrogen removal,a systemic monitoring of the biological and hydrological parameters of Carrousel oxidation ditch in Chongqing Jingkou Wastewater Treatment Plant was carried out to study the feasibility...To enhance the nitrogen removal,a systemic monitoring of the biological and hydrological parameters of Carrousel oxidation ditch in Chongqing Jingkou Wastewater Treatment Plant was carried out to study the feasibility of simultaneous nitrification and denitrification(SND).The variation and distribution of parameters such as flow velocity,concentration of dissolved oxygen(DO) and mixed liquor suspended solids(MLSS) in oxidation ditch were monitored and analyzed,which were major control factors for SND.The results showed that,the dimensional distribution of flow velocity,DO and MLSS were affected significantly by the operation condition of the aeration wheels.With all the four aeration wheels being in operation,DO and flow velocity were higher and the mixing of MLSS was sufficient.With three aeration wheels being in operation,the flow velocity in most of the bottom areas was enough to meet the basic requirements of no deposition,and the anaerobic region and aerobic region could exist simultaneously in one oxidation ditch,which was helpful to the process of SND.According to spatial distribution characteristics of the flow velocity,DO and soluble components under optimized condition,different functional zones of biochemical reaction in the Carrousel oxidation ditch system were defined,which might contribute to the optimization control and SND of Carrousel oxidation ditch.展开更多
Dealloyed ribbons with a layer of networked nanoporous structure of different pore sizes were fabricated by dealloying the as-spun Mg_(65)Cu_(25-x)Ag_(x)Y_(10)(x=0,5,10,at.%)ribbons in dilute H_(2)SO_(4) solution in o...Dealloyed ribbons with a layer of networked nanoporous structure of different pore sizes were fabricated by dealloying the as-spun Mg_(65)Cu_(25-x)Ag_(x)Y_(10)(x=0,5,10,at.%)ribbons in dilute H_(2)SO_(4) solution in order to enhance the degradation efficiency of pesticide wastewater.Compared to the as-spun ribbons,it is found that the dealloyed ribbons with the networked nanoporous structure exhibit higher degradation efficiency due to their large specific surface areas and enough active sites for the degradation process.Both the average pore sizes of the nanoporous structure and the degradation efficiency of the pesticide wastewater increase with the increase of Ag addition in the dealloyed ribbons.The maximum degradation efficiency up to 95.8%is obtained for the Mg_(65)Cu_(15)Ag_(10)Y_(10)dealloyed ribbon under the optimal conditions of pH being 3,the initial cis-cypermethrin concentration being 500 mg/L,and the dosage of dealloyed ribbon being 1.33 g/L.展开更多
In this study, the rice straw was hydrolysed by using 3.0% (w/v) H2SO4 followed by enzymatic hydrolysis. The rice straw hydrolysate obtained was treated with charcoal powder and the optimal condition of detoxificati...In this study, the rice straw was hydrolysed by using 3.0% (w/v) H2SO4 followed by enzymatic hydrolysis. The rice straw hydrolysate obtained was treated with charcoal powder and the optimal condition of detoxification with charcoal powder was investigated. The results showed that the optimal condition for detoxification was the use of 2.5 grams of non-sterilized charcoal powder in 100 mL hydrolysate. The mixture was operated at pH 5.0, 30 ℃ and 160 rpm for 5 min. The detoxified hydrolysate was then used for ethanol production using P. stipitis TISTR 5806. The condition of the detoxified hydrolysate fermentation which gave maximum ethanol concentration of 21 g/L was at pH 5.0, 30 ℃ and 160 rpm for 72 h. Without detoxification, the P. stipitis TISTR 5806 could not however utilize the hydrolysate for ethanol production.展开更多
Thermal dehydration of gypsum and borogypsum was investigated under nonisothermal conditions in air by using simultaneous thermogravimetric-differential thermal analyzer. Nonisothermal experiments were carried out at ...Thermal dehydration of gypsum and borogypsum was investigated under nonisothermal conditions in air by using simultaneous thermogravimetric-differential thermal analyzer. Nonisothermal experiments were carried out at various linear heating rates. Kinetics of dehydration in the temperature range of 373-503 K were evaluated from the DTA (differential thermal analysis)-TGA (thermogravimetric analysis) data by means of Coats-Redfern,Kissinger and Doyle Equations. Values of the activation energy and the pre-exponential factor of the dehydration were calculated. The results of thermal experiments and kinetic parameters indicated that borogypsum is similar to gypsum from dehydration mechanism point of view although it consists of boron and small amount of alkali metal oxides.展开更多
Oxidative desulfurization (ODS) of Azeri crude oil was studied under the electric field.By means of orthogonal experiments,the optimum conditions for desulfurization of crude oil were identified,while the effect of ox...Oxidative desulfurization (ODS) of Azeri crude oil was studied under the electric field.By means of orthogonal experiments,the optimum conditions for desulfurization of crude oil were identified,while the effect of oxidative desulfurization under the electric field was compared with that of the single oxidative desulfurization method.The test results showed that the desulfurization reaction taking place under the electric field would be better than the traditional method.The desulfurization rate of crude oil could reach up to 77.06% at 115 ℃ at a distilled water amount of 10 m%,a desulfurizer dosage of 200 μg/g,and a demulsifier dosage of 50 μg/g.展开更多
Adsorption experiment from aqueous solutions containing known amount of Cr (chromium) using chitosan was explored to evaluate the efficiency of chitosan as sorbent for Cr. Some variable parameters such as pH, reacti...Adsorption experiment from aqueous solutions containing known amount of Cr (chromium) using chitosan was explored to evaluate the efficiency of chitosan as sorbent for Cr. Some variable parameters such as pH, reaction time and chitosan dosage were optimized. Under the optimum experiment condition, the effect of common ions on the adsorption of Cr (i.e., Na^+, K^+, Mg^2+, Ca^2+ for Cr(Ⅲ), and Cl^-, NO3^-, SO4^2- for Cr(Ⅵ)) was also investigated. Furthermore, the sorption mechanism of Cr by chitosan was investigated by applying Langmuir and Freundlich isotherm equations to the data obtained. In addition, to confirm the characteristics of the chitosan, the surface morphology of the biomass was determined by SEM (scanning electron microscope) and specific surface area analyzer (N2-BET (Brunaeur, Emmet and Teller)). Consequently, the following matters have been mainly clarified: (1) chitosan can be an efficient sorbent for Cr (both Cr(Ⅲ) and Cr(Ⅵ)); (2) the effect of common ions on the adsorption ofCr (Cr(Ⅲ) and Cr(Ⅵ)) was not significant under this experimental conditions; (3) adsorption isotherms using the chitosan can be generally described by Langmuir isotherm more satisfactorily for Cr. The adsorption may have occurred mainly by monolayer reaction; (4) the rates of adsorption were found to conform to pseudo-second order kinetics.展开更多
The present study is intended to be an analysis of the main Romanian legal provision in what concerns the impact of foreign exchange differences and potential consequences at the level of financial statements for comp...The present study is intended to be an analysis of the main Romanian legal provision in what concerns the impact of foreign exchange differences and potential consequences at the level of financial statements for companies. In Romanian legislation, the issue of the foreign exchange differences is treated at a general level: these are recognized as a profit and loss item and as a consequence, they are included in the taxable base when booked in the accounting. Our legislation does not provide for specific treatments depending on the 'realization momenf' of these differences or depending on the conditions for recognizing a gain/loss from foreign exchange differences. For the unrealized exchange differences arising from the application of accounting rules on monthly assessment of foreign currency monetary items, there is not a specific event or transaction to determine income or expenditure. This monthly review depending on the National Bank of Romania [BNR] foreign exchange rate valid on the last day of the month aims to bring closer to reality the financial position of an entity. The exchange rate is a monetary policy item set by the central bank and may be influenced by various factors such as: monetary policy of the BNR; inflation target objectives and rate of exchange stabilization or reduction efforts, as is the case of BNR in the last years to fulfill EU criteria for adoption of the EURO; periodical influences of speculative capitals on the exchange rate level; economic status and especially exports and imports. However, a taxpayer should not be charged unless there is evidence of the "economic enrichment" thereof. However, this enrichment, seen as a rising economic value of the company, depends on the perspective from which is seen: the owner of the company or the tax authorities. The exchange differences impact also the value of the owners' equity for which a minimum level is requested under the commercial company law. In case of negative values, this triggers various risks at the level of the continuity principle or even endangers the existence of the company.展开更多
基金Supported by National Natural Science Foundation of China(51064011)Jiangxi Education Science " Twelfth Five-year" Planning Program (10YB335)Science Foundation for Youths of Jiangxi Educational Committee (GJJ09599)~~
文摘[Objective] To screen out a microbial flocculant with good decolorization effect on methyl orange wastewater,and study the effect of different cultural conditions on decolorization effect of methyl orange.[Method] Absorbance of methyl orange solution before and after decolorization was determined by spectrophotometer,and the decolorization rate was calculated to compare the effects of different cultural conditions on removal rate of methyl orange.[Result]An optimal actinomycete stain(F-1-2) was screened out,and the best cultural condition was as follows:with sucrose as carbon source and NaNO3 as nitrogen source,cultured in constant temperature oscillator at 150 r/min,30℃ for 72 h.Under the optimal condition,the removal rate against methyl orange could reach 68.4%.[Conclusion]Different culture conditions have great impact on decolorization effect of strain.
基金Project(2011ZX07303-002)supported by National Water Pollution Control and Management Technology Major Program,China
文摘The behaviors of inorganic nitrogen species in three types of bioretention columns under an intermittently wetting regime were investigated. The mean NH+4—N, NO-3—N and total N(TN) removal efficiencies for the conventional bioretention column(Col. T1) are 71%, 1% and 41%, for layered bioretention column with less permeable soil layer(Col. T2) the efficiencies are 83%, 84% and 82%, and for the bioretention column with submerged zone(Col. T3) the values are 63%, 31% and 53%, respectively. The best nitrogen removal is obtained using Col. T2 with relatively low infiltration rate. Adsorption during runoff dosing and nitrification during the drying period are the primary NH+4—N removal pathways. Less permeable soil and the elevated outlet promote the formation of anoxic conditions. 30%–70% of NO-3—N applied to columns in a single repetition is denitrified during the draining period, suggesting that the draining period is an important timeframe for the removal of NO-3—N. Infiltration rate controls the contact time with media during the draining periods, greatly influencing the NO-3—N removal effects. Bioretention systems with infiltration rate ranging from 3 to 7 cm/h have a great potential to remove NO-3—N.
基金Supported by the Scientific Innovation Platform of Beijing Municipal Education Commission(PXM2008_014204_050843)State Key Laboratory of Urban Water Resource and Environment(HIT)(QAK200802)Environment and Water Industry(EWI)Development Scheme of Singapore-The Process Control and Enhanced Biological Nutrient Removal of CSTR Proc-ess(EDB S07/1-53974082)
文摘In order to investigate the competition for carbon source between denitrification and phosphorus release processes,simultaneous phosphorus release and denitrification in sludge operated in anoxic,aerobic mode are investigated by varying the ratio of influent COD to nitrogenous compound concentration under anoxic condition using a lab-scale sequencing batch reactor(SBR).The results show that the nitrate reduction rate is nearly independent of the ratio of influent COD to nitrate under anoxic condition.More NOx^--N in the influent leads to less PO4^3--P release during the feeding period.However, PO4^3--P release proceeds at a low rate simultaneously with denitrification even when the influent NOx^--N concentration is as large as 20 mg·L^-1and its rate is increased obviously when NOx^--N is denitrified to a concentration lower than 0.5 mg·L^-1.The variation of pH during anoxic period gives some information about the biochemical reactions of denitrification and PO4^3--P release.When more nitrate is present in the influent,more acetate uptake in feeding period is used for direct microorganism growth.
基金Project(2009ZX07315-002-01) supported by the Water Pollution Control and Management of Major Special Science and Technology, China Project(CDJXS11210001) supported by the Scientific and Technical Innovation Project of Chongqing University Graduation Foundation, China
文摘To enhance the nitrogen removal,a systemic monitoring of the biological and hydrological parameters of Carrousel oxidation ditch in Chongqing Jingkou Wastewater Treatment Plant was carried out to study the feasibility of simultaneous nitrification and denitrification(SND).The variation and distribution of parameters such as flow velocity,concentration of dissolved oxygen(DO) and mixed liquor suspended solids(MLSS) in oxidation ditch were monitored and analyzed,which were major control factors for SND.The results showed that,the dimensional distribution of flow velocity,DO and MLSS were affected significantly by the operation condition of the aeration wheels.With all the four aeration wheels being in operation,DO and flow velocity were higher and the mixing of MLSS was sufficient.With three aeration wheels being in operation,the flow velocity in most of the bottom areas was enough to meet the basic requirements of no deposition,and the anaerobic region and aerobic region could exist simultaneously in one oxidation ditch,which was helpful to the process of SND.According to spatial distribution characteristics of the flow velocity,DO and soluble components under optimized condition,different functional zones of biochemical reaction in the Carrousel oxidation ditch system were defined,which might contribute to the optimization control and SND of Carrousel oxidation ditch.
基金the financial supports from State Key Laboratory of Light Alloy Casting Technology for High-end Equipmentthe Natural Science Foundation of Liaoning Province,China(No.2020-KF-14-03)the National Natural Science Foundation of China(No.51775353)。
文摘Dealloyed ribbons with a layer of networked nanoporous structure of different pore sizes were fabricated by dealloying the as-spun Mg_(65)Cu_(25-x)Ag_(x)Y_(10)(x=0,5,10,at.%)ribbons in dilute H_(2)SO_(4) solution in order to enhance the degradation efficiency of pesticide wastewater.Compared to the as-spun ribbons,it is found that the dealloyed ribbons with the networked nanoporous structure exhibit higher degradation efficiency due to their large specific surface areas and enough active sites for the degradation process.Both the average pore sizes of the nanoporous structure and the degradation efficiency of the pesticide wastewater increase with the increase of Ag addition in the dealloyed ribbons.The maximum degradation efficiency up to 95.8%is obtained for the Mg_(65)Cu_(15)Ag_(10)Y_(10)dealloyed ribbon under the optimal conditions of pH being 3,the initial cis-cypermethrin concentration being 500 mg/L,and the dosage of dealloyed ribbon being 1.33 g/L.
文摘In this study, the rice straw was hydrolysed by using 3.0% (w/v) H2SO4 followed by enzymatic hydrolysis. The rice straw hydrolysate obtained was treated with charcoal powder and the optimal condition of detoxification with charcoal powder was investigated. The results showed that the optimal condition for detoxification was the use of 2.5 grams of non-sterilized charcoal powder in 100 mL hydrolysate. The mixture was operated at pH 5.0, 30 ℃ and 160 rpm for 5 min. The detoxified hydrolysate was then used for ethanol production using P. stipitis TISTR 5806. The condition of the detoxified hydrolysate fermentation which gave maximum ethanol concentration of 21 g/L was at pH 5.0, 30 ℃ and 160 rpm for 72 h. Without detoxification, the P. stipitis TISTR 5806 could not however utilize the hydrolysate for ethanol production.
基金Supported by the Turkish Republic Prime Ministry State Planning Organization (No. 98-DPT-07-01-02) and the Yildiz Technical University Research Foundation (No. 95-B-07-01-04).
文摘Thermal dehydration of gypsum and borogypsum was investigated under nonisothermal conditions in air by using simultaneous thermogravimetric-differential thermal analyzer. Nonisothermal experiments were carried out at various linear heating rates. Kinetics of dehydration in the temperature range of 373-503 K were evaluated from the DTA (differential thermal analysis)-TGA (thermogravimetric analysis) data by means of Coats-Redfern,Kissinger and Doyle Equations. Values of the activation energy and the pre-exponential factor of the dehydration were calculated. The results of thermal experiments and kinetic parameters indicated that borogypsum is similar to gypsum from dehydration mechanism point of view although it consists of boron and small amount of alkali metal oxides.
基金financial supports from the Science and Technology Office of Liaoning Province (Project number:2008403001)the Liaoning Provincial Office of Education for Innovation Team (Project number:2009T002)
文摘Oxidative desulfurization (ODS) of Azeri crude oil was studied under the electric field.By means of orthogonal experiments,the optimum conditions for desulfurization of crude oil were identified,while the effect of oxidative desulfurization under the electric field was compared with that of the single oxidative desulfurization method.The test results showed that the desulfurization reaction taking place under the electric field would be better than the traditional method.The desulfurization rate of crude oil could reach up to 77.06% at 115 ℃ at a distilled water amount of 10 m%,a desulfurizer dosage of 200 μg/g,and a demulsifier dosage of 50 μg/g.
文摘Adsorption experiment from aqueous solutions containing known amount of Cr (chromium) using chitosan was explored to evaluate the efficiency of chitosan as sorbent for Cr. Some variable parameters such as pH, reaction time and chitosan dosage were optimized. Under the optimum experiment condition, the effect of common ions on the adsorption of Cr (i.e., Na^+, K^+, Mg^2+, Ca^2+ for Cr(Ⅲ), and Cl^-, NO3^-, SO4^2- for Cr(Ⅵ)) was also investigated. Furthermore, the sorption mechanism of Cr by chitosan was investigated by applying Langmuir and Freundlich isotherm equations to the data obtained. In addition, to confirm the characteristics of the chitosan, the surface morphology of the biomass was determined by SEM (scanning electron microscope) and specific surface area analyzer (N2-BET (Brunaeur, Emmet and Teller)). Consequently, the following matters have been mainly clarified: (1) chitosan can be an efficient sorbent for Cr (both Cr(Ⅲ) and Cr(Ⅵ)); (2) the effect of common ions on the adsorption ofCr (Cr(Ⅲ) and Cr(Ⅵ)) was not significant under this experimental conditions; (3) adsorption isotherms using the chitosan can be generally described by Langmuir isotherm more satisfactorily for Cr. The adsorption may have occurred mainly by monolayer reaction; (4) the rates of adsorption were found to conform to pseudo-second order kinetics.
文摘The present study is intended to be an analysis of the main Romanian legal provision in what concerns the impact of foreign exchange differences and potential consequences at the level of financial statements for companies. In Romanian legislation, the issue of the foreign exchange differences is treated at a general level: these are recognized as a profit and loss item and as a consequence, they are included in the taxable base when booked in the accounting. Our legislation does not provide for specific treatments depending on the 'realization momenf' of these differences or depending on the conditions for recognizing a gain/loss from foreign exchange differences. For the unrealized exchange differences arising from the application of accounting rules on monthly assessment of foreign currency monetary items, there is not a specific event or transaction to determine income or expenditure. This monthly review depending on the National Bank of Romania [BNR] foreign exchange rate valid on the last day of the month aims to bring closer to reality the financial position of an entity. The exchange rate is a monetary policy item set by the central bank and may be influenced by various factors such as: monetary policy of the BNR; inflation target objectives and rate of exchange stabilization or reduction efforts, as is the case of BNR in the last years to fulfill EU criteria for adoption of the EURO; periodical influences of speculative capitals on the exchange rate level; economic status and especially exports and imports. However, a taxpayer should not be charged unless there is evidence of the "economic enrichment" thereof. However, this enrichment, seen as a rising economic value of the company, depends on the perspective from which is seen: the owner of the company or the tax authorities. The exchange differences impact also the value of the owners' equity for which a minimum level is requested under the commercial company law. In case of negative values, this triggers various risks at the level of the continuity principle or even endangers the existence of the company.