厚度可控薄板形Silicalite-1的制备(英文)

通过精细调整控制合成条件,在SiO2-TPAOH-H2O-NH4F(TPAOH:四丙基氢氧化铵)体系中制备出了厚度可控的薄板型Silicalite-1分子筛材料,并利用扫描电镜(SEM)、高分辨透射电镜(HRTEM)、粉末X射线衍射(XRD)及差热-热重分析(TG-DTA)对样品的结构信息、样品形貌及物理化学性质进行了表征.研究表明,NH4F浓度和反应体系pH值对Silicalite-1分子筛的形貌起着重要的导向作用.随着NH4F/SiO2的摩尔比(n(NH4F)/n(SiO2))由0增加到0.18,分子筛形貌由交互生长的椭圆形变为板形,其厚度也逐渐变薄;当n(NH4F)/n(SiO2)=0.4时,厚度达到最薄.继续增加NH4F/SiO2的摩尔比,其厚度增加,这是由于F-提高了样品结晶度.HRTEM研究表明b轴垂直于平面,由于在MFI结构的材料中,b轴方向是其直孔道方向,这种材料有利于客体分子的进出.还研究了样品的热稳性,所有样品在1100°C焙烧2h后,其形貌和结构不发生变化.

Analysis of bulging process of aluminum alloy by overlapping sheet metal and its formability

The influences of strength coefficient K, work hardening exponent n and thickness t of the overlapping sheet on bulging process are analyzed based on hardening material model. Also, bulging experiments are carried out by taking the aluminum alloy LF21 as formed sheet metal, and selecting overlapping sheet with different thicknesses and material properties, by which accuracy of the above analysis result is verified in the aspects of geometric shape, thickness distribution and limit bulging height. The results show that higher strength coefficient K, larger work hardening exponent n and proper thickness of the overlapping sheet are helpful to improve the formability and forming uniformity of formed sheet metal.

Three-dimensional analysis of a thick FGM rectangular plate in thermal environment

The thermal behavior of a thick transversely isotropic FGM rectangular plate was investigated within the scope of three-dimensional elasticity. Noticing many FGMs may have temperature-dependent properties, the material constants were further considered as functions of temperature. A solution method based on state-space formulations with a laminate approximate model was proposed. For a thin plate, the method was clarified by comparison with the thin plate theory. The influences of material inhomogeneity and temperature-dependent characteristics were finally discussed through numerical examples.

Computational Simulation of Hypervelocity Penetration Using Adaptive SPH Method

The normal hypervelocity impact of an Al-thin plate by an Al-sphere was numerically simulated by using the adaptive smoothed particle hydrodynamics (ASPH) method. In this method, the isotropic smoothing algorithm of standard SPH is replaced with anisotropic smoothing involving ellipsoidal kernels whose axes evolve automatically to follow the mean particle spacing as it varies in time, space, and direction around each particle. Using the ASPH, the anisotropic volume changes under strong shock condition are captured more accurately and clearly. The sophisticated features of meshless and Lagrangian nature inherent in the SPH method are kept for treating large deformations, large inhomogeneities and tracing free surfaces in the extremely transient impact process. A two-dimensional ASPH program is coded with C++. The developed hydrocode is examined for example problems of hypervelocity impacts of solid materials. The results obtained from the numerical simulation are compared with available experimental ones. Good agreement is observed.

Formability of the AMS 5596 Sheet in Comparison with EDDQ Steel Sheet

Some materials form better than others, moreover, a material that has the best formability for one stamping may behave very poorly in a stamping of another Configuration. The forming limit of a metal sheet is generally given in terms of the limiting principal strains under different loading conditions and represented by the so-called FLD （forming limit diagram）. In view of the difficulty to experimentally determine the forming limits, many researchers have sought to predict FLD. The formability of sheet metal has frequently been expressed by the value of strain hardening exponent and plastic anisotropy ratio. The stress-strain and hardening behaviour of a material is very important in determining its resistance to plastic instability. For these reasons, extensive test programs are often carried out in an attempt to correlate material formability with value of some mechanical properties. In this study, mechanical properties and the FLD of the AMS 5596 sheet metal was determined by using uniaxial tensile test and Marciniak＇s flat bottomed punch test respectively.

Template-directed fabrication of 3D graphene-based composite and their electrochemical energy-related applications

Graphene shows great potentials in electrochemical energy-related areas.To enhance its properties and corresponding electrochemical performance,recently,three-dimensional(3D)graphene-based materials especially monolithic porous graphene with encapsulated functional nanomaterials have arisen much research interest for electrochemical catalysis,lithium ion batteries(LIBs),lithium–sulfur batteries,supercapacitors,etc.With the enhanced structure properties such as interconnected graphene network,high volume-specific surface area and electronic conductivity,3D monolithic graphene is more suitable for the fabrication of composite electrode materials in real devices.In this article,we discuss recent development in fabricating monolithic 3D graphene and their composites using template-directed methods and their applications in electrochemical energy-related areas.

Automatic recognition of intersecting features of freeform sheet metal parts

This paper presents an approach for recognizing both isolated and intersecting geometric features of freeform surface models of parts,for the purpose of automating the process planning of sheet metal forming.The developed methodology has three major steps:subdivision of B-spline surfaces,detection of protrusions and depressions,and recognition of geometric features for sheet metal forming domain.The input geometry data format of the part is based on an IGES CAD surface model represented in the form of trimmed B-spline surfaces.Each surface is classified or subdivided into different curvature regions with the aid of curvature property surfaces obtained by using symbolic computation of B-spline surfaces.Those regions satisfying a particular geometry and topology relation are recognized as protrusion and depression(DP) shapes.The DP shapes are then classified into different geometric features using a rule-based approach.A verified feasibility study of the developed method is also presented.

Multi-pulse orbits dynamics of composite laminated piezoelectric rectangular plate

The multi-pulse orbits and chaotic dynamics of a simply supported laminated composite piezoelectric rectangular plate under combined parametric excitation and transverse excitation are studied in detail. It is assumed that different layers are perfectly bonded to each other with piezoelectric actuator patches embedded. The nonlinear equations of motion for the laminated composite piezoelectric rectangular plate are derived from von Karman-type equation and third-order shear deformation plate theory of Reddy. The two-degree-of-freedom dimensionless equations of motion are obtained by using the Galerkin approach to the partial differential governing equation of motion for the laminated composite piezoelectric rectangular plate. The four-dimensional averaged equation in the case of primary parametric resonance and 1:3 internal resonances is obtained by using the method of multiple scales. From the averaged equation, the theory of normal form is used to find the explicit formulas of normal form. Based on the normal form obtained, the energy phase method is utilized to analyze the multi-pulse global bifurcations and chaotic dynamics for the laminated composite piezoelectric rectangular plate. The analysis of the global dynamics indicates that there exist multi-pulse jumping orbits in the perturbed phase space of the averaged equation. Based on the averaged equation obtained, the chaotic motions and the Shilnikov type multi-pulse orbits of the laminated composite piezoelectric rectangular plate are also found by numerical simulation. The results obtained above mean the existence of the chaos in the Smale horseshoe sense for the simply supported laminated composite piezoelectric rectangular plate.