Graphene shows great potentials in electrochemical energy-related areas.To enhance its properties and corresponding electrochemical performance,recently,three-dimensional(3D)graphene-based materials especially monolit...Graphene shows great potentials in electrochemical energy-related areas.To enhance its properties and corresponding electrochemical performance,recently,three-dimensional(3D)graphene-based materials especially monolithic porous graphene with encapsulated functional nanomaterials have arisen much research interest for electrochemical catalysis,lithium ion batteries(LIBs),lithium–sulfur batteries,supercapacitors,etc.With the enhanced structure properties such as interconnected graphene network,high volume-specific surface area and electronic conductivity,3D monolithic graphene is more suitable for the fabrication of composite electrode materials in real devices.In this article,we discuss recent development in fabricating monolithic 3D graphene and their composites using template-directed methods and their applications in electrochemical energy-related areas.展开更多
基金supported by Thousand Young Talents Program of the Chinese Central Government (0220002 102003)the National Natural Science Foundation of China (21373280)+2 种基金Beijing National Laboratory for Molecular Sciences (BNLMS)Hundred Talents Program at Chongqing University (0903005203205)Chongqing Basic and Frontier Research Project (cstc2015jcyj A50026)
文摘Graphene shows great potentials in electrochemical energy-related areas.To enhance its properties and corresponding electrochemical performance,recently,three-dimensional(3D)graphene-based materials especially monolithic porous graphene with encapsulated functional nanomaterials have arisen much research interest for electrochemical catalysis,lithium ion batteries(LIBs),lithium–sulfur batteries,supercapacitors,etc.With the enhanced structure properties such as interconnected graphene network,high volume-specific surface area and electronic conductivity,3D monolithic graphene is more suitable for the fabrication of composite electrode materials in real devices.In this article,we discuss recent development in fabricating monolithic 3D graphene and their composites using template-directed methods and their applications in electrochemical energy-related areas.