We present a general approach to fabricate metal/TiO2 core/shell nanorod structures by twostep electrodeposition. Firstly, TiO2 nanotubes with uniform wall thickness are prepared in anodic aluminum oxide (AAO) membr...We present a general approach to fabricate metal/TiO2 core/shell nanorod structures by twostep electrodeposition. Firstly, TiO2 nanotubes with uniform wall thickness are prepared in anodic aluminum oxide (AAO) membranes by electrodeposition. The wall thickness of the nanotubes could be easily controlled by modulating the deposition time, and their outer diameter and length are only limited by the channel diameter and the thickness of the AAO membranes, respectively. The nanotubes' tops prepared by this method are open, while the bottoms are connected directly with the Au film at the back of the AAO membranes. Secondly, Pd, Cu, and Fe elements are filled into the TiO2 nanotubes to form core/shell structures. The core/shell nanorods prepared by this two-step process are high density and free-standing, and their length is dependent on the deposition time.展开更多
The venom apparatus in the large carpenter bees, Xylocopafenestrata (Fabricius) (Hymenoptera: Apidae) has been studied It consists of typical parts, i.e., the venom sac, free filament, Dufour gland, sting shaft a...The venom apparatus in the large carpenter bees, Xylocopafenestrata (Fabricius) (Hymenoptera: Apidae) has been studied It consists of typical parts, i.e., the venom sac, free filament, Dufour gland, sting shaft and accessory sclerites. It is highly sclerotized and concealed by the 7th abdominal tergite and sternite. The venom sac serves as a reservoir for the venom which synthesized by the convoluted gland present in it, which is remarkably uniform to that of ants. The median duct extends from lower portion of venom sac, which measures 2.5 ±0.17 mm (mean + SD) (n = 20) in length. The Dufour gland is a tube-like structure which is inserted in the sting-bulb. The triangular plate is attached at terminal portion of rami, which is in turn attached with lancets. The gonostyli are paired long and tubular structure with 5.29 ± 0.23 mm (n = 20) in length. The sting length is 5.29 ±0.23 mm (n = 20). The fulcral arm is well-developed with an inverse Y-shaped structure present beneath the sting-bulb. Barbs on the sting shaft are weakly developed in X fenestrata but well developed in ants. The venom apparatus ofX. fenestrata when compared is similar to the bees but differs from that of the wasps and ants.展开更多
基金This work is supported by the National Natural Science Foundation of China (No.10574122, No.50772110, No.50721091) and the National Basic Research Program of China (No.2011CB921400, No.2007CB925202, No.2009CB939901).
文摘We present a general approach to fabricate metal/TiO2 core/shell nanorod structures by twostep electrodeposition. Firstly, TiO2 nanotubes with uniform wall thickness are prepared in anodic aluminum oxide (AAO) membranes by electrodeposition. The wall thickness of the nanotubes could be easily controlled by modulating the deposition time, and their outer diameter and length are only limited by the channel diameter and the thickness of the AAO membranes, respectively. The nanotubes' tops prepared by this method are open, while the bottoms are connected directly with the Au film at the back of the AAO membranes. Secondly, Pd, Cu, and Fe elements are filled into the TiO2 nanotubes to form core/shell structures. The core/shell nanorods prepared by this two-step process are high density and free-standing, and their length is dependent on the deposition time.
文摘The venom apparatus in the large carpenter bees, Xylocopafenestrata (Fabricius) (Hymenoptera: Apidae) has been studied It consists of typical parts, i.e., the venom sac, free filament, Dufour gland, sting shaft and accessory sclerites. It is highly sclerotized and concealed by the 7th abdominal tergite and sternite. The venom sac serves as a reservoir for the venom which synthesized by the convoluted gland present in it, which is remarkably uniform to that of ants. The median duct extends from lower portion of venom sac, which measures 2.5 ±0.17 mm (mean + SD) (n = 20) in length. The Dufour gland is a tube-like structure which is inserted in the sting-bulb. The triangular plate is attached at terminal portion of rami, which is in turn attached with lancets. The gonostyli are paired long and tubular structure with 5.29 ± 0.23 mm (n = 20) in length. The sting length is 5.29 ±0.23 mm (n = 20). The fulcral arm is well-developed with an inverse Y-shaped structure present beneath the sting-bulb. Barbs on the sting shaft are weakly developed in X fenestrata but well developed in ants. The venom apparatus ofX. fenestrata when compared is similar to the bees but differs from that of the wasps and ants.