Fe96-xZrxn4 （1〈x〈12） nanowires were prepared by electrodepositing into anodic aluminum oxide templates. The diameter of nanowires used is 100 nm and the aspect ratio is 75. The structure of the nanowire arrays was...Fe96-xZrxn4 （1〈x〈12） nanowires were prepared by electrodepositing into anodic aluminum oxide templates. The diameter of nanowires used is 100 nm and the aspect ratio is 75. The structure of the nanowire arrays was studied by selected area electron diffraction, X-ray diffraction and MOssbauer spectrometer. The phase structure of Fe96_xZrxB4 nanowires is changed from a crystalline phase to a homogenous amorphous phase with the increasing of Zr content. The Fe96_xZrxB4 nanowires are com- posed of a-Fe-like and Zr-rich FeZrB phases. With the increasing of Zr composition, the atoms of Fe site in both phases are more disorderly, and the ct-Fe-like phase decreasing with the FeZrB phase increasing. The anisotropy of Fe96_xZrxB4 nanowires becomes more obvious with the increasing of Zr content, and the easy magnetizing axis is parallel to the nanowire arrays.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.11074312)the Fundamental Research Funds for the Central Universities(Grant No.1112KYQN35)+3 种基金the"985 project"(Grant No.98507-012009)the Ministry of Education of Chinathe National Innovation and Training(Grant No.GCCX 2012110014)the Undergraduate Research Training Program of Minzu University of China(Grant Nos.URTP 2012110009 and URTP 2012110010)
文摘Fe96-xZrxn4 （1〈x〈12） nanowires were prepared by electrodepositing into anodic aluminum oxide templates. The diameter of nanowires used is 100 nm and the aspect ratio is 75. The structure of the nanowire arrays was studied by selected area electron diffraction, X-ray diffraction and MOssbauer spectrometer. The phase structure of Fe96_xZrxB4 nanowires is changed from a crystalline phase to a homogenous amorphous phase with the increasing of Zr content. The Fe96_xZrxB4 nanowires are com- posed of a-Fe-like and Zr-rich FeZrB phases. With the increasing of Zr composition, the atoms of Fe site in both phases are more disorderly, and the ct-Fe-like phase decreasing with the FeZrB phase increasing. The anisotropy of Fe96_xZrxB4 nanowires becomes more obvious with the increasing of Zr content, and the easy magnetizing axis is parallel to the nanowire arrays.
