Ti/TiN/Zr/ZrN multilayer coatings were deposited on Cr_17Ni_2 steel substrates with different surface roughnesses by vacuum cathodic arc deposition method. Microstructure, micro-hardness, adhesion strength and cross-s...Ti/TiN/Zr/ZrN multilayer coatings were deposited on Cr_17Ni_2 steel substrates with different surface roughnesses by vacuum cathodic arc deposition method. Microstructure, micro-hardness, adhesion strength and cross-sectional morphology of the obtained multilayer coatings were investigated. The results show that the Vickers hardness of Ti/TiN/Zr/ZrN multilayer coating, with a film thickness of 11.37 μm, is 29.36 GPa. The erosion and salt spray resistance performance of Cr_17Ni_2 steel substrates can be evidently improved by Ti/TiN/Zr/ZrN multilayer coating. The surface roughness of Cr_17Ni_2 steel substrates plays an important role in determining the mechanical and erosion performances of Ti/TiN/Zr/ZrN multilayer coatings. Overall, a low value of the surface roughness of substrates corresponds to an improved performance of erosion and salt spray resistance of multilayer coatings. The optimized performance of Ti/TiN/Zr/ZrN multilayer coatings can be achieved provided that the surface roughness of Cr_17Ni_2 steel substrates is lower than 0.4μm.展开更多
Zn reduction was investigated by the vacuum carbothermic reduction of hemimorphite with or without CaF2 as catalyst.Results indicate that CaF2 can catalyze the carbothermic reduction of zinc silicate,decrease the reac...Zn reduction was investigated by the vacuum carbothermic reduction of hemimorphite with or without CaF2 as catalyst.Results indicate that CaF2 can catalyze the carbothermic reduction of zinc silicate,decrease the reaction temperature and time.The lower the reaction temperature and the more the amount of CaF2,the better the catalytic effect.The optimal process condition is obtained as follows:the addition of about 10% CaF2,the reaction temperature of 1373 K,the molar ratio of C to ZnTotal of 2.5,the pressure of system lower than 20 kPa,the reaction time of about 40 min.Under the optimal process condition,the zinc reduction rate is about 93% from hemimorphite.展开更多
The finite element method is first introduced into the design process of detecting electrodes of three electrode capacitance fuze, the mutual capacitance of the fuze and target is calculated by the finite element met...The finite element method is first introduced into the design process of detecting electrodes of three electrode capacitance fuze, the mutual capacitance of the fuze and target is calculated by the finite element method, which provides the parameters for simulation circuit and design of detecting electrode. The finite element method pierces the traditional method of designing detecting electrode-design, test and adjustment. The system capacitance can be calculated accurately and the performance can be predicted in the design period of the detecting electrode, which saves a lot of research fee. The capacitances of a mortar shell fuze above ground 2 m and lower are given. After putting the computing data into simulating circuit, the demodulation voltage can be obtained, its changing trend is in agreement with the tested result.展开更多
The feasibility of separation of lead anode slime with low silver by vacuum distillation was analyzed theoretically. The volatilization rates and mass fractions of elements, influenced by distillation temperature, hea...The feasibility of separation of lead anode slime with low silver by vacuum distillation was analyzed theoretically. The volatilization rates and mass fractions of elements, influenced by distillation temperature, heat preservation time and material thickness, were investigated under laboratory conditions. The experimental results indicate that almost all of lead and bismuth can be separated from silver-contained multicomponent alloy at 1 223 K for 45 min when the chamber pressure maintains at 10-25 Pa. Silver can be easily enriched in the residue and its mass fraction increases from 3.6% to 27.8% when the distillation temperature is between 1 133 K and 1 373 K. Due to the forming ofintermetallic compounds Cu2Sb, Cul0Sb3 and Ag3Sb, the antimony could not be evaporated completely during the vacuum distillation. EDS analysis indicates that the condensate has a columnar crystal structure.展开更多
Ti0.5Al0.25Ni0.25 alloy prepared by vacuum induction melting was studied.The phase composition was analyzed with X-ray technique and EDS analysis,and its electrochemical properties were investigated at various tempera...Ti0.5Al0.25Ni0.25 alloy prepared by vacuum induction melting was studied.The phase composition was analyzed with X-ray technique and EDS analysis,and its electrochemical properties were investigated at various temperatures.Electrochemical reaction kinetic parameters were also studied with proper electrochemical techniques.The influence of the secondary corrosion reaction on the anodic linear polarization measurement was also analyzed by theoretical simulation.The results show that,proper ball-milling with nickel powders is beneficial to electrochemical performance.The theoretical simulation proves that,the existence of the side reaction can disturb the measurement of electrochemical reaction kinetic parameters.展开更多
A surface photocatalysis-TPD apparatus devoted to studying kinetics and mechanism of pho- tocatalytic processes with various signal crystal surfaces has been constructed. Extremely high vacuum (-0.2 nPa) in the ioni...A surface photocatalysis-TPD apparatus devoted to studying kinetics and mechanism of pho- tocatalytic processes with various signal crystal surfaces has been constructed. Extremely high vacuum (-0.2 nPa) in the ionization region is obtained by using multiple ultrahigh vacuum pumps. Compared with similar instruments built previously by others~ the H2, CH4 background in the ionization region can be reduced by about two orders of magnitude, and other residual gases in the ionization region can be reduced by about an order of magnitude. Therefore, the signal-to-noise ratio for the temperature programmed desorption (TPD) and time of flight (TOF) spectra is substantially enhanced, making experimental studies of pho- tocatalytic processes on surfaces much easier. In this work, we describe the new apparatus in detail and present some preliminary studies on the photo-induced oxygen vacancy defects on TiO2(110) at 266 nm by using the TPD and TOF methods. Preliminary results suggest that the apparatus is a powerful tool for studying kinetics and mechanism of photochemical processes.展开更多
A digital predistorted class-F power amplifier (PA) using Cree GaN HEMT CGH40010 operating at 2. 12 GHz is presented to obtain high efficiency and excellent linearity for wideband code-division multiple access ( WC...A digital predistorted class-F power amplifier (PA) using Cree GaN HEMT CGH40010 operating at 2. 12 GHz is presented to obtain high efficiency and excellent linearity for wideband code-division multiple access ( WCDMA ) applications. Measurement results with the continuous wave (CW) signals indicate that the designed class-F PA achieves a peak power-added efficiency (PAE) of 75. 2% with an output power of 39.4 dBm. The adjacent channel power ratio (ACPR) of the designed PA after digital predistortion (DPD) decreases from -28. 3 and -27. 5 dBc to -51.9 and -54. 0 dBc, respectively, for a 4-carrier 20 MHz WCDMA signal with 7. 1 dB peak to average power ratio (PAPR). The drain efficiency (DE) of the PA is 37. 8% at an average output power of 33. 3 dBm. The designed power amplifier can be aoolied in the WCDMA system.展开更多
In wireless sensor networks,node localization is a fundamental middleware service.In this paper,a robust and accurate localization algorithm is proposed,which uses a novel iterative clustering model to obtain the most...In wireless sensor networks,node localization is a fundamental middleware service.In this paper,a robust and accurate localization algorithm is proposed,which uses a novel iterative clustering model to obtain the most representative intersection points between every two circles and use them to estimate the position of unknown nodes.Simulation results demonstrate that the proposed algorithm outperforms other localization schemes (such as Min-Max,etc.) in accuracy,scalability and gross error tolerance.展开更多
We investigate the behavior of the vacuum polarization of the gauge-boson Ⅱ and the wave-function renormalization factor of the fermion A in QEDs, using the coupled Dyson-Schwinger equations for the gauge-boson and f...We investigate the behavior of the vacuum polarization of the gauge-boson Ⅱ and the wave-function renormalization factor of the fermion A in QEDs, using the coupled Dyson-Schwinger equations for the gauge-boson and fermion propagator. Using several different ansatze for the fermion-gauge-boson vertex, we find that the wave-function renormalization factor .4 and especially the vacuum polarization Ⅱ have different behaviors in the dynamical chiral symmetry breaking phase and in the chiral symmetric phase and hence in the phenomenological applications of QED3 one should choose different forms of gauge-boson propagator for these two phases. We also find that when adopting a specific ansatze of the fermion-gauge-boson vertex (ansatze (3)) the vacuum polarization function equals its one-loop perturbative result in the chiral symmetric phase. This fact suggests that in QEDs the Wigner vacuum corresponds to the perturbative vacuum.展开更多
TiAlN multilayer coatings composed of TiAl and TiAlN layers were deposited on ZL109 alloys using filtered cathodic vacuum arc(FCVA)technology.The effect of bias voltage on the microstructure and properties of the coat...TiAlN multilayer coatings composed of TiAl and TiAlN layers were deposited on ZL109 alloys using filtered cathodic vacuum arc(FCVA)technology.The effect of bias voltage on the microstructure and properties of the coating was systematically studied.The results show that the coating exhibits a multi-phase structure dominated by TiAlN phase.As the bias voltage increases,the orientation of TiAlN changes from(200)plane to(111)plane due to the increase of atomic mobility and lattice distortion.The hardness,elastic modulus and adhesion of the coating show the same trend of change,that is,first increase and then decrease.When the bias voltage is 75 V,the coating exhibits the highest hardness(~30.3 GPa),elastic modulus(~229.1 GPa),adhesion(HF 2)and the lowest wear rate(~4.44×10^(−5)mm^(3)/(N·m)).Compared with bare ZL109 alloy,the mechanical and tribological properties of TiAlN coated alloy surface can effectively be improved.展开更多
The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resisti...The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resistivity is always not equal to the real resistivity.To determine the real resistivity,a linear relationship of the measured resistivity,contact resistance and the real resistivity was established.Then experiments for six specimens with varying graphite contents were designed and performed to validate the formulation.Results of experiments demonstrate that the slope of the line represents contact resistance,and the intercept indicates the real resistivity.The effects of graphite content on contact resistance and real resistivity are also revealed.Finally,results show that the influence of contact resistance on accuracy of resisitvity measurement becomes more serious if graphite content is beyond 3%.Hence,it is the time to choose this novel methodology to determine the real resistivity of asphalt concrete by taking account of contact resistance.展开更多
To assess the adiabaticity of acoustic propagation in the ocean is very important for acoustic field calculation(forward problem) and tomographic retrieving (inverse problem). A new criterion of adiabaticity is propos...To assess the adiabaticity of acoustic propagation in the ocean is very important for acoustic field calculation(forward problem) and tomographic retrieving (inverse problem). A new criterion of adiabaticity is proposed recently (Shang et al., 2001). In this paper, numerical simulation has been conducted for acoustic propagation through the Polar Front to verify the new criterion. Numerical results on the f (frequency) -m (mode number) plan demonstrate that the new criterion works very well for this extremely non-gradual ocean structure.展开更多
This paper investigates the influence of Indian Ocean Dipole (IOD) on climatic variations over East Asian monsoon region, based on CAS IAP AGCM-Ⅱduring Equatorial East Pacific Ocean SSTA or not. The results show that...This paper investigates the influence of Indian Ocean Dipole (IOD) on climatic variations over East Asian monsoon region, based on CAS IAP AGCM-Ⅱduring Equatorial East Pacific Ocean SSTA or not. The results show that the southwest monsoon over East Asian will break out later than normal, the intensity of the summer monsoon over the South China Sea (SCS) is stronger than normal, and more rainfall on Chinese main land is simulated when only IOD forcing exists. With both IOD and Equatorial East Pacific Ocean SSTA forcing, the southwest monsoon will break out much later than normal, the intensity of the SCS summer monsoon also is weaker than normal, and less rainfall in North China is simulated. Therefore, Equatorial East Pacific Ocean SSTA and IOD have a synergic effect.展开更多
A method was proposed to determine boron trifluoride in boron trifluoride complex using fluoride ion selective electrode(ISE). Hydroxide was chosen to mask aluminum for the determination of 0.01—0.1 mol/L of fluoride...A method was proposed to determine boron trifluoride in boron trifluoride complex using fluoride ion selective electrode(ISE). Hydroxide was chosen to mask aluminum for the determination of 0.01—0.1 mol/L of fluoride. The simulation indicated that the permissible aluminum masked at a certain p H value was limited and hardly related to F-concentration and boric acid. It is better to control p H value below 11.5 and the aluminum concentration within 0.025 mol/L to minimize the interference of hydroxide to the fluoride ISE. The decomposition conditions of boron trifluoride by aluminum chloride were investigated. It is found that the F-detection ratio will approach 1.0 if the Al/F molar ratio is 0.3—0.7 and aluminum concentration is no more than 0.02 mol/L when heated at 80 ℃ for 10 min. In one word, hydroxide is quite fit to mask aluminum for samples which contain high content of fluoride and aluminum and the BF3 content can be successfully determined by this method.展开更多
基金Project(2011B050400007)supported by the International Cooperation Program of Guangdong Province,China
文摘Ti/TiN/Zr/ZrN multilayer coatings were deposited on Cr_17Ni_2 steel substrates with different surface roughnesses by vacuum cathodic arc deposition method. Microstructure, micro-hardness, adhesion strength and cross-sectional morphology of the obtained multilayer coatings were investigated. The results show that the Vickers hardness of Ti/TiN/Zr/ZrN multilayer coating, with a film thickness of 11.37 μm, is 29.36 GPa. The erosion and salt spray resistance performance of Cr_17Ni_2 steel substrates can be evidently improved by Ti/TiN/Zr/ZrN multilayer coating. The surface roughness of Cr_17Ni_2 steel substrates plays an important role in determining the mechanical and erosion performances of Ti/TiN/Zr/ZrN multilayer coatings. Overall, a low value of the surface roughness of substrates corresponds to an improved performance of erosion and salt spray resistance of multilayer coatings. The optimized performance of Ti/TiN/Zr/ZrN multilayer coatings can be achieved provided that the surface roughness of Cr_17Ni_2 steel substrates is lower than 0.4μm.
基金Project(2007CB613601) supported by the National Basic Research Program of ChinaProject(51142001) supported the National Natural Science Foundation of China+1 种基金Project(11B099) supported the Scientific Research Fund of the Human Provincial Education Department, ChinaProject(2011TT2038) supported the Scientific Research Fund of the Human Provincial Scientific and Technological Department, China
文摘Zn reduction was investigated by the vacuum carbothermic reduction of hemimorphite with or without CaF2 as catalyst.Results indicate that CaF2 can catalyze the carbothermic reduction of zinc silicate,decrease the reaction temperature and time.The lower the reaction temperature and the more the amount of CaF2,the better the catalytic effect.The optimal process condition is obtained as follows:the addition of about 10% CaF2,the reaction temperature of 1373 K,the molar ratio of C to ZnTotal of 2.5,the pressure of system lower than 20 kPa,the reaction time of about 40 min.Under the optimal process condition,the zinc reduction rate is about 93% from hemimorphite.
文摘The finite element method is first introduced into the design process of detecting electrodes of three electrode capacitance fuze, the mutual capacitance of the fuze and target is calculated by the finite element method, which provides the parameters for simulation circuit and design of detecting electrode. The finite element method pierces the traditional method of designing detecting electrode-design, test and adjustment. The system capacitance can be calculated accurately and the performance can be predicted in the design period of the detecting electrode, which saves a lot of research fee. The capacitances of a mortar shell fuze above ground 2 m and lower are given. After putting the computing data into simulating circuit, the demodulation voltage can be obtained, its changing trend is in agreement with the tested result.
基金Project(2010CI009) supported by Science Foundation of Yunnan Province,ChinaProjects(U1202271) supported by the National Natural Science Foundation of China
文摘The feasibility of separation of lead anode slime with low silver by vacuum distillation was analyzed theoretically. The volatilization rates and mass fractions of elements, influenced by distillation temperature, heat preservation time and material thickness, were investigated under laboratory conditions. The experimental results indicate that almost all of lead and bismuth can be separated from silver-contained multicomponent alloy at 1 223 K for 45 min when the chamber pressure maintains at 10-25 Pa. Silver can be easily enriched in the residue and its mass fraction increases from 3.6% to 27.8% when the distillation temperature is between 1 133 K and 1 373 K. Due to the forming ofintermetallic compounds Cu2Sb, Cul0Sb3 and Ag3Sb, the antimony could not be evaporated completely during the vacuum distillation. EDS analysis indicates that the condensate has a columnar crystal structure.
文摘Ti0.5Al0.25Ni0.25 alloy prepared by vacuum induction melting was studied.The phase composition was analyzed with X-ray technique and EDS analysis,and its electrochemical properties were investigated at various temperatures.Electrochemical reaction kinetic parameters were also studied with proper electrochemical techniques.The influence of the secondary corrosion reaction on the anodic linear polarization measurement was also analyzed by theoretical simulation.The results show that,proper ball-milling with nickel powders is beneficial to electrochemical performance.The theoretical simulation proves that,the existence of the side reaction can disturb the measurement of electrochemical reaction kinetic parameters.
文摘A surface photocatalysis-TPD apparatus devoted to studying kinetics and mechanism of pho- tocatalytic processes with various signal crystal surfaces has been constructed. Extremely high vacuum (-0.2 nPa) in the ionization region is obtained by using multiple ultrahigh vacuum pumps. Compared with similar instruments built previously by others~ the H2, CH4 background in the ionization region can be reduced by about two orders of magnitude, and other residual gases in the ionization region can be reduced by about an order of magnitude. Therefore, the signal-to-noise ratio for the temperature programmed desorption (TPD) and time of flight (TOF) spectra is substantially enhanced, making experimental studies of pho- tocatalytic processes on surfaces much easier. In this work, we describe the new apparatus in detail and present some preliminary studies on the photo-induced oxygen vacancy defects on TiO2(110) at 266 nm by using the TPD and TOF methods. Preliminary results suggest that the apparatus is a powerful tool for studying kinetics and mechanism of photochemical processes.
基金The National Natural Science Foundation of China(No.60702163)the National Science and Technology Major Project(No.2010ZX03007-002-01,2011ZX03004-003)
文摘A digital predistorted class-F power amplifier (PA) using Cree GaN HEMT CGH40010 operating at 2. 12 GHz is presented to obtain high efficiency and excellent linearity for wideband code-division multiple access ( WCDMA ) applications. Measurement results with the continuous wave (CW) signals indicate that the designed class-F PA achieves a peak power-added efficiency (PAE) of 75. 2% with an output power of 39.4 dBm. The adjacent channel power ratio (ACPR) of the designed PA after digital predistortion (DPD) decreases from -28. 3 and -27. 5 dBc to -51.9 and -54. 0 dBc, respectively, for a 4-carrier 20 MHz WCDMA signal with 7. 1 dB peak to average power ratio (PAPR). The drain efficiency (DE) of the PA is 37. 8% at an average output power of 33. 3 dBm. The designed power amplifier can be aoolied in the WCDMA system.
基金supported in part by the Key Program of National Natural Science Foundation of China(Grant No.60873244,60973110,61003307)the Beijing Municipal Natural Science Foundation(Grant No.4102059)
文摘In wireless sensor networks,node localization is a fundamental middleware service.In this paper,a robust and accurate localization algorithm is proposed,which uses a novel iterative clustering model to obtain the most representative intersection points between every two circles and use them to estimate the position of unknown nodes.Simulation results demonstrate that the proposed algorithm outperforms other localization schemes (such as Min-Max,etc.) in accuracy,scalability and gross error tolerance.
基金The project supported in part by National Natural Science Foundation of China under Grant Nos, 10175033 and 10135030 and the Research Fund for the Doctoral Program of Higher Education under Grant No. 20030284009
文摘We investigate the behavior of the vacuum polarization of the gauge-boson Ⅱ and the wave-function renormalization factor of the fermion A in QEDs, using the coupled Dyson-Schwinger equations for the gauge-boson and fermion propagator. Using several different ansatze for the fermion-gauge-boson vertex, we find that the wave-function renormalization factor .4 and especially the vacuum polarization Ⅱ have different behaviors in the dynamical chiral symmetry breaking phase and in the chiral symmetric phase and hence in the phenomenological applications of QED3 one should choose different forms of gauge-boson propagator for these two phases. We also find that when adopting a specific ansatze of the fermion-gauge-boson vertex (ansatze (3)) the vacuum polarization function equals its one-loop perturbative result in the chiral symmetric phase. This fact suggests that in QEDs the Wigner vacuum corresponds to the perturbative vacuum.
基金Hunan Provincial Natural Science Foundation,China(No.2021JJ30646)Educational Commission of Hunan Province,China(No.20B579)+1 种基金the National Natural Science Foundation of China(Nos.51701172,12027813)Innovation Team of Hunan Province,China(No.2018RS3091).
文摘TiAlN multilayer coatings composed of TiAl and TiAlN layers were deposited on ZL109 alloys using filtered cathodic vacuum arc(FCVA)technology.The effect of bias voltage on the microstructure and properties of the coating was systematically studied.The results show that the coating exhibits a multi-phase structure dominated by TiAlN phase.As the bias voltage increases,the orientation of TiAlN changes from(200)plane to(111)plane due to the increase of atomic mobility and lattice distortion.The hardness,elastic modulus and adhesion of the coating show the same trend of change,that is,first increase and then decrease.When the bias voltage is 75 V,the coating exhibits the highest hardness(~30.3 GPa),elastic modulus(~229.1 GPa),adhesion(HF 2)and the lowest wear rate(~4.44×10^(−5)mm^(3)/(N·m)).Compared with bare ZL109 alloy,the mechanical and tribological properties of TiAlN coated alloy surface can effectively be improved.
基金Project(51178348)supported by the National Natural Science Foundation of China
文摘The objective of this work is to develop a novel methodology for determining real resistivity of conductive asphalt concrete based on two-electrode method.Due to an influence of contact resistance,the measured resistivity is always not equal to the real resistivity.To determine the real resistivity,a linear relationship of the measured resistivity,contact resistance and the real resistivity was established.Then experiments for six specimens with varying graphite contents were designed and performed to validate the formulation.Results of experiments demonstrate that the slope of the line represents contact resistance,and the intercept indicates the real resistivity.The effects of graphite content on contact resistance and real resistivity are also revealed.Finally,results show that the influence of contact resistance on accuracy of resisitvity measurement becomes more serious if graphite content is beyond 3%.Hence,it is the time to choose this novel methodology to determine the real resistivity of asphalt concrete by taking account of contact resistance.
文摘To assess the adiabaticity of acoustic propagation in the ocean is very important for acoustic field calculation(forward problem) and tomographic retrieving (inverse problem). A new criterion of adiabaticity is proposed recently (Shang et al., 2001). In this paper, numerical simulation has been conducted for acoustic propagation through the Polar Front to verify the new criterion. Numerical results on the f (frequency) -m (mode number) plan demonstrate that the new criterion works very well for this extremely non-gradual ocean structure.
基金National key fundamental research development program "Research of formation mechanism and forecast theory about fatal climatic calamity of China" (G1998040900).
文摘This paper investigates the influence of Indian Ocean Dipole (IOD) on climatic variations over East Asian monsoon region, based on CAS IAP AGCM-Ⅱduring Equatorial East Pacific Ocean SSTA or not. The results show that the southwest monsoon over East Asian will break out later than normal, the intensity of the summer monsoon over the South China Sea (SCS) is stronger than normal, and more rainfall on Chinese main land is simulated when only IOD forcing exists. With both IOD and Equatorial East Pacific Ocean SSTA forcing, the southwest monsoon will break out much later than normal, the intensity of the SCS summer monsoon also is weaker than normal, and less rainfall in North China is simulated. Therefore, Equatorial East Pacific Ocean SSTA and IOD have a synergic effect.
基金Supported by the Independent Innovation Fund of Tianjin University(No.1307)
文摘A method was proposed to determine boron trifluoride in boron trifluoride complex using fluoride ion selective electrode(ISE). Hydroxide was chosen to mask aluminum for the determination of 0.01—0.1 mol/L of fluoride. The simulation indicated that the permissible aluminum masked at a certain p H value was limited and hardly related to F-concentration and boric acid. It is better to control p H value below 11.5 and the aluminum concentration within 0.025 mol/L to minimize the interference of hydroxide to the fluoride ISE. The decomposition conditions of boron trifluoride by aluminum chloride were investigated. It is found that the F-detection ratio will approach 1.0 if the Al/F molar ratio is 0.3—0.7 and aluminum concentration is no more than 0.02 mol/L when heated at 80 ℃ for 10 min. In one word, hydroxide is quite fit to mask aluminum for samples which contain high content of fluoride and aluminum and the BF3 content can be successfully determined by this method.