Mg-Gd-Y-Zr alloys were purified by filtering purification with and without vacuum. The type, morphology, size distribution and volume fraction of inclusion were analyzed with OM and SEM. The effect of inclusion in Mg-...Mg-Gd-Y-Zr alloys were purified by filtering purification with and without vacuum. The type, morphology, size distribution and volume fraction of inclusion were analyzed with OM and SEM. The effect of inclusion in Mg-Gd-Y-Zr alloys on anticorrosion ability was investigated with salt spray test and electrochemical test. The results show that the inclusions in the alloy can be removed effectively by filtering purification. The average size of inclusions in the alloys is decreased from 12.7 μm to 2.0 μm and the volume fraction of inclusions is reduced from 0.30% to 0.04%. With the decrease of the size of inclusions in the alloys, the corrosion rate of the alloys decreases dramatically from 38.8 g/(m 2 ·d) to 2.4 g/(m 2 ·d) in the salt spray test. The corrosion potential increases while the corrosion current decreases and the polarization resistance increases in the electrochemical tests, which indicates that the anticorrosion ability is improved.展开更多
Significant progress has been made in the development of non-precious metal electrocatalysts (NPMEs) during the past decade. Correspondingly, there is an urgent demand for an appropriate measurement method to be est...Significant progress has been made in the development of non-precious metal electrocatalysts (NPMEs) during the past decade. Correspondingly, there is an urgent demand for an appropriate measurement method to be established for the reliable evaluation of NPMEs. In this study, platinum and graphite counter electrodes were used to investigate the impact of counter electrode material on the accelerated durability testing (ADT) of NPMEs in acidic medium. Platinum used as the coun- ter electrode in a traditional three-electrode electrochemical cell was found to dissolve in acidic medium and re-deposit on NPME coated on the working electrode during ADT. Such re-deposition causes the oxygen reduction reaction (ORR) performance of NPMEs to remarkably improve, and thus will seriously mislead our judgment of NPMEs if we are unaware of it. The phenomenon can be avoided using a graphite counter electrode.展开更多
The influence of thermal treatment on Si 1-x Ge x/Si multiple-quantum wells (MQW) p-i-n photodiodes has been investigated by photocurrent spectroscopy combined with X-ray double crystal dif...The influence of thermal treatment on Si 1-x Ge x/Si multiple-quantum wells (MQW) p-i-n photodiodes has been investigated by photocurrent spectroscopy combined with X-ray double crystal diffraction.The cutoff wavelength is significantly reduced due to the Si-Ge interdiffusion and partial relaxation of the strained SiGe alloy.The values of the blue shift increase slowly with the annealing temperatures in the range of 750℃ to 850℃.However,the nonlinear changes in photocurrent intensities of the samples annealed at different temperatures have been observed,which is mainly dominated by the generation of misfit dislocations and the reduction of the point defects in the heating process.展开更多
PS converted-waves (C-waves) have been commonly used to image through gas clouds but the C-wave imaging may also be degraded by the diodic effect introduced by the gas cloud. It may be compensated for using a veloci...PS converted-waves (C-waves) have been commonly used to image through gas clouds but the C-wave imaging may also be degraded by the diodic effect introduced by the gas cloud. It may be compensated for using a velocity perturbation method which decouples the diodic moveout into two parts: the base velocity and the velocity perturbation. Gas clouds are widely distributed in the Sanhu area in the Qaidam basin of northwest China which is rich in natural gas. A land 2D3C seismic dataset is analyzed from the Sanhu area and significant diodic effects are observed in the data which harm the C-wave imaging. The diodic correction is applied to this data and the resultant C-wave imaging and the details of the reservoir structure are significantly improved. The diodic moveout plays an important role in working out the residu~ shear wave statics and the association of diodie correction and shear wave residual statics computation is a key step of C-wave high fidelity imaging in the gas cloud area. Finally, the new process workflow with diodic moveout is given.展开更多
Chemically resistant anodic oxide layers were formed on pure aluminum substrates in oxalic acid-sulphuric acid bath.Acid dissolution tests of the obtained anodic layers were achieved in accordance with the ASTM B 680-...Chemically resistant anodic oxide layers were formed on pure aluminum substrates in oxalic acid-sulphuric acid bath.Acid dissolution tests of the obtained anodic layers were achieved in accordance with the ASTM B 680-80 specifications:35mL/L 85% H3PO4+20g/L CrO3 at 38℃.Influence of oxalic acid concentration,bath temperature and anodic current density on dissolution rate and coating ratio was examined,when the sulphuric acid concentration was maintained at 160g/L.It was found that chemically resistant and compact oxide layers were produced under low operational temperature (5℃) and high current densities (3A/dm^2).A beneficial effect was observed concerning the addition of oxalic acid (18g/L).The morphology and the composition of the anodic oxide layer were examined by scanning electron microscopy (SEM),atomic force microscopy (AFM) and glow-discharge optical emission spectroscopy (GDOES).展开更多
Elastic wave propagation and attenuation in porous rock layers with oriented sets of fractures, especially in carbonate reservoirs, are anisotropic owing to fracture sealing, fracture size, fracture density, filling f...Elastic wave propagation and attenuation in porous rock layers with oriented sets of fractures, especially in carbonate reservoirs, are anisotropic owing to fracture sealing, fracture size, fracture density, filling fluid, and fracture strike orientation. To address this problem, we adopt the Chapman effective medium model and carry out numerical experiments to assess the variation in P-wave velocity and attenuation, and the shear-wave splitting anisotropy with the frequency and azimuth of the incident wave. The results suggest that velocity, attenuation, and anisotropy vary as function of azimuth and frequency. The azimuths of the minimum attenuation and maximum P-wave velocity are nearly coincident with the average strike of the two sets of open fractures. P-wave velocity is greater in sealed fractures than open fractures, whereas the attenuation of energy and anisotropy is stronger in open fractures than sealed fractures. For fractures of different sizes, the maximum velocity together with the minimum attenuation correspond to the average orientation of the fracture sets. Small fractures affect the wave propagation less. Azimuth-dependent anisotropy is low and varies more than the other attributes. Fracture density strongly affects the P-wave velocity, attenuation, and shear-wave anisotropy. The attenuation is more sensitive to the variation of fracture size than that of velocity and anisotropy. In the seismic frequency band, the effect of oil and gas saturation on attenuation is very different from that for brine saturation and varies weakly over azimuth. It is demonstrated that for two sets of fractures with the same density, the fast shear-wave polarization angle is almost linearly related with the orientation of one of the fracture sets.展开更多
The spatial and temporal variations of some important near-surface climate parameters and extreme climate events in North China during 1961-2010 are analyzed by using 94 meteorological stations' data in the study are...The spatial and temporal variations of some important near-surface climate parameters and extreme climate events in North China during 1961-2010 are analyzed by using 94 meteorological stations' data in the study area. Results show that the annual mean surface air temperature in North China increased at the rate of 0.36℃ per decade, higher than the national average in the same period. Increasing was particularly significant since the mid-1980s, with maximum increase in the middle and northeastern parts of Inner Mongolia. Increasing rate of the annual mean minimum temperature is much higher than that of the maximum temperature, which results in the decrease of the annual mean diurnal temperature range. Noticeable decrease is also observed in the frequency of cold wave. Annual precipitation shows a slight decreasing trend, with more pronounced decrease in southern Shanxi and eastern Hebei provinces, which is mainly represented as decreasing in contribution rates of rainstorm and heavy storm in flood-season (May to September). During 1961 -2010, North China is characterized by a noticeable reduction in annual extreme precipitation, and an increase in high-temperature days over most parts, as well as more frequent droughts. There are remarkable reductions in annual sunshine duration and mean wind speed, associated with the most significant reduction of mean wind speed in midwestern and eastern parts of Inner Mongolia. Meanwhile, North China has experienced a noticeable decrease/increase in annual mean sanddust/haze days during the study period. However, there is no significant trend in fog days, except a pronounced decrease since the 1990s.展开更多
The problem of joint direction of arrival(DOA)and polarization estimation for polarization sensitive coprime planar arrays(PS-CPAs)is investigated,and a fast-convergence quadrilinear decomposition approach is proposed...The problem of joint direction of arrival(DOA)and polarization estimation for polarization sensitive coprime planar arrays(PS-CPAs)is investigated,and a fast-convergence quadrilinear decomposition approach is proposed.Specifically,we first decompose the PS-CPA into two sparse polarization sensitive uniform planar subarrays and employ propagator method(PM)to construct the initial steering matrices separately.Then we arrange the received signals into two quadrilinear models so that the potential DOA and polarization estimates can be attained via quadrilinear alternating least square(QALS).Subsequently,we distinguish the true DOA estimates from the approximate intersecting estimations of the two subarrays in view of the coprime feature.Finally,the polarization estimates paired with DOA can be obtained.In contrast to the conventional QALS algorithm,the proposed approach can remarkably reduce the computational complexity without degrading the estimation performance.Simulations demonstrate the superiority of the proposed fast-convergence approach for PS-CPAs.展开更多
Monolithic integration of resonant tunneling diodes (RTDs) and high electron mobility transistors (HEMTs) is an important development direction of ultra-high speed integrated circuit. A kind of top-RTD and bottom-HEMT...Monolithic integration of resonant tunneling diodes (RTDs) and high electron mobility transistors (HEMTs) is an important development direction of ultra-high speed integrated circuit. A kind of top-RTD and bottom-HEMT material structure is epitaxied on InP substrate through molecular beam epitaxy. Based on wet chemical etching, metal lift-off and air bridge interconnection technology, RTD and HEMT are fabricated simultaneously. The peak-to-valley current ratio of RTD is 7.7 and the peak voltage is 0.33 V at room temperature. The pinch-off voltage is -0.5 V and the current gain cut-frequency is 30 GHz for a 1.0 μm gate length depletion mode HEMT. The two devices are conformable in current magnitude, which is suitable for the construction of various RTD/HEMT monolithic integration logic circuits.展开更多
Broadband three-component seismic data recorded by Beijingstation (BJI) of CDSN were used to calculate P-wave polarization of teleseismic events. These polarization data were then used in the inversion for the undergr...Broadband three-component seismic data recorded by Beijingstation (BJI) of CDSN were used to calculate P-wave polarization of teleseismic events. These polarization data were then used in the inversion for the underground structure around the Beijing station, especially for the details of velocity discontinuities. The result shows that a conspicuous low velocity zone exists in the crust on the west of the station, which is in good agreement with previous studies. It proves the theory that polarization data could be applied to inversion for velocity structures, especially for boundaries with large velocity gradient. It also demonstrates the feasibility of velocity structure inversion with polarization data from high-quality broadband data recorded by a single station. Therefore, travel-times and polarization data can be jointly used to study velocity structure. Polarization data are more suitable for delineating the boundary of velocity anomalies. Moreover, if the polarization method is combined with receiver function method to fully exploit their complementarity, it is possible to obtain the lateral velocity variation around the station as well as the detailed vertical variation below the station.展开更多
The catalytic effect of electrode materials is one of the most crucial factors for achieving efficient electrochemical energy conversion and storage.Carbon-based metal composites were widely synthesized and employed a...The catalytic effect of electrode materials is one of the most crucial factors for achieving efficient electrochemical energy conversion and storage.Carbon-based metal composites were widely synthesized and employed as electrode materials because of their inherited outstanding properties.Usually,electrode materials can provide a higher capacity than the anticipated values,even beyond the theoretical limit.The origin of the extra capacity has not yet been explained accurately,and its formation mechanism is still ambiguous.Herein,we first summarized the current research progress and drawbacks in energy storage devices(ESDs),and elaborated the role of catalytic effect in enhancing the performance of ESDs as follows:promoting the evolution of the solid electrolyte interphase(SEI),accelerating the reversible conversion of discharge/charge products,and improving the conversion speed of the intermediate and the utilization rate of the active materials,thereby avoiding the shuttling effect.Additionally,a particular focus was placed on the interaction between the catalytic effect and energy storage performance in order to highlight the efficacy and role of the catalytic effect.We hope that this review could provide innovative ideas for designing the electrode materials with an efficient catalytic effect for ESDs to promote the development of this research field.展开更多
基金Project(2007CB613700)supported by the National Basic Research Program of China
文摘Mg-Gd-Y-Zr alloys were purified by filtering purification with and without vacuum. The type, morphology, size distribution and volume fraction of inclusion were analyzed with OM and SEM. The effect of inclusion in Mg-Gd-Y-Zr alloys on anticorrosion ability was investigated with salt spray test and electrochemical test. The results show that the inclusions in the alloy can be removed effectively by filtering purification. The average size of inclusions in the alloys is decreased from 12.7 μm to 2.0 μm and the volume fraction of inclusions is reduced from 0.30% to 0.04%. With the decrease of the size of inclusions in the alloys, the corrosion rate of the alloys decreases dramatically from 38.8 g/(m 2 ·d) to 2.4 g/(m 2 ·d) in the salt spray test. The corrosion potential increases while the corrosion current decreases and the polarization resistance increases in the electrochemical tests, which indicates that the anticorrosion ability is improved.
基金supported by the Fundamental Research Funds for the Central Universities(DUT15RC(3)001,DUT15ZD225)the Program for Liao-ning Excellent Talents in University(LR2015014)+1 种基金the Liaoning BaiQianWan Talents Program(201519)Dalian Excellent Young Scientific and Technological Talents(2015R006)
文摘Significant progress has been made in the development of non-precious metal electrocatalysts (NPMEs) during the past decade. Correspondingly, there is an urgent demand for an appropriate measurement method to be established for the reliable evaluation of NPMEs. In this study, platinum and graphite counter electrodes were used to investigate the impact of counter electrode material on the accelerated durability testing (ADT) of NPMEs in acidic medium. Platinum used as the coun- ter electrode in a traditional three-electrode electrochemical cell was found to dissolve in acidic medium and re-deposit on NPME coated on the working electrode during ADT. Such re-deposition causes the oxygen reduction reaction (ORR) performance of NPMEs to remarkably improve, and thus will seriously mislead our judgment of NPMEs if we are unaware of it. The phenomenon can be avoided using a graphite counter electrode.
文摘The influence of thermal treatment on Si 1-x Ge x/Si multiple-quantum wells (MQW) p-i-n photodiodes has been investigated by photocurrent spectroscopy combined with X-ray double crystal diffraction.The cutoff wavelength is significantly reduced due to the Si-Ge interdiffusion and partial relaxation of the strained SiGe alloy.The values of the blue shift increase slowly with the annealing temperatures in the range of 750℃ to 850℃.However,the nonlinear changes in photocurrent intensities of the samples annealed at different temperatures have been observed,which is mainly dominated by the generation of misfit dislocations and the reduction of the point defects in the heating process.
基金supported by the National Natural Science Foundation of China (No. 41074080)the Important National Science & Technology Specific Projects (No. 2011ZX05019-008)
文摘PS converted-waves (C-waves) have been commonly used to image through gas clouds but the C-wave imaging may also be degraded by the diodic effect introduced by the gas cloud. It may be compensated for using a velocity perturbation method which decouples the diodic moveout into two parts: the base velocity and the velocity perturbation. Gas clouds are widely distributed in the Sanhu area in the Qaidam basin of northwest China which is rich in natural gas. A land 2D3C seismic dataset is analyzed from the Sanhu area and significant diodic effects are observed in the data which harm the C-wave imaging. The diodic correction is applied to this data and the resultant C-wave imaging and the details of the reservoir structure are significantly improved. The diodic moveout plays an important role in working out the residu~ shear wave statics and the association of diodie correction and shear wave residual statics computation is a key step of C-wave high fidelity imaging in the gas cloud area. Finally, the new process workflow with diodic moveout is given.
文摘Chemically resistant anodic oxide layers were formed on pure aluminum substrates in oxalic acid-sulphuric acid bath.Acid dissolution tests of the obtained anodic layers were achieved in accordance with the ASTM B 680-80 specifications:35mL/L 85% H3PO4+20g/L CrO3 at 38℃.Influence of oxalic acid concentration,bath temperature and anodic current density on dissolution rate and coating ratio was examined,when the sulphuric acid concentration was maintained at 160g/L.It was found that chemically resistant and compact oxide layers were produced under low operational temperature (5℃) and high current densities (3A/dm^2).A beneficial effect was observed concerning the addition of oxalic acid (18g/L).The morphology and the composition of the anodic oxide layer were examined by scanning electron microscopy (SEM),atomic force microscopy (AFM) and glow-discharge optical emission spectroscopy (GDOES).
基金This study was supported by the National Natural Science Foundation of China Rsearch (Nos. 41674046, 41440030, and 41574078) and the Fundamental Research Funds for the Central Universities of Lanzhou university (No. lzujbky-2015-175).
文摘Elastic wave propagation and attenuation in porous rock layers with oriented sets of fractures, especially in carbonate reservoirs, are anisotropic owing to fracture sealing, fracture size, fracture density, filling fluid, and fracture strike orientation. To address this problem, we adopt the Chapman effective medium model and carry out numerical experiments to assess the variation in P-wave velocity and attenuation, and the shear-wave splitting anisotropy with the frequency and azimuth of the incident wave. The results suggest that velocity, attenuation, and anisotropy vary as function of azimuth and frequency. The azimuths of the minimum attenuation and maximum P-wave velocity are nearly coincident with the average strike of the two sets of open fractures. P-wave velocity is greater in sealed fractures than open fractures, whereas the attenuation of energy and anisotropy is stronger in open fractures than sealed fractures. For fractures of different sizes, the maximum velocity together with the minimum attenuation correspond to the average orientation of the fracture sets. Small fractures affect the wave propagation less. Azimuth-dependent anisotropy is low and varies more than the other attributes. Fracture density strongly affects the P-wave velocity, attenuation, and shear-wave anisotropy. The attenuation is more sensitive to the variation of fracture size than that of velocity and anisotropy. In the seismic frequency band, the effect of oil and gas saturation on attenuation is very different from that for brine saturation and varies weakly over azimuth. It is demonstrated that for two sets of fractures with the same density, the fast shear-wave polarization angle is almost linearly related with the orientation of one of the fracture sets.
基金supported by the Climate Change Special Foundation of China Meteorological Administration(No. CCSF2010-1)
文摘The spatial and temporal variations of some important near-surface climate parameters and extreme climate events in North China during 1961-2010 are analyzed by using 94 meteorological stations' data in the study area. Results show that the annual mean surface air temperature in North China increased at the rate of 0.36℃ per decade, higher than the national average in the same period. Increasing was particularly significant since the mid-1980s, with maximum increase in the middle and northeastern parts of Inner Mongolia. Increasing rate of the annual mean minimum temperature is much higher than that of the maximum temperature, which results in the decrease of the annual mean diurnal temperature range. Noticeable decrease is also observed in the frequency of cold wave. Annual precipitation shows a slight decreasing trend, with more pronounced decrease in southern Shanxi and eastern Hebei provinces, which is mainly represented as decreasing in contribution rates of rainstorm and heavy storm in flood-season (May to September). During 1961 -2010, North China is characterized by a noticeable reduction in annual extreme precipitation, and an increase in high-temperature days over most parts, as well as more frequent droughts. There are remarkable reductions in annual sunshine duration and mean wind speed, associated with the most significant reduction of mean wind speed in midwestern and eastern parts of Inner Mongolia. Meanwhile, North China has experienced a noticeable decrease/increase in annual mean sanddust/haze days during the study period. However, there is no significant trend in fog days, except a pronounced decrease since the 1990s.
基金supported by the Open Research Fund of the State Key Laboratory of Complex Electromagnetic Environment Effects on Electronics and Information System(No.CEMEE2019Z0104B)。
文摘The problem of joint direction of arrival(DOA)and polarization estimation for polarization sensitive coprime planar arrays(PS-CPAs)is investigated,and a fast-convergence quadrilinear decomposition approach is proposed.Specifically,we first decompose the PS-CPA into two sparse polarization sensitive uniform planar subarrays and employ propagator method(PM)to construct the initial steering matrices separately.Then we arrange the received signals into two quadrilinear models so that the potential DOA and polarization estimates can be attained via quadrilinear alternating least square(QALS).Subsequently,we distinguish the true DOA estimates from the approximate intersecting estimations of the two subarrays in view of the coprime feature.Finally,the polarization estimates paired with DOA can be obtained.In contrast to the conventional QALS algorithm,the proposed approach can remarkably reduce the computational complexity without degrading the estimation performance.Simulations demonstrate the superiority of the proposed fast-convergence approach for PS-CPAs.
基金Supported by National Natural Science Foundation of China (No. 60876009)Tianjin Research Program of Application Foundation and Advanced Technology (No. 09JCZDJC16600)
文摘Monolithic integration of resonant tunneling diodes (RTDs) and high electron mobility transistors (HEMTs) is an important development direction of ultra-high speed integrated circuit. A kind of top-RTD and bottom-HEMT material structure is epitaxied on InP substrate through molecular beam epitaxy. Based on wet chemical etching, metal lift-off and air bridge interconnection technology, RTD and HEMT are fabricated simultaneously. The peak-to-valley current ratio of RTD is 7.7 and the peak voltage is 0.33 V at room temperature. The pinch-off voltage is -0.5 V and the current gain cut-frequency is 30 GHz for a 1.0 μm gate length depletion mode HEMT. The two devices are conformable in current magnitude, which is suitable for the construction of various RTD/HEMT monolithic integration logic circuits.
基金The data are provided by CDSN of China Seismological Bureau, Mr. Zhang Decun and other colleagues in the Institute of Geophysics of CSB gave great help The discussion with colleagues in the research group was greatly beneficial The authors are deeply
文摘Broadband three-component seismic data recorded by Beijingstation (BJI) of CDSN were used to calculate P-wave polarization of teleseismic events. These polarization data were then used in the inversion for the underground structure around the Beijing station, especially for the details of velocity discontinuities. The result shows that a conspicuous low velocity zone exists in the crust on the west of the station, which is in good agreement with previous studies. It proves the theory that polarization data could be applied to inversion for velocity structures, especially for boundaries with large velocity gradient. It also demonstrates the feasibility of velocity structure inversion with polarization data from high-quality broadband data recorded by a single station. Therefore, travel-times and polarization data can be jointly used to study velocity structure. Polarization data are more suitable for delineating the boundary of velocity anomalies. Moreover, if the polarization method is combined with receiver function method to fully exploit their complementarity, it is possible to obtain the lateral velocity variation around the station as well as the detailed vertical variation below the station.
基金the National Natural Science Foundation of China(21875221,21890753,22162026,22225204,and U1967215)the National Key Research and Development Program of China(2016YFB0101202)+2 种基金the Youth Talent Support Program of High-Level Talents Special Support Plan in Henan Province(ZYQR201810148)Qiushi Scientific Research Initiation Plan of Zhengzhou University(32213243)the Distinguished Young Scholars Innovation Team of Zhengzhou University(32320275).
文摘The catalytic effect of electrode materials is one of the most crucial factors for achieving efficient electrochemical energy conversion and storage.Carbon-based metal composites were widely synthesized and employed as electrode materials because of their inherited outstanding properties.Usually,electrode materials can provide a higher capacity than the anticipated values,even beyond the theoretical limit.The origin of the extra capacity has not yet been explained accurately,and its formation mechanism is still ambiguous.Herein,we first summarized the current research progress and drawbacks in energy storage devices(ESDs),and elaborated the role of catalytic effect in enhancing the performance of ESDs as follows:promoting the evolution of the solid electrolyte interphase(SEI),accelerating the reversible conversion of discharge/charge products,and improving the conversion speed of the intermediate and the utilization rate of the active materials,thereby avoiding the shuttling effect.Additionally,a particular focus was placed on the interaction between the catalytic effect and energy storage performance in order to highlight the efficacy and role of the catalytic effect.We hope that this review could provide innovative ideas for designing the electrode materials with an efficient catalytic effect for ESDs to promote the development of this research field.