Isothermal compression experiments were conducted to study the hot deformation behaviors of a Sr-modified Al-Si-Mg alloy in the temperature range of 300-420°C and strain rate range of 0.01-10 s-1.A physically-bas...Isothermal compression experiments were conducted to study the hot deformation behaviors of a Sr-modified Al-Si-Mg alloy in the temperature range of 300-420°C and strain rate range of 0.01-10 s-1.A physically-based model was developed to accurately predict the flow stress.Meanwhile,processing maps were established to optimize hot working parameters.It is found that decreasing the strain rate or increasing the deformation temperature reduces the flow stress.The high activation energy is closely related to the pinning of dislocations from Si-containing dispersoids.Moreover,the deformed grains and the Si-containing dispersoids in the matrix are elongated perpendicular to the compression direction,and incomplete dynamic recrystallization(DRX)is discovered on the elongated boundaries in domain with peak efficiency.The flow instability is mainly attributed to the flow localization,brittle fracture of eutectic Si phase,and formation of adiabatic shear band.The optimum hot working window is 380-420°C and 0.03-0.28 s-1.展开更多
The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact an...The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact angle hysteresis,and roll-off angle of water droplets on both of these superhydrophobic surfaces with a high speed contact angle meter.The dynamic contact angles and internal velocity distribution of water droplets on superhydrophobic surfaces were studied with a high-speed camera system and a particle image velocimetry (PIV) system,respectively.We found that the acceleration of water droplets when they slide off lotus leaves is greater than that of water droplets sliding off the silicon wafers with microscale pillar structures although the static contact angles of water droplets on lotus leaves are slightly smaller than those on the silicon wafers.The reason is that water droplets sliding off lotus leaves have smaller contact angle hysteresis and larger slip velocities.These results indicate that the dynamic contact angle hysteresis and sliding acceleration of liquid droplets are more suitable for reflecting the hydrophobicity of material surfaces compared with static contact angles.Our experiments also show that lotus leaves with multiscale micro/nanostructures have stronger hydrophobicity and self-cleaning properties compared with the micro-structured superhydrophobic surfaces.展开更多
We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substr...We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substrate is patterned with a rectangular array of nanoscale holes. Because of the high quality of the pattern, using neutron reflectometry, we are able to map the surface-normal density distribution of the patterned silicon, the penetration of water into the pattern, and the distribution of a deposited film inside and outside of the etched holes. In this stud; 1,2-dilauroyl-sn-glycero-3-phosphocholine （DLPC） single bilayers were deposited on the hydrophilic patterned surface. For bilayers deposited either by vesicle fusion （VF） or by the Langmuir-Schaefer （L-S） technique, the most consistent model found to fit the data shows that the lipids form bilayer coatings on top of the substrate as well as the bottoms of the holes in an essentially conformal fashion. However, while there is a single bilayer on the unetched silicon surface, the lipids coating the bottoms of the holes form a complex bimodal structure consistent with a rough surface produced by the etching process. This study provides insight into film transfer both outside and inside regular nanopatterned features.展开更多
基金Project(51375502)supported by the National Natural Science Foundation of ChinaProject(2015CX002)supported by the Innovation-driven Plan in Central South University,China+2 种基金Project(2016RS2006)supported by the Science and Technology Leading Talent in Hunan Province,ChinaProject(Q2015140)supported by the Program of Chang Jiang Scholars of Ministry of Education,ChinaProject(2016JJ1017)supported by the Natural Science Foundation for Distinguished Young Scholars of Hunan Province,China
文摘Isothermal compression experiments were conducted to study the hot deformation behaviors of a Sr-modified Al-Si-Mg alloy in the temperature range of 300-420°C and strain rate range of 0.01-10 s-1.A physically-based model was developed to accurately predict the flow stress.Meanwhile,processing maps were established to optimize hot working parameters.It is found that decreasing the strain rate or increasing the deformation temperature reduces the flow stress.The high activation energy is closely related to the pinning of dislocations from Si-containing dispersoids.Moreover,the deformed grains and the Si-containing dispersoids in the matrix are elongated perpendicular to the compression direction,and incomplete dynamic recrystallization(DRX)is discovered on the elongated boundaries in domain with peak efficiency.The flow instability is mainly attributed to the flow localization,brittle fracture of eutectic Si phase,and formation of adiabatic shear band.The optimum hot working window is 380-420°C and 0.03-0.28 s-1.
基金supported by the National Natural Science Foundation of China(Grant Nos. 11072126 and 10872106)
文摘The dynamic wetting characteristics of water droplets on silicon wafers with microscale regular pillars structures and fresh lotus leaves are investigated experimentally.We measured the static contact angle,contact angle hysteresis,and roll-off angle of water droplets on both of these superhydrophobic surfaces with a high speed contact angle meter.The dynamic contact angles and internal velocity distribution of water droplets on superhydrophobic surfaces were studied with a high-speed camera system and a particle image velocimetry (PIV) system,respectively.We found that the acceleration of water droplets when they slide off lotus leaves is greater than that of water droplets sliding off the silicon wafers with microscale pillar structures although the static contact angles of water droplets on lotus leaves are slightly smaller than those on the silicon wafers.The reason is that water droplets sliding off lotus leaves have smaller contact angle hysteresis and larger slip velocities.These results indicate that the dynamic contact angle hysteresis and sliding acceleration of liquid droplets are more suitable for reflecting the hydrophobicity of material surfaces compared with static contact angles.Our experiments also show that lotus leaves with multiscale micro/nanostructures have stronger hydrophobicity and self-cleaning properties compared with the micro-structured superhydrophobic surfaces.
文摘We present measurements of the in situ, microscopic architecture of a self- assembled bilayer at the interface between a regularly nanopatterned surface and an aqueous sub-phase using neutron reflectometry. The substrate is patterned with a rectangular array of nanoscale holes. Because of the high quality of the pattern, using neutron reflectometry, we are able to map the surface-normal density distribution of the patterned silicon, the penetration of water into the pattern, and the distribution of a deposited film inside and outside of the etched holes. In this stud; 1,2-dilauroyl-sn-glycero-3-phosphocholine （DLPC） single bilayers were deposited on the hydrophilic patterned surface. For bilayers deposited either by vesicle fusion （VF） or by the Langmuir-Schaefer （L-S） technique, the most consistent model found to fit the data shows that the lipids form bilayer coatings on top of the substrate as well as the bottoms of the holes in an essentially conformal fashion. However, while there is a single bilayer on the unetched silicon surface, the lipids coating the bottoms of the holes form a complex bimodal structure consistent with a rough surface produced by the etching process. This study provides insight into film transfer both outside and inside regular nanopatterned features.
