By the constant stress tensile creep test method, creep tests were performed on aluminum silicate short fiber-reinforced AZ91D magnesium matrix composite with volume fraction of 30% and its matrix alloy AZ91D under di...By the constant stress tensile creep test method, creep tests were performed on aluminum silicate short fiber-reinforced AZ91D magnesium matrix composite with volume fraction of 30% and its matrix alloy AZ91D under different temperatures and stresses. The results indicate that the composite and the matrix have the same true stress exponent and true activation energy for creep, which are 3 and 144.63 kJ/mol, respectively. The creep of the composite is controlled by the creep of its matrix, which is mainly the controlling of viscous slip of dislocation, and the controlling of grain boundary slippage as a supplement. The creep constitutive model obtained from the experiment data can well describe the creep deformation pattern of the composite.展开更多
The effect of realistic topology configuration of intercellular connections on the response ability in coupled cell system is numerically investigated by using the Hindmarsh-Rose model. For the proper coupling intensi...The effect of realistic topology configuration of intercellular connections on the response ability in coupled cell system is numerically investigated by using the Hindmarsh-Rose model. For the proper coupling intensity, we set the control parameter to be near the critical value, and the external stimulus is introduced to the first cell in coupled system. It is found that, on one hand, when the cells are coupled with some proper topological structures, the external stimulus could transmit through the system, and shows better response ability and higher sensitivity. On the other hand, the influence of topological configuration on the synchronous ability and selection effect of neural system are also discussed. Our results display that the topology of coupled system may play an important role in the process of signal propagation, which could help us to understand the coordinated performance of cells in tissue.展开更多
A multi-parameter nonlinear elasto-plastic constitutive model which can fully capture the three typical features of stress-strain response, linearity, plasticity-like stress plateau and densification phases was develo...A multi-parameter nonlinear elasto-plastic constitutive model which can fully capture the three typical features of stress-strain response, linearity, plasticity-like stress plateau and densification phases was developed. The functional expression of each parameter was determined using uniaxial compression tests for aluminum alloy foams. The parameters of the model can be systematically varied to describe the effect of relative density which may be responsible for the changes in yield stress and hardening-like or softening-like behavior at various strain rates. A comparison between model predictions and experimental results of the aluminum alloy foams was provided to validate the model. It was proved to be useful in the selection of the optimal-density and energy absorption foam for a specific application at impact events.展开更多
Effects of four factors on thin sheet metal flow stress were considered, including grain size d, thickness t, grain number across thickness (t/d ratio) and surface property. Surface model was adopted to quantitative...Effects of four factors on thin sheet metal flow stress were considered, including grain size d, thickness t, grain number across thickness (t/d ratio) and surface property. Surface model was adopted to quantitatively describe the effect of t/d ratio on flow stress for pure copper. It is predicted that when t/d ratio is larger than a critical value, effect of t/d ratio on flow stress can be neglected. Existence of critical t/d ratio changes the Hall-Petch relationship and evolution of flow stress with thickness. A criterion was proposed to determine critical t/d ratio. Then a comprehensive constitutive model was developed to consider all the four factors, with parameters determined by fitting experimental data of high purity Ni. The predicted results show the same tendencies with experiment results. Particularly when t/d ratio decreases, Hall-Petch relationship and evolution of true stress show varied slopes with two transition points.展开更多
Systematic search of the potential energy surface of tetrapeptide glycine-phenylalanine- glycine-glycine (GFGG) in gas phase is conducted by a combination of PM3, HF and BHandHLYP methods. The conformational search ...Systematic search of the potential energy surface of tetrapeptide glycine-phenylalanine- glycine-glycine (GFGG) in gas phase is conducted by a combination of PM3, HF and BHandHLYP methods. The conformational search method is described in detail. The relative electronic energies, zero point vibrational energies, dipole moments, rotational constants, vertical ionization energies and the temperature dependent conformational distributions for a number of important conformers are obtained. The structural characteristics of these conformers are analyzed and it is found that the entropic effect is a dominating factor in determining the relative stabilities of the conformers. The measurements of dipole moments and some characteristic IR mode are shown to be effective approaches to verify the theoreti- cal prediction. The structures of the low energy GFGG conformers are also analyzed in their connection with the secondary structures of proteins. Similarity between the local structures of low energy GFGG conformers and the α-helix is discussed and many β- and γ-turn local structures in GFGG conformers are found.展开更多
Several MoS2 catalysts of different structure, prepared by in situ decomposition of ammonium heptamolybdate (AHM) and molybdenum naphthenate (MoNaph), and by MoS2 exfoliation (TDM), were characterized by BET, X-...Several MoS2 catalysts of different structure, prepared by in situ decomposition of ammonium heptamolybdate (AHM) and molybdenum naphthenate (MoNaph), and by MoS2 exfoliation (TDM), were characterized by BET, X-ray diffraction (XRD), Energy Dispersive X-ray (EDX) and transmission electron microscopy (TEM). The analysis showed that MoS2 structure was dependant upon the preparation procedure. The activity of the catalysts was determined by measuring the hydrodeoxygenation (HDO) of phenol, 4-methylphenol and 4-methoxyphenol using a batch autoclave reactor operated at 2.8 MPa of hydrogen and temperatures ranging from 320-370℃. By comparing the conversion, the reactivity order of the catalysts was: AHM〉TDM-D〉MoNaph〉thermal〉MoS2 powder〉 TDM-W. Also, the effect of reaction temperature on the HDO conversion was explained in terms of equilibrium of reversible reaction kinetics. The main products of the HDO for phenolic compounds were identified by gas chromatography/mass spectrometry (GC/MS). The results showed that the product distribution and the HDO selectivity were correlated with the reaction temperature. Two parallel reaction routes, direct hydrogenolysis and combined hydrogenation-hydrogenolysis, were confirmed by the analysis of the product distribution. High temperature favored hydrogenolysis over hydrogenation for HDO of phenol and 4-methoxyphenol, whereas for 4-methylphenol the reverse was true.展开更多
In this paper, the acoustic scale effects and boundary effects for the similitude model of underwater complex shell-structure are investigated. The similitude conditions and relations between the similitude model and ...In this paper, the acoustic scale effects and boundary effects for the similitude model of underwater complex shell-structure are investigated. The similitude conditions and relations between the similitude model and its prototype were studied in the references. This paper investigates the acoustic scale effects for the similitude model, which are influenced by loss factor, shear and rotatory inertia. At the same time, the boundary effects which are influenced by surface sound reflection are investigated in the experiment of similitude model. The results show that the acoustic scale effects may be controlled with model designing, the boundary effects can be controlled with experimental designing between the similitude model and its prototype.展开更多
The aluminum matrix syntactic foam was fabricated by pressure infiltration technique,and the filling material is syntactic foam material with fly ash cenosphere as the main component and polyurethane foam as the binde...The aluminum matrix syntactic foam was fabricated by pressure infiltration technique,and the filling material is syntactic foam material with fly ash cenosphere as the main component and polyurethane foam as the binder.Split Hopkinson pressure bar(SHPB)dynamic compression and quasi-static tests were carried out to examine the compressive response of syntactic foam in this study.Then the dynamic constitutive model was established.Results show that the compressive stress-strain curve of syntactic aluminum foam is similar to that of other metallic foam materials:both kinds of aluminum matrix syntactic foams have strain rate effect,and the syntactic foam has higher compressive strength and energy absorption than the same density aluminum foams.However,due to the different sizes of cenospheres,the dynamic compression results of two kinds of syntactic foams are different,and the energy absorption effect of syntactic foam with small size under dynamic impact is the best.In the range of strain rate and density studied experimentally,the curves of constitutive model fit well with the curves of experimental data.展开更多
Mergers & acquisitions (M&As) are important strategic instruments, yet nearly half of all transactions fail, often resulting in disastrous write-offs and losses for corporations and financing institutions alike - ...Mergers & acquisitions (M&As) are important strategic instruments, yet nearly half of all transactions fail, often resulting in disastrous write-offs and losses for corporations and financing institutions alike - despite promising prospects upfront. Applied research has been trying to find a "panacea" to prevent or at least predict M&A failure, investigating motives, synergies and performance. Despite the growing unease with the stationary explanatory models in literature, research has only marginally focused on the concept of time, with inquiries into market timing and integration speed. Yet other timing concepts have been neglected in concepts so far despite early empirical evidence for their existence. The purpose of this paper is thus to identify and elaborate on the importance of further relevant theories of timing. For this, and true to the exploratory nature of the topic, the authors have chosen a qualitative comparative case study design based on existing case reports which are investigated for narrations highlighting timing concepts. This study reveals six factors which have a crucial impact on the M&A outcome: time of acquisition, M&A duration in its entirety, M&A sequence, synergy chronology, frequency of acquisitions and time to step back. It contributes to theory and practice in outlining the careful attention that needs to be paid in planning in these factors to enhance the chances of a successful M&A transaction.展开更多
基金Project(10151170003000002)supported by the National Science Foundation of Guangdong Province,China
文摘By the constant stress tensile creep test method, creep tests were performed on aluminum silicate short fiber-reinforced AZ91D magnesium matrix composite with volume fraction of 30% and its matrix alloy AZ91D under different temperatures and stresses. The results indicate that the composite and the matrix have the same true stress exponent and true activation energy for creep, which are 3 and 144.63 kJ/mol, respectively. The creep of the composite is controlled by the creep of its matrix, which is mainly the controlling of viscous slip of dislocation, and the controlling of grain boundary slippage as a supplement. The creep constitutive model obtained from the experiment data can well describe the creep deformation pattern of the composite.
文摘The effect of realistic topology configuration of intercellular connections on the response ability in coupled cell system is numerically investigated by using the Hindmarsh-Rose model. For the proper coupling intensity, we set the control parameter to be near the critical value, and the external stimulus is introduced to the first cell in coupled system. It is found that, on one hand, when the cells are coupled with some proper topological structures, the external stimulus could transmit through the system, and shows better response ability and higher sensitivity. On the other hand, the influence of topological configuration on the synchronous ability and selection effect of neural system are also discussed. Our results display that the topology of coupled system may play an important role in the process of signal propagation, which could help us to understand the coordinated performance of cells in tissue.
基金Projects (90716005, 10802055, 10972153) supported by the National Natural Science Foundation of ChinaProject (2007021005) supported by the Natural Science Foundation of Shanxi Province, China+2 种基金Project supported by the Postdoctoral Science Foundation of ChinaProject supported by the Homecomings Foundation, ChinaProject supported by the Top Young Academic Leaders of Higher Learning Institutions of Shanxi, China
文摘A multi-parameter nonlinear elasto-plastic constitutive model which can fully capture the three typical features of stress-strain response, linearity, plasticity-like stress plateau and densification phases was developed. The functional expression of each parameter was determined using uniaxial compression tests for aluminum alloy foams. The parameters of the model can be systematically varied to describe the effect of relative density which may be responsible for the changes in yield stress and hardening-like or softening-like behavior at various strain rates. A comparison between model predictions and experimental results of the aluminum alloy foams was provided to validate the model. It was proved to be useful in the selection of the optimal-density and energy absorption foam for a specific application at impact events.
基金Projects(50835002,50975174,50821003)supported by the National Natural Science Foundation of ChinaProjects(200802480053,20100073110044)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘Effects of four factors on thin sheet metal flow stress were considered, including grain size d, thickness t, grain number across thickness (t/d ratio) and surface property. Surface model was adopted to quantitatively describe the effect of t/d ratio on flow stress for pure copper. It is predicted that when t/d ratio is larger than a critical value, effect of t/d ratio on flow stress can be neglected. Existence of critical t/d ratio changes the Hall-Petch relationship and evolution of flow stress with thickness. A criterion was proposed to determine critical t/d ratio. Then a comprehensive constitutive model was developed to consider all the four factors, with parameters determined by fitting experimental data of high purity Ni. The predicted results show the same tendencies with experiment results. Particularly when t/d ratio decreases, Hall-Petch relationship and evolution of true stress show varied slopes with two transition points.
文摘Systematic search of the potential energy surface of tetrapeptide glycine-phenylalanine- glycine-glycine (GFGG) in gas phase is conducted by a combination of PM3, HF and BHandHLYP methods. The conformational search method is described in detail. The relative electronic energies, zero point vibrational energies, dipole moments, rotational constants, vertical ionization energies and the temperature dependent conformational distributions for a number of important conformers are obtained. The structural characteristics of these conformers are analyzed and it is found that the entropic effect is a dominating factor in determining the relative stabilities of the conformers. The measurements of dipole moments and some characteristic IR mode are shown to be effective approaches to verify the theoreti- cal prediction. The structures of the low energy GFGG conformers are also analyzed in their connection with the secondary structures of proteins. Similarity between the local structures of low energy GFGG conformers and the α-helix is discussed and many β- and γ-turn local structures in GFGG conformers are found.
文摘Several MoS2 catalysts of different structure, prepared by in situ decomposition of ammonium heptamolybdate (AHM) and molybdenum naphthenate (MoNaph), and by MoS2 exfoliation (TDM), were characterized by BET, X-ray diffraction (XRD), Energy Dispersive X-ray (EDX) and transmission electron microscopy (TEM). The analysis showed that MoS2 structure was dependant upon the preparation procedure. The activity of the catalysts was determined by measuring the hydrodeoxygenation (HDO) of phenol, 4-methylphenol and 4-methoxyphenol using a batch autoclave reactor operated at 2.8 MPa of hydrogen and temperatures ranging from 320-370℃. By comparing the conversion, the reactivity order of the catalysts was: AHM〉TDM-D〉MoNaph〉thermal〉MoS2 powder〉 TDM-W. Also, the effect of reaction temperature on the HDO conversion was explained in terms of equilibrium of reversible reaction kinetics. The main products of the HDO for phenolic compounds were identified by gas chromatography/mass spectrometry (GC/MS). The results showed that the product distribution and the HDO selectivity were correlated with the reaction temperature. Two parallel reaction routes, direct hydrogenolysis and combined hydrogenation-hydrogenolysis, were confirmed by the analysis of the product distribution. High temperature favored hydrogenolysis over hydrogenation for HDO of phenol and 4-methoxyphenol, whereas for 4-methylphenol the reverse was true.
基金Supported by Specialized Research Fund for the Doctoral Program of Higher Education Under Grant No. 20030317013.
文摘In this paper, the acoustic scale effects and boundary effects for the similitude model of underwater complex shell-structure are investigated. The similitude conditions and relations between the similitude model and its prototype were studied in the references. This paper investigates the acoustic scale effects for the similitude model, which are influenced by loss factor, shear and rotatory inertia. At the same time, the boundary effects which are influenced by surface sound reflection are investigated in the experiment of similitude model. The results show that the acoustic scale effects may be controlled with model designing, the boundary effects can be controlled with experimental designing between the similitude model and its prototype.
基金National Natural Science Foundation of China(No.11602233)。
文摘The aluminum matrix syntactic foam was fabricated by pressure infiltration technique,and the filling material is syntactic foam material with fly ash cenosphere as the main component and polyurethane foam as the binder.Split Hopkinson pressure bar(SHPB)dynamic compression and quasi-static tests were carried out to examine the compressive response of syntactic foam in this study.Then the dynamic constitutive model was established.Results show that the compressive stress-strain curve of syntactic aluminum foam is similar to that of other metallic foam materials:both kinds of aluminum matrix syntactic foams have strain rate effect,and the syntactic foam has higher compressive strength and energy absorption than the same density aluminum foams.However,due to the different sizes of cenospheres,the dynamic compression results of two kinds of syntactic foams are different,and the energy absorption effect of syntactic foam with small size under dynamic impact is the best.In the range of strain rate and density studied experimentally,the curves of constitutive model fit well with the curves of experimental data.
文摘Mergers & acquisitions (M&As) are important strategic instruments, yet nearly half of all transactions fail, often resulting in disastrous write-offs and losses for corporations and financing institutions alike - despite promising prospects upfront. Applied research has been trying to find a "panacea" to prevent or at least predict M&A failure, investigating motives, synergies and performance. Despite the growing unease with the stationary explanatory models in literature, research has only marginally focused on the concept of time, with inquiries into market timing and integration speed. Yet other timing concepts have been neglected in concepts so far despite early empirical evidence for their existence. The purpose of this paper is thus to identify and elaborate on the importance of further relevant theories of timing. For this, and true to the exploratory nature of the topic, the authors have chosen a qualitative comparative case study design based on existing case reports which are investigated for narrations highlighting timing concepts. This study reveals six factors which have a crucial impact on the M&A outcome: time of acquisition, M&A duration in its entirety, M&A sequence, synergy chronology, frequency of acquisitions and time to step back. It contributes to theory and practice in outlining the careful attention that needs to be paid in planning in these factors to enhance the chances of a successful M&A transaction.