CdS/ZnS core-shell microparticles were prepared by a simple two-step method combining ultrasonic spray pyrolysis and chemical bath deposition.The core-shell structures showed enhanced photocatalytic properties compare...CdS/ZnS core-shell microparticles were prepared by a simple two-step method combining ultrasonic spray pyrolysis and chemical bath deposition.The core-shell structures showed enhanced photocatalytic properties compared with those of CdS or ZnS spherical particles.CdS/ZnS photocatalysts with different amount of ZnS loaded as shells were prepared by adjusting the concentrations of Zn and S precursors during synthesis.The optical properties and photocatalytic activity for hydrogen production were investigated and the amount of ZnS loaded as shell was optimized.Thermal annealing and hydrothermal sulfurization treatments were applied to the core-shell structure and both treatments enhanced the material's photocatalytic activity and stability by eliminating crystalline defects and surface states.The result showed that thermal annealing treatment improved the bulk crystallinity and hydrothermal sulfurization improved the surface properties.The sample subjected to both treatments showed the highest photocatalytic activity.These results indicate that CdS/ZnS core-shell microspheres are a simple structure that can be used as efficient photocatalysts.The hydrothermal sulfurization treatment may also be a useful surface treatment for metal sulfide photocatalysts.The simple two-step method provides a promising approach to the large-scale synthesis of core-shell microsphere catalysts.展开更多
Among the reactions catalyzed by zeolites there are some that exhibit high selectivity due to the spatial confinement effect of the zeolite framework.Tailoring the acidity,particularly the distribution and location of...Among the reactions catalyzed by zeolites there are some that exhibit high selectivity due to the spatial confinement effect of the zeolite framework.Tailoring the acidity,particularly the distribution and location of the Bronsted acid sites in the zeolite is effective for making it a better catalyst for these reactions.We prepared a series of H-mordenite(H-MOR) samples by varying the composition of the sol-gel,using different structure directing agents and post-treatment.NH3-TPD and IR characterization of adsorbed pyridine were employed to determine the amount of Bronsted acid sites in the 8-membered ring and 12-membered ring channels.It was shown that controlled synthesis was a promising approach to improve the concentration of Bronsted acid sites in MOR,even with a low Al content.Using an appropriate composition of Si and Al in the sol-gel favored a higher proportion of Bronsted acid sites in the 8-membered ring channels.HMI as a structure-direct agent gave an obvious enrichment of Bronsted acid sites in the 8-membered ring.Carbonylation of dimethyl ether was used as a probe reaction to examine the modification of the acid properties,especially the Bronsted acid sites in the 8-membered ring channels.There was a linear relationship between methyl acetate formation and the number of Bronsted acid sites in the 8-membered ring channels,demonstrating the successful modification of acid properties.Our results provide information for the rational design and modification of zeolites with spatial constraints.展开更多
In this paper, a novel component-based scene graph is proposed, in which all objects in the scene are classified to different entities, and a scene can be represented as a hierarchical graph composed of the instances ...In this paper, a novel component-based scene graph is proposed, in which all objects in the scene are classified to different entities, and a scene can be represented as a hierarchical graph composed of the instances of entities. Each entity contains basic data and its operations which are encapsulated into the entity component. The entity possesses certain behaviours which are responses to rules and interaction defined by the high-level application. Such behaviours can be described by script or behaviours model. The component-based scene graph in the paper is more abstractive and high-level than traditional scene graphs. The contents of a scene could be extended flexibly by adding new entities and new entity components, and behaviour modification can be obtained by modifying the model components or behaviour scripts. Its robustness and efficiency are verified by many examples implemented in the Virtual Scenario developed by Peking University.展开更多
The formation mechanism and wear behavior of a gradient nanostructured(GNS) Inconel 625 alloy were investigated using SEM, TEM and ball-on-disc sliding wear tester. The results show that surface mechanical grinding tr...The formation mechanism and wear behavior of a gradient nanostructured(GNS) Inconel 625 alloy were investigated using SEM, TEM and ball-on-disc sliding wear tester. The results show that surface mechanical grinding treatment(SMGT) induced an approximately 800 μm-deep gradient microstructure, consisting of surface nano-grained,nano-laminated, nano-twined, and severely deformed layers, which resulted in a reduced gradient in micro-hardness from 6.95 GPa(topmost surface) to 2.77 GPa(coarse-grained matrix). The nano-grained layer resulted from the formation of high-density nano-twins and subsequent interaction between nano-twins and dislocations. The width and depth of the wear scar, wear loss volume, and wear rate of the SMGT-treated sample were smaller than those of untreated coarse-grained sample. Moreover, the wear mechanisms for both samples were mainly abrasive wear and adhesive wear, accompanied with mild oxidation wear. The notable wear resistance enhancement of the GNS Inconel 625 alloy was attributed to the high micro-hardness, high residual compressive stress, and high strain capacity of the GNS surface layer.展开更多
Processors have been playing important roles in both communication infrastructure systems and terminals.In this paper,both application specific and general purpose processors for communications are discussed including...Processors have been playing important roles in both communication infrastructure systems and terminals.In this paper,both application specific and general purpose processors for communications are discussed including the roles,the history,the current situations,and the trends.One trend is that ASIPs(Application Specific Instruction-set Processors) are taking over ASICs(Application Specific Integrated Circuits) because of the increasing needs both on performance and compatibility of multi-modes.The trend opened opportunities for researchers crossing the boundary between communications and computer architecture.Another trend is the serverlization,i.e.,more infrastructure equipments are replaced by servers.The trend opened opportunities for researchers working towards high performance computing for communication,such as research on communication algorithm kernels and real time programming methods on servers.展开更多
The Ti Bw reinforced near-α titanium matrix composite(Ti-5.8 Al-3.4 Zr-4.0 Sn-0.4 Mo-0.4 Nb-0.4 Si-0.06 C) was successfully synthesized by powder metallurgy and hot extrusion route. The effects of solution and agin...The Ti Bw reinforced near-α titanium matrix composite(Ti-5.8 Al-3.4 Zr-4.0 Sn-0.4 Mo-0.4 Nb-0.4 Si-0.06 C) was successfully synthesized by powder metallurgy and hot extrusion route. The effects of solution and aging temperature on the microstructure and high temperature tensile properties of the composite were investigated. The results revealed that the fine transformed β phase can be obtained by the solution treatment at β phase region and aging treatment, no other precipitates were observed. The α2 phase(Ti3 Al) can be acquired when the solution treated at α+β phase region followed by aging treatment. With increasing the aging temperature from 500 to 700℃ for 5 h, the size of α2 precipitates increases from about 5 to about 30 nm. The Ti Bw are stable without any interfacial reaction during the heat treatments. The high temperature tensile properties show that the composite performed by solution and aging treatment exhibits good strengthening effects. With increasing the aging temperature from 500 to 700℃, the strength of the composite increases at the expense of elongation due to the increment of α2 precipitates.The strength of the composite at 600℃ increases by 17% to 986 MPa after 1000℃/2 h/AC and 700℃/5 h/AC heat treatment.展开更多
基金supported by the National Natural Science Foundation of China(51202186,51323011)the Fundamental Research Funds for the Central University(xjj2016039)~~
文摘CdS/ZnS core-shell microparticles were prepared by a simple two-step method combining ultrasonic spray pyrolysis and chemical bath deposition.The core-shell structures showed enhanced photocatalytic properties compared with those of CdS or ZnS spherical particles.CdS/ZnS photocatalysts with different amount of ZnS loaded as shells were prepared by adjusting the concentrations of Zn and S precursors during synthesis.The optical properties and photocatalytic activity for hydrogen production were investigated and the amount of ZnS loaded as shell was optimized.Thermal annealing and hydrothermal sulfurization treatments were applied to the core-shell structure and both treatments enhanced the material's photocatalytic activity and stability by eliminating crystalline defects and surface states.The result showed that thermal annealing treatment improved the bulk crystallinity and hydrothermal sulfurization improved the surface properties.The sample subjected to both treatments showed the highest photocatalytic activity.These results indicate that CdS/ZnS core-shell microspheres are a simple structure that can be used as efficient photocatalysts.The hydrothermal sulfurization treatment may also be a useful surface treatment for metal sulfide photocatalysts.The simple two-step method provides a promising approach to the large-scale synthesis of core-shell microsphere catalysts.
基金supported by the National Natural Science Foundation of China(21325626,21406120)the Postdoctoral Science Foundation of China(2014M560181,2015T80214)~~
文摘Among the reactions catalyzed by zeolites there are some that exhibit high selectivity due to the spatial confinement effect of the zeolite framework.Tailoring the acidity,particularly the distribution and location of the Bronsted acid sites in the zeolite is effective for making it a better catalyst for these reactions.We prepared a series of H-mordenite(H-MOR) samples by varying the composition of the sol-gel,using different structure directing agents and post-treatment.NH3-TPD and IR characterization of adsorbed pyridine were employed to determine the amount of Bronsted acid sites in the 8-membered ring and 12-membered ring channels.It was shown that controlled synthesis was a promising approach to improve the concentration of Bronsted acid sites in MOR,even with a low Al content.Using an appropriate composition of Si and Al in the sol-gel favored a higher proportion of Bronsted acid sites in the 8-membered ring channels.HMI as a structure-direct agent gave an obvious enrichment of Bronsted acid sites in the 8-membered ring.Carbonylation of dimethyl ether was used as a probe reaction to examine the modification of the acid properties,especially the Bronsted acid sites in the 8-membered ring channels.There was a linear relationship between methyl acetate formation and the number of Bronsted acid sites in the 8-membered ring channels,demonstrating the successful modification of acid properties.Our results provide information for the rational design and modification of zeolites with spatial constraints.
基金Project supported by the National Basic Research Program (973) of China (No. 2004CB719403), and the National Natural Science Foun-dation of China (Nos. 60573151 and 60473100)
文摘In this paper, a novel component-based scene graph is proposed, in which all objects in the scene are classified to different entities, and a scene can be represented as a hierarchical graph composed of the instances of entities. Each entity contains basic data and its operations which are encapsulated into the entity component. The entity possesses certain behaviours which are responses to rules and interaction defined by the high-level application. Such behaviours can be described by script or behaviours model. The component-based scene graph in the paper is more abstractive and high-level than traditional scene graphs. The contents of a scene could be extended flexibly by adding new entities and new entity components, and behaviour modification can be obtained by modifying the model components or behaviour scripts. Its robustness and efficiency are verified by many examples implemented in the Virtual Scenario developed by Peking University.
基金financially supported by the National Key Research and Development Program of China (No. 2017YFA07007003)the National Natural Science Foundation of China (No. 51661019)+4 种基金the Program for Major Projects of Science and Technology in Gansu Province, China (No. 145RTSA004)the Hongliu First-class Discipline Construction Plan of Lanzhou University of Technology, Chinathe Incubation Program of Excellent Doctoral Dissertation, Lanzhou University of Technology, Chinathe Lanzhou University of Technology Excellent Students Studying Abroad Learning Exchange Fundthe State Key Laboratory of Cooperation and Exchange Fund。
文摘The formation mechanism and wear behavior of a gradient nanostructured(GNS) Inconel 625 alloy were investigated using SEM, TEM and ball-on-disc sliding wear tester. The results show that surface mechanical grinding treatment(SMGT) induced an approximately 800 μm-deep gradient microstructure, consisting of surface nano-grained,nano-laminated, nano-twined, and severely deformed layers, which resulted in a reduced gradient in micro-hardness from 6.95 GPa(topmost surface) to 2.77 GPa(coarse-grained matrix). The nano-grained layer resulted from the formation of high-density nano-twins and subsequent interaction between nano-twins and dislocations. The width and depth of the wear scar, wear loss volume, and wear rate of the SMGT-treated sample were smaller than those of untreated coarse-grained sample. Moreover, the wear mechanisms for both samples were mainly abrasive wear and adhesive wear, accompanied with mild oxidation wear. The notable wear resistance enhancement of the GNS Inconel 625 alloy was attributed to the high micro-hardness, high residual compressive stress, and high strain capacity of the GNS surface layer.
基金The National High-Tech Research and Development Program of China(863 Program)2014AA01A705
文摘Processors have been playing important roles in both communication infrastructure systems and terminals.In this paper,both application specific and general purpose processors for communications are discussed including the roles,the history,the current situations,and the trends.One trend is that ASIPs(Application Specific Instruction-set Processors) are taking over ASICs(Application Specific Integrated Circuits) because of the increasing needs both on performance and compatibility of multi-modes.The trend opened opportunities for researchers crossing the boundary between communications and computer architecture.Another trend is the serverlization,i.e.,more infrastructure equipments are replaced by servers.The trend opened opportunities for researchers working towards high performance computing for communication,such as research on communication algorithm kernels and real time programming methods on servers.
基金supported by the National Natural Science Foundation of China(Grant Nos.51701114,11604204,51471063,51271111)the Youth Teacher Development Program of Shanghai Universities(Grant No.ZZGCD15101)+1 种基金Scientific Research Project of Shanghai University of Engineering ScienceTalents Project of Shanghai University of Engineering Science
文摘The Ti Bw reinforced near-α titanium matrix composite(Ti-5.8 Al-3.4 Zr-4.0 Sn-0.4 Mo-0.4 Nb-0.4 Si-0.06 C) was successfully synthesized by powder metallurgy and hot extrusion route. The effects of solution and aging temperature on the microstructure and high temperature tensile properties of the composite were investigated. The results revealed that the fine transformed β phase can be obtained by the solution treatment at β phase region and aging treatment, no other precipitates were observed. The α2 phase(Ti3 Al) can be acquired when the solution treated at α+β phase region followed by aging treatment. With increasing the aging temperature from 500 to 700℃ for 5 h, the size of α2 precipitates increases from about 5 to about 30 nm. The Ti Bw are stable without any interfacial reaction during the heat treatments. The high temperature tensile properties show that the composite performed by solution and aging treatment exhibits good strengthening effects. With increasing the aging temperature from 500 to 700℃, the strength of the composite increases at the expense of elongation due to the increment of α2 precipitates.The strength of the composite at 600℃ increases by 17% to 986 MPa after 1000℃/2 h/AC and 700℃/5 h/AC heat treatment.