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P(DEAM-co-MAA)在稀水溶液中构象行为的荧光探针研究 被引量:3
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作者 刘守信 柳明珠 《物理化学学报》 SCIE CAS CSCD 北大核心 2004年第5期478-482,共5页
利用UV透光率测定,荧光探针技术等研究了N,N-二乙基丙烯酰胺(DEAM)与甲基丙烯酸(MAA)的共聚物P(DEAM-co-MAA)在稀水溶液中的构象行为.结果表明,当共聚物中DEAM含量小于8.00%(molarfrac-tion),溶液的pH<6时,P(DEAM-co-MAA)在稀水溶液... 利用UV透光率测定,荧光探针技术等研究了N,N-二乙基丙烯酰胺(DEAM)与甲基丙烯酸(MAA)的共聚物P(DEAM-co-MAA)在稀水溶液中的构象行为.结果表明,当共聚物中DEAM含量小于8.00%(molarfrac-tion),溶液的pH<6时,P(DEAM-co-MAA)在稀水溶液中的构象行为与聚甲基丙烯酸(PMAA)相似,共聚物可形成疏水微区,表现为一种较为高度压缩的线团构象;当共聚物中DEAM含量大于8.00%(molarfraction)时,由于高分子的稀释效应,P(DEAM-co-MAA)在pH2~10范围内表现为较为松散的伸展构象.P(DEAM-co-MAA)构象随其组成和pH变化的这种性质有可能在新型敏感性凝胶的合成设计上获得应用. 展开更多
关键词 稀水溶液 构象行为 荧光探针 透光率 P(DEAM-co-MAA) 共聚物 疏水缔合反应 凝胶
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温度/pH双敏感性接枝共聚物P(MAA-g-NIPAM)相行为研究
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作者 李芳 刘守信 +3 位作者 刘侠 张朝阳 余娟 房喻 《陕西师范大学学报(自然科学版)》 CAS CSCD 北大核心 2007年第3期52-56,共5页
利用大分子单体技术通过自由基溶液聚合合成了不同组成的接枝共聚物聚(甲基丙烯酸-g-N-异丙基丙烯酰胺)(P(MAA-g-NIPAM)),通过UV透光率的测定和荧光探针技术对接枝共聚物在稀水溶液中的相行为进行了研究.结果表明,接枝共聚物P(MAA-g-NIP... 利用大分子单体技术通过自由基溶液聚合合成了不同组成的接枝共聚物聚(甲基丙烯酸-g-N-异丙基丙烯酰胺)(P(MAA-g-NIPAM)),通过UV透光率的测定和荧光探针技术对接枝共聚物在稀水溶液中的相行为进行了研究.结果表明,接枝共聚物P(MAA-g-NIPAM)具有温度和pH值的双重敏感性,不同组成的P(MAA-g-NIPAM)具有基本相同的低临界溶解温度(LCST).当溶液的pH<6时,随着pH值的降低P(MAA-g-NIPAM)的主链从较为松散的线团构象变为较为压缩的线团构象. 展开更多
关键词 温度和pH敏感性 接枝共聚物 构象行为 临界相变pH 低临界溶解温度(LCST)
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High-extensible scene graph framework based on component techniques
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作者 LI Qi-cheng WANG Guo-ping ZHOU Feng 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2006年第7期1247-1252,共6页
In this paper, a novel component-based scene graph is proposed, in which all objects in the scene are classified to different entities, and a scene can be represented as a hierarchical graph composed of the instances ... In this paper, a novel component-based scene graph is proposed, in which all objects in the scene are classified to different entities, and a scene can be represented as a hierarchical graph composed of the instances of entities. Each entity contains basic data and its operations which are encapsulated into the entity component. The entity possesses certain behaviours which are responses to rules and interaction defined by the high-level application. Such behaviours can be described by script or behaviours model. The component-based scene graph in the paper is more abstractive and high-level than traditional scene graphs. The contents of a scene could be extended flexibly by adding new entities and new entity components, and behaviour modification can be obtained by modifying the model components or behaviour scripts. Its robustness and efficiency are verified by many examples implemented in the Virtual Scenario developed by Peking University. 展开更多
关键词 Scene graph ENTITY Entity component Behaviour script Behaviour model
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A Phenomenological Constitutive Law for the Description of Nonlinear Post-yield Behaviour of Glassy Polymers under Different Strain Rate
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作者 F.ZA■RI K.WOZNICA M.NA■T ABDELAZIZ 《宁波大学学报(理工版)》 CAS 2003年第4期382-387,共6页
In this study, a modelization of the viscoplastic behaviour of amorphous polymers is proposed, from an approach originally developed for metals behaviour at high temperature, in which state variable constitutive equat... In this study, a modelization of the viscoplastic behaviour of amorphous polymers is proposed, from an approach originally developed for metals behaviour at high temperature, in which state variable constitutive equations have been modified. The model includes the effect of strain rate sensitivity, strain softening and strain hardening. A procedure for the identification of model parameters is developed through the use of experimental data from uniaxial tests extracted from the literature, across a variety of strain rates and below the glass transition temperature ( Tg). The numerical algorithm shows that the predictions of this model well describe the intrinsic softening upon yield threshold and the subsequent progressive orientational hardening typical for amorphous glassy polymers. 展开更多
关键词 VISCOPLASTICITY parameters identification glassy polymers behaviour
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二维大分子的构象及凝聚态调控
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作者 王亚 刘森坪 许震 《高分子学报》 SCIE CAS CSCD 北大核心 2022年第7期752-768,共17页
近年来,二维大分子蓬勃发展,已经成为继经典线形与支化拓扑大分子之后的一个重要分支.二维大分子不但补全了经典高分子科学中缺失的二维分子维度,而且成为具有广泛且重要应用前景的材料新体系,将延续高分子科学在国民经济生产生活中的... 近年来,二维大分子蓬勃发展,已经成为继经典线形与支化拓扑大分子之后的一个重要分支.二维大分子不但补全了经典高分子科学中缺失的二维分子维度,而且成为具有广泛且重要应用前景的材料新体系,将延续高分子科学在国民经济生产生活中的重要作用.类比成熟的线形高分子系统,深入理解二维大分子的构象与凝聚态并建立精确的材料结构调控方法是其发展的基础,目前仍然处于起步阶段.本文以我们课题组的研究工作为主线,以氧化石墨烯为二维大分子理想模型,总结了二维大分子构象行为与凝聚态结构调控的研究思路与进展.简要回顾了二维大分子构象的研究历史,介绍了构象行为规律、液晶凝聚态以及固态凝聚结构调控方法的系列新进展,并对未来二维大分子构象及凝聚态研究进行了展望,为二维大分子及材料的发展提供了新思路. 展开更多
关键词 二维大分子 构象行为 凝聚态 二维材料
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Effect of chain length on the conformation and friction behaviour of DNA
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作者 WANG Mian CUI ShuXun +1 位作者 YU BingJun QIAN LinMao 《Science China(Technological Sciences)》 SCIE EI CAS 2013年第12期2927-2933,共7页
Four double-stranded DNA films with different chain lengths were prepared on 3-aminopropyltriethoxysilane(APS)-modified mica surfaces in the NaCl solution with concentration ranging from 0.001 to 0.1 M.By using an ato... Four double-stranded DNA films with different chain lengths were prepared on 3-aminopropyltriethoxysilane(APS)-modified mica surfaces in the NaCl solution with concentration ranging from 0.001 to 0.1 M.By using an atomic force microscope,the force-distance curves and friction behaviour of each DNA film were studied in the NaCl solution that was used in the sample preparation.When adsorbed on mica as films in salt solution,the conformation of DNA molecules would be a combination of loops and"train-like".As the chain length increased from 50 to 20000 bp,the extension rate of DNA film increased from 7.1to 11.5 in 0.001 mol/L NaCl solution,which suggested that the DNA molecule with long chain likely resulted in more extended conformation.In addition,under low normal load,low NaCl concentration could increase the friction of DNA film and the chain length revealed insignificant effect on the friction force of DNA film.Therefore,long chain DNA with low salt concentration is more conducive to the nanopore sequencing process,since extended conformation can make DNA molecules easier to reach into nanopore and the high friction can reduce the translocation speed.These results may benefit the development of the third-generation sequencing technique based on nanopore. 展开更多
关键词 DNA sequencing FRICTION DNA conformation chain length
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