中国东部燕山期的大规模岩浆活动,即侏罗纪—白垩纪(150—100Ma)的碱性流纹岩-碱性玄武岩-金伯利岩-钾镁煌斑岩-碳酸岩及其管道系统,分布于江南造山带内侧和郯庐断裂带南段以西的华北地台内,累积面积超过30万km;。该期短时限内大规模活...中国东部燕山期的大规模岩浆活动,即侏罗纪—白垩纪(150—100Ma)的碱性流纹岩-碱性玄武岩-金伯利岩-钾镁煌斑岩-碳酸岩及其管道系统,分布于江南造山带内侧和郯庐断裂带南段以西的华北地台内,累积面积超过30万km;。该期短时限内大规模活动的岩浆事件代表了中国东部地质历史演化中的一次大火成岩省(LIP)事件,实质控制着中生代以来中国华北—扬子地台的构造格局变化、资源能源形成与地质环境变迁。晚侏罗世—早白垩世(150—100 Ma)的大火成岩省,是中生代中期古太平洋大火成岩省沿中国克拉通东部边缘活动的一部分,是包括昂通爪哇(Ongtong-Java)(Mahoney et al., 1993;Ingle and Coffin, 2004)—中国东部在内的超级地幔柱上涌,在岩石圈板片对流,挤压地幔物质快速上升,引起陆域内长英质地壳物质大规模重熔的结果,形成:(1)髫髻山组—张家口组碱性流纹质-玄武质双峰式火山岩及其管道系统,与华北大规模金-多金属矿成矿作用密切相关;(2)辽宁瓦房店—山东蒙阴—安徽栏杆,湖南宁乡—贵州镇远一带的金伯利岩—钾镁煌斑岩±碳酸岩±基性超基性杂岩及其管道系统,与金刚石、金-铂族元素等成矿关系密切;(3)辽东—胶东半岛、南岭—滇黔桂交界地区的连片花岗岩,是硅质大火成岩省(SLIP)的管道系统(plumbing systems),与金刚石矿、金-铂族元素矿、钨锡铌钽矿、锂-钾-铷-铯-铀矿等,以及油气等战略性关键金属成矿关系密切。同时,巨型岩浆作用引发的富含钾、磷及稀土等微量元素的基岩形成优质土壤层对生态多样性的助益等有利和/或有害的环境效应,直接关系到地球家园的生态环境。因此,中国东部燕山期大火成岩省产生深刻的岩浆-构造-资源-环境效应。展开更多
Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way t...Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines.展开更多
文摘中国东部燕山期的大规模岩浆活动,即侏罗纪—白垩纪(150—100Ma)的碱性流纹岩-碱性玄武岩-金伯利岩-钾镁煌斑岩-碳酸岩及其管道系统,分布于江南造山带内侧和郯庐断裂带南段以西的华北地台内,累积面积超过30万km;。该期短时限内大规模活动的岩浆事件代表了中国东部地质历史演化中的一次大火成岩省(LIP)事件,实质控制着中生代以来中国华北—扬子地台的构造格局变化、资源能源形成与地质环境变迁。晚侏罗世—早白垩世(150—100 Ma)的大火成岩省,是中生代中期古太平洋大火成岩省沿中国克拉通东部边缘活动的一部分,是包括昂通爪哇(Ongtong-Java)(Mahoney et al., 1993;Ingle and Coffin, 2004)—中国东部在内的超级地幔柱上涌,在岩石圈板片对流,挤压地幔物质快速上升,引起陆域内长英质地壳物质大规模重熔的结果,形成:(1)髫髻山组—张家口组碱性流纹质-玄武质双峰式火山岩及其管道系统,与华北大规模金-多金属矿成矿作用密切相关;(2)辽宁瓦房店—山东蒙阴—安徽栏杆,湖南宁乡—贵州镇远一带的金伯利岩—钾镁煌斑岩±碳酸岩±基性超基性杂岩及其管道系统,与金刚石、金-铂族元素等成矿关系密切;(3)辽东—胶东半岛、南岭—滇黔桂交界地区的连片花岗岩,是硅质大火成岩省(SLIP)的管道系统(plumbing systems),与金刚石矿、金-铂族元素矿、钨锡铌钽矿、锂-钾-铷-铯-铀矿等,以及油气等战略性关键金属成矿关系密切。同时,巨型岩浆作用引发的富含钾、磷及稀土等微量元素的基岩形成优质土壤层对生态多样性的助益等有利和/或有害的环境效应,直接关系到地球家园的生态环境。因此,中国东部燕山期大火成岩省产生深刻的岩浆-构造-资源-环境效应。
基金Project(2021YFC2902102)supported by the National Key Research and Development Program of ChinaProject(52374142)supported by the National Natural Science Foundation of ChinaProject(JSTU-2022-066)supported by the Young Talent Support Project of Jiangsu Association for Science and Technology,China。
文摘Roof disaster has always been an important factor restricting coal mine safety production.Acidic effect can reform the rock mass structure to weaken the macroscopic strength characteristics,which is an effective way to control the hard limestone roof.In this study,the effects of various factors on the reaction characteristics and mechanical properties of limestone were analyzed.The results show that the acid with stronger hydrogen production capacity after ionization(pK_(a)<0)has more prominent damage to the mineral grains of limestone.When pKa increases from−8.00 to 15.70,uniaxial compressive strength and elastic modulus of limestone increase by 117.22%and 75.98%.The influence of acid concentration is manifested in the dissolution behavior of mineral crystals,the crystal defects caused by large-scale acid action will lead to the deterioration of limestone strength,and the strength after 15%concentration reformation can be reduced by 59.42%.The effect of acidification time on limestone has stages and is the most obvious in the initial metathesis reaction stage(within 60 min).The key to the strength damage of acidified limestone is the participation of hydrogen ions in the reaction system.Based on the analytic hierarchy process method,the influence weights of acid type,acid concentration and acidification time on strength are 24.30%,59.54% and 16.16%,respectively.The research results provide theoretical support for the acidification control of hard limestone roofs in coal mines.
