取向硅钢中MnS粒子形核析出的动力学计算与分析

利用热力学和动力学的相关理论计算分析了取向硅钢中MnS沉淀析出的动力学行为。计算分析结果表明,MnS粒子在取向硅钢中以在位错线上形核为主导,主要在铁素体中析出。在本文讨论的薄规格取向硅钢的合金成分下,计算出MnS的有效析出温度范围为850~1000℃,临界核心尺寸为0.4~0.8 nm,从开始析出到完全析出所需时间约30 s,建议热轧工序的终轧温度应控制在950℃,热轧板的正火时间应控制在5 min。

镁合金中位错的高分辨Z衬度成像研究

利用Z衬度成像技术研究了两种耐热镁合金Mg_(97)Zn_1Y_2与Mg_(97)Zn_1Gd_2(at.%)中的位错。塑性变形过程中形成的倾侧晶界上周期性分布的基面〈a〉位错分解形成层错,伴随合金元素在层错上富集可以形成类似长周期堆垛的结构,能够钉扎晶界并抑制晶界高温软化。随着应变量增加,观察到了基面〈a〉位错与锥面〈c+a〉位错构成的复合倾侧晶界,以及单纯由〈c+a_(60)〉位错或〈c+a_s〉位错重排构成的晶界,表明开动了〈c+a〉锥面滑移系,有利于协调材料变形。合金元素在位错处偏聚形成柯垂尔气团,可以强化材料。热变形过程中Gd元素在Mg基体内位错的张应变区富集形成柯垂尔气团,加速β′-Mg_7Gd柱面析出相的异质形核生长。

Effect of different quenching processes following solid-solution treatment on properties and precipitation behaviors of 7050 alloy

The effects of quenching in different ways following solid-solution treatment on properties and precipitation behaviors of7050 alloy were investigated by transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, selected areaelectron diffraction （SAED）, hardness and electrical conductivity tests. Results show that after quenching in different ways, electricalconductivity of the alloy decreases rapidly in the first 48 h of natural aging. The electrical conductivity of 7050 alloy in natural agingstate is determined by the size and density of GP zones, and the size of GP zones is the main factor. After natural aging for 70 d, thesize of GP zones is 1.8-2.6 nm in matrix of the immersion quenched sample and it is 1.4-1.8 nm in matrix of both water mist andforced air quenched samples. After natural and artificial peak aging, the hardness of the water mist quenched sample is HV 193.6 andits electrical conductivity is 30.5% （IACS） which are both higher than those of the immersion quenched sample. Therefore, watermist quenching is an ideal quenching method for 7050 alloy sheets after solid-solution treatment.

Effect of pre-recovery on subsequent recrystallization kinetics in moderately deformed and supersaturated Al–Mn alloys

The effect of pre-recovery on the recrystallization kinetics of a supersaturated Al–Mn alloy annealed at 530°C was investigated.The results show that the pre-recovery treatment can lead to faster recrystallization kinetics at the initial stage but cause sluggish recrystallization at the later stage.This different recrystallization behavior is explained by the formation of precipitates-free zones and the consumption of driving force during the pre-recovery treatment.The promoted recrystallization at the early stage can be interpreted by the promotion of recrystallization nucleation through sub-grain growth to a critical size inside precipitates-free zones.A simple model is presented to describe the nucleation of recrystallization with pre-recovery treatment in the supersaturated Al–Mn alloys.

Mg、Zn在2099铝锂合金中的微合金化作用

研究Mg、Zn添加对一种Al-Cu-Li合金微观组织演变及力学性能的影响。结果表明,Mg、Zn的添加促进了δ′相的形核析出,并且可以降低其长大速度,因而使得合金中的δ′相更加细小弥散。在时效早期,含Mg和Zn的合金中析出大量的GP区,而不含Mg只含Zn的合金中没有看到GP区的存在,只有少量粗大的θ′相;含Mg不含Zn的合金中也有较多的GP区生成,这说明Mg促进GP区的形成,Zn单独作用对GP区形成无太大影响,只有和Mg一起作用时起到加速GP区形成的作用。随着时效的进行,含Mg和Zn的合金中GP区转变成θ′/θ′′相,而不含Mg只含Zn的合金中θ′相无明显变化,含Mg不含Zn的合金中也有大量θ′/θ′′相生成。说明Mg是促进θ′/θ′′相形成的主要元素,而Zn只是在有Mg的存在下起到促进其形成的作用。