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水蒸气对煤焦油模化物裂解行为及析碳的影响 被引量:2
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作者 翟建荣 钟梅 +1 位作者 马凤云 胡浩权 《化工学报》 EI CAS CSCD 北大核心 2019年第8期2898-2908,F0002,共12页
采用机械化学法制备Ni-Ce/Al2O3催化剂,在固定床反应器中考察了水蒸气气氛对煤焦油模型化合物甲苯+芘催化裂解行为的影响。根据产物生成规律提出了芘向萘转化的裂解机理,并以D2O对其进行了验证。通过XRD、TG-DTG和Raman等表征了析碳的... 采用机械化学法制备Ni-Ce/Al2O3催化剂,在固定床反应器中考察了水蒸气气氛对煤焦油模型化合物甲苯+芘催化裂解行为的影响。根据产物生成规律提出了芘向萘转化的裂解机理,并以D2O对其进行了验证。通过XRD、TG-DTG和Raman等表征了析碳的类型与结构特征。结果表明:相较于纯氮气气氛,水的加入可明显提升重质组分芘的裂解率,且随水碳比(S/C)增加呈先增加后降低的趋势,在S/C=0.15时达到最大值98.93%,比S/C=0时增加32.09%。析碳率随S/C比增加一直呈下降趋势,由S/C=0时的10.04%降至S/C=0.26时的5.39%。析碳分析结果表明,S/C=0时,生成的积炭类型主要是β型碳及γ型碳,水蒸气存在时,活性较高的α型碳含量增加,说明水蒸气的持续消碳作用抑制了Cα向Cβ与Cγ方向转化。 展开更多
关键词 催化剂 催化(作用) 固定床 模型化合物 S/C比 析碳类型
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Mathematical Analysis of a Chemotaxis-Type Model of Soil Carbon Dynamic
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作者 alaaeddine hammoudi oana iosifescu 《Chinese Annals of Mathematics,Series B》 SCIE CSCD 2018年第2期253-280,共28页
The goal of this paper is to study the mathematical properties of a new model of soil carbon dynamics which is a reaction-diffusion system with a chemotactic term, with the aim to account for the formation of soil agg... The goal of this paper is to study the mathematical properties of a new model of soil carbon dynamics which is a reaction-diffusion system with a chemotactic term, with the aim to account for the formation of soil aggregations in the bacterial and microorganism spatial organization(hot spot in soil). This is a spatial and chemotactic version of MOMOS(Modelling Organic changes by Micro-Organisms of Soil), a model recently introduced by M. Pansu and his group. The authors present here two forms of chemotactic terms, first a"classical" one and second a function which prevents the overcrowding of microorganisms.They prove in each case the existence of a nonnegative global solution, and investigate its uniqueness and the existence of a global attractor for all the solutions. 展开更多
关键词 Soil organic carbon dynamics Reaction-Diffusion-Advection system Positive weak solutions Periodic weak solutions
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