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高效液相色谱法测定玉米淀粉中禁用的脲类农药 被引量:2
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作者 田玉平 顾玲玲 《理化检验(化学分册)》 CAS CSCD 北大核心 2008年第9期880-882,共3页
应用高效液相色谱法(HPLC)测定了玉米淀粉中3种禁用的脲衍生物农药,即氯磺隆、枯草隆及定虫隆。试样中的上述农药用甲醇超声萃取,所得萃取液经蒸发并用氮气吹干后溶于1mL甲醇中供HPLC测定用。用ZORBAX Eclipse XDB-C_(18)色谱柱(2.1mm&#... 应用高效液相色谱法(HPLC)测定了玉米淀粉中3种禁用的脲衍生物农药,即氯磺隆、枯草隆及定虫隆。试样中的上述农药用甲醇超声萃取,所得萃取液经蒸发并用氮气吹干后溶于1mL甲醇中供HPLC测定用。用ZORBAX Eclipse XDB-C_(18)色谱柱(2.1mm×150mm,5μm)作为固定相,并用不同比例配成的乙腈和水的混合液作为流动相进行梯度淋洗,采用220nm波长的列阵二极管检测器进行检测。3种农药的线性范围均在0.2~100.0mg·L^(-1)范围内,方法的检出限(S/N=3)为0.04mg·kg^(-1)(氯磺隆),0.03mg·kg^(-1)(枯草隆)及0.01mg·kg^(-1)(定虫隆)。以玉米淀粉样品作基体用标准加入法作方法回收试验和精密度试验,测得上述3种农药的平均回收率(n=5)依次为92.0%,93.4%及95.9%;相对标准偏差(n=6)依次为3.5%,2.7%及3.8%。 展开更多
关键词 高效液相色谱法 氯磺 枯草隆 定虫 玉米淀粉
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Effects of Different Herbicides on Maize Growth and Weed Control in Maize Fields 被引量:1
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作者 Yanyan CHEN Yang YANG +1 位作者 Jing ZHOU Guiyuan MENG 《Agricultural Science & Technology》 CAS 2017年第9期1738-1740,共3页
Effects of four herbicides(paraquat, acetochlor, nicosulfuron and atrazine) on the growth of maize and control effect of plant quantity and fresh weight of weeds were studied. The results showed that 15 days after spr... Effects of four herbicides(paraquat, acetochlor, nicosulfuron and atrazine) on the growth of maize and control effect of plant quantity and fresh weight of weeds were studied. The results showed that 15 days after spraying the herbicides on weeds,the prevention and control effect of paraquat on weeds was the optimum, and its effects on the plant quantity and fresh weight of weeds were above 81.57%; the prevention and control effect of acetochlor on weeds was the second best; the prevention and control effect of atrazine on weeds was the worst, and its effects on the plant quantity and fresh weight of weeds were only 51.04% and 37.86%. After 30 or 45 days, the prevention and control effect of atrazine and nicosulfuron on weeds in the maize fields was better than the other herbicides, and their effects on the plant quantity and fresh weight of weeds were higher than 70.00% and 85.00%. Acetochlor and paraquat had certain phytotoxicity to the growth of maize after about 15 days, and its leaves became yellow and grew slowly. On the whole, nicosulfuron had good prevention and control effect on weeds and had no phytotoxicity to the growth of maize. 展开更多
关键词 MAIZE HERBICIDES WEEDS GROWTH Prevention and control effect
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