Different solvothermal reactions of ZnC2O_(4)with oxalic acid(H_(2)ox)and 1,2,4-triazole(Htrz)successfully gave a new quaternary(NJTU-Bai83,NJTU-Bai=Nanjing Tech University Bai's group)and a new quinary(NJTU-Bai84...Different solvothermal reactions of ZnC2O_(4)with oxalic acid(H_(2)ox)and 1,2,4-triazole(Htrz)successfully gave a new quaternary(NJTU-Bai83,NJTU-Bai=Nanjing Tech University Bai's group)and a new quinary(NJTU-Bai84)anionic metal-organic frameworks(MOFs),where NJTU-Bai83=(Me_(2)NH_(2))2[Zn_(3)(trz)_(2)(ox)_(3)]·2H_(2)O and NJTU-Bai84=(Me_(2)NH_(2))[Zn_(3)(trz)_(3)(ox)_(2)]·H_(2)O,respectively.With the[Zn_(2)(ox)4(trz)_(2)]secondary building unit(SBU)in NJTU-Bai83 replaced by the[Zn_(3)(ox)_(2)(trz)_(6)]and planar[Zn(ox)_(2)(trz)_(2)]ones in NJTU-Bai84,2D supramolecular building layers(SBLs)are changed from the A-layer and B-layer to another A-layer,while pillars are transformed from the tetrahedral[Zn(ox)_(2)(trz)_(2)]SBU to the irregular tetrahedral[Zn(ox)_(2)(trz)_(2)]and planar[Zn(ox)_(2)(trz)_(2)]SBUs.Thus,cdq-topological quaternary NJTU-Bai83 is tuned to(4,4,8)-c new topological quinary NJTU-Bai84.Two MOFs were well characterized by powder X-ray diffraction,thermogravimetric analysis,elemental analysis,etc.CCDC:2351819,NJTU-Bai83;2351820,NJTU-Bai84.展开更多
In order to achieve the safe mining in Sanshandao Gold Mine,five schemes of secure pillar group are designed.Using the method of the renormalization group,the failure mechanism of the pillar group is explored,and the ...In order to achieve the safe mining in Sanshandao Gold Mine,five schemes of secure pillar group are designed.Using the method of the renormalization group,the failure mechanism of the pillar group is explored,and the safety factor of the pillar system is also obtained.The displacement characteristics,stress-strain laws,distribution of plastic zone and damage range of different pillar group are analyzed using numerical calculation software FLAC3D.To determine a reasonable pillar group scheme,the pillar stability and roof deformation are utilized to evaluate the safety of the pillar group.In addition,the theory of fuzzy comprehensive evaluation is adopted to verify the optimal scheme.The pillar group with the lowest roof deformation value is chosen as the optimal plan,which renders a factor of safety of 2.06 for the pillar group.According to this scheme,pillars with the width of 10 m are set along the strike of undersea deposit with the interval of 50 m.Rib pillars of 15 m in width are set at the location of the exploration line of 127,151 and 167.The analysis can be used to provide guidance for optimal design of pillar structures in undersea mining.展开更多
In order to solve the surrounding rock control problem of large section gangue replacement roadway under complicated conditions, this paper analyzed the impact to the roadway controlling produced by the geological con...In order to solve the surrounding rock control problem of large section gangue replacement roadway under complicated conditions, this paper analyzed the impact to the roadway controlling produced by the geological conditions such as high ground stress, folded structure tilted roof asymmetry and soft wall rock, and built the tilt layered roof structural mechanics model to clarify the increase span mechanism of the weak coal instability. Then, we proposed the combined control system including roof inclined truss cable, coal-side cable-channel steel and intensive bolt support. And then by building the structural mechanics model of roof inclined truss cable system, the support principle was described. Besides, according to this model, we deduced the calculation formula of cable anchoring force and its tensile stress. Finally surrounding rock control technology of large section roadway in fold coal pillar area was formed. Field practice shows that the greatest roof convergence of gangue replacement roadway is 158 mm and coal-side deformation is 243 mm. Roadway deformation is controlled effectively and technical support is provided for replacement mining.展开更多
Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed und...Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed under cyclic loading. The original columns at lower two stories of the model frame are short columns and they are replaced by the split columns. The hysteresis curves between the horizontal cyclic load and the lateral displacement at the top of the model frame, indicate that under the cyclic loading, the model frame undergoes the process of cracking, yielding, and maximum loading before being destroyed at the ultimate load. They also indicate that the model frame has better ductility, and the ratio of the ultimate displacement to the yielding displacement, reaches 6.0. The yielding process of the model frame shows that for the frame with split columns, plastic hinges are generated at the ends of beams and then the columns begin yielding while the frame still possesses the bearing and deformation capacity. The design idea of directly changing the short column to long one in the reinforced concrete frame may be realized by replacing the short column with the split one.展开更多
The inter-story drift stiffness considered the semirigidity of beam and column joints connection, and P-Delta second order effect of steel frame parts in the mixed structure is presented in the paper. After considerin...The inter-story drift stiffness considered the semirigidity of beam and column joints connection, and P-Delta second order effect of steel frame parts in the mixed structure is presented in the paper. After considering on the influence of semirigidity between steel beams and steel columns, second order effect of beam-column members for steel frame and structural second order effect, the traditional continuum analytial method used in RC shear-frames wall structure is developed to steel frames-reinforced concrete shear wall mixed structure subject to horizontal load in this paper. A continuum approach, which is suitable for analyzing steel frames-reinforced concrete shear wall mixed structure subject to horizontal load, is presented. The method is relatively simple and more practical. It will be referred to structural design for steel frames-reinforced concrete shear wall mixed structure.展开更多
文摘Different solvothermal reactions of ZnC2O_(4)with oxalic acid(H_(2)ox)and 1,2,4-triazole(Htrz)successfully gave a new quaternary(NJTU-Bai83,NJTU-Bai=Nanjing Tech University Bai's group)and a new quinary(NJTU-Bai84)anionic metal-organic frameworks(MOFs),where NJTU-Bai83=(Me_(2)NH_(2))2[Zn_(3)(trz)_(2)(ox)_(3)]·2H_(2)O and NJTU-Bai84=(Me_(2)NH_(2))[Zn_(3)(trz)_(3)(ox)_(2)]·H_(2)O,respectively.With the[Zn_(2)(ox)4(trz)_(2)]secondary building unit(SBU)in NJTU-Bai83 replaced by the[Zn_(3)(ox)_(2)(trz)_(6)]and planar[Zn(ox)_(2)(trz)_(2)]ones in NJTU-Bai84,2D supramolecular building layers(SBLs)are changed from the A-layer and B-layer to another A-layer,while pillars are transformed from the tetrahedral[Zn(ox)_(2)(trz)_(2)]SBU to the irregular tetrahedral[Zn(ox)_(2)(trz)_(2)]and planar[Zn(ox)_(2)(trz)_(2)]SBUs.Thus,cdq-topological quaternary NJTU-Bai83 is tuned to(4,4,8)-c new topological quinary NJTU-Bai84.Two MOFs were well characterized by powder X-ray diffraction,thermogravimetric analysis,elemental analysis,etc.CCDC:2351819,NJTU-Bai83;2351820,NJTU-Bai84.
基金Project(41630642)supported by the Key Project of National Natural Science Foundation of ChinaProjects(51674288,11402311)supported by the National Natural Science Foundation of China
文摘In order to achieve the safe mining in Sanshandao Gold Mine,five schemes of secure pillar group are designed.Using the method of the renormalization group,the failure mechanism of the pillar group is explored,and the safety factor of the pillar system is also obtained.The displacement characteristics,stress-strain laws,distribution of plastic zone and damage range of different pillar group are analyzed using numerical calculation software FLAC3D.To determine a reasonable pillar group scheme,the pillar stability and roof deformation are utilized to evaluate the safety of the pillar group.In addition,the theory of fuzzy comprehensive evaluation is adopted to verify the optimal scheme.The pillar group with the lowest roof deformation value is chosen as the optimal plan,which renders a factor of safety of 2.06 for the pillar group.According to this scheme,pillars with the width of 10 m are set along the strike of undersea deposit with the interval of 50 m.Rib pillars of 15 m in width are set at the location of the exploration line of 127,151 and 167.The analysis can be used to provide guidance for optimal design of pillar structures in undersea mining.
文摘In order to solve the surrounding rock control problem of large section gangue replacement roadway under complicated conditions, this paper analyzed the impact to the roadway controlling produced by the geological conditions such as high ground stress, folded structure tilted roof asymmetry and soft wall rock, and built the tilt layered roof structural mechanics model to clarify the increase span mechanism of the weak coal instability. Then, we proposed the combined control system including roof inclined truss cable, coal-side cable-channel steel and intensive bolt support. And then by building the structural mechanics model of roof inclined truss cable system, the support principle was described. Besides, according to this model, we deduced the calculation formula of cable anchoring force and its tensile stress. Finally surrounding rock control technology of large section roadway in fold coal pillar area was formed. Field practice shows that the greatest roof convergence of gangue replacement roadway is 158 mm and coal-side deformation is 243 mm. Roadway deformation is controlled effectively and technical support is provided for replacement mining.
基金Supported by National Science Fund for Distinguished Young Scholars of China( No. 50425824
文摘Based on a series of previous studies, an experiment on the integral seismic behavior of a 1/3 scaled model of two-bay and three-story reinforced concrete frame with split columns at lower two stories is performed under cyclic loading. The original columns at lower two stories of the model frame are short columns and they are replaced by the split columns. The hysteresis curves between the horizontal cyclic load and the lateral displacement at the top of the model frame, indicate that under the cyclic loading, the model frame undergoes the process of cracking, yielding, and maximum loading before being destroyed at the ultimate load. They also indicate that the model frame has better ductility, and the ratio of the ultimate displacement to the yielding displacement, reaches 6.0. The yielding process of the model frame shows that for the frame with split columns, plastic hinges are generated at the ends of beams and then the columns begin yielding while the frame still possesses the bearing and deformation capacity. The design idea of directly changing the short column to long one in the reinforced concrete frame may be realized by replacing the short column with the split one.
文摘The inter-story drift stiffness considered the semirigidity of beam and column joints connection, and P-Delta second order effect of steel frame parts in the mixed structure is presented in the paper. After considering on the influence of semirigidity between steel beams and steel columns, second order effect of beam-column members for steel frame and structural second order effect, the traditional continuum analytial method used in RC shear-frames wall structure is developed to steel frames-reinforced concrete shear wall mixed structure subject to horizontal load in this paper. A continuum approach, which is suitable for analyzing steel frames-reinforced concrete shear wall mixed structure subject to horizontal load, is presented. The method is relatively simple and more practical. It will be referred to structural design for steel frames-reinforced concrete shear wall mixed structure.